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# Origin of acidic surface waters and the evolution of atmospheric chemistry on early Mars

## Abstract

Observations from in situ experiments and planetary orbiters have shown that the sedimentary rocks found at Meridiani Planum, Mars were formed in the presence of acidic surface waters1,2,3,4. The water was thought to be brought to the surface by groundwater upwelling5,6, and may represent the last vestiges of the widespread occurrence of liquid water on Mars. However, it is unclear why the surface waters were acidic. Here we use geochemical calculations, constrained by chemical and mineralogical data from the Mars Exploration Rover Opportunity7,8,9,10, to show that Fe oxidation and the precipitation of oxidized iron (Fe3+) minerals generate excess acid with respect to the amount of base anions available in the rocks present in outcrop. We suggest that subsurface waters of near-neutral pH and rich in Fe2+ were rapidly acidified as iron was oxidized on exposure to O2 or photo-oxidized by ultraviolet radiation at the martian surface. Temporal variation in surface acidity would have been controlled by the availability of liquid water, and as such, low-pH fluids could be a natural consequence of the aridification of the martian surface. Finally, because iron oxidation at Meridiani would have generated large amounts of gaseous H2, ultimately derived from the reduction of H2O, we conclude that surface geochemical processes would have affected the redox state of the early martian atmosphere.

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Download references ## Acknowledgements Research was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (J.A.H., R.E.M.). This work was also supported by the California Institute of Technology (W.W.F.) and by an Origins Initiative Postdoctoral Fellowship (N.J.T.). The authors thank Y. Yung, N. Heavens and J. Wilson for constructive comments. ## Author information ### Affiliations Authors ### Contributions J.A.H. carried out data analysis, modelling and wrote the paper, W.W.F. and J.A.H. conceived the study, N.J.T. and R.E.M. contributed to modelling and W.W.F., N.J.T. and R.E.M. contributed to writing. ### Corresponding authors Correspondence to Joel A. Hurowitz or Nicholas J. Tosca. ## Ethics declarations ### Competing interests The authors declare no competing financial interests. ## Supplementary information ### Supplementary Information Supplementary Information (PDF 429 kb) ## Rights and permissions Reprints and Permissions ## About this article ### Cite this article Hurowitz, J., Fischer, W., Tosca, N. et al. Origin of acidic surface waters and the evolution of atmospheric chemistry on early Mars. Nature Geosci 3, 323–326 (2010). https://doi.org/10.1038/ngeo831 Download citation • Received: • Accepted: • Published: • Issue Date: ## Further reading • ### A coupled model of episodic warming, oxidation and geochemical transitions on early Mars • Robin Wordsworth • , Andrew H. Knoll • , Joel Hurowitz • , Mark Baum • , Bethany L. Ehlmann • , James W. Head • & Kathryn Steakley Nature Geoscience (2021) • ### Anoxic chemical weathering under a reducing greenhouse on early Mars • J. Liu • , J. R. Michalski • , W. Tan • , H. He • , B. Ye • & L. 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