Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Earth's air pressure 2.7 billion years ago constrained to less than half of modern levels

Abstract

How the Earth stayed warm several billion years ago when the Sun was considerably fainter is the long-standing problem of the ‘faint young Sun paradox’. Because of negligible1 O2 and only moderate CO2 levels2 in the Archaean atmosphere, methane has been invoked as an auxiliary greenhouse gas3. Alternatively, pressure broadening in a thicker atmosphere with a N2 partial pressure around 1.6–2.4 bar could have enhanced the greenhouse effect4. But fossilized raindrop imprints indicate that air pressure 2.7 billion years ago (Gyr) was below twice modern levels and probably below 1.1 bar, precluding such pressure enhancement5. This result is supported by nitrogen and argon isotope studies of fluid inclusions in 3.0–3.5 Gyr rocks6. Here, we calculate absolute Archaean barometric pressure using the size distribution of gas bubbles in basaltic lava flows that solidified at sea level 2.7 Gyr in the Pilbara Craton, Australia. Our data indicate a surprisingly low surface atmospheric pressure of Patm = 0.23 ± 0.23 (2σ) bar, and combined with previous studies suggests 0.5 bar as an upper limit to late Archaean Patm. The result implies that the thin atmosphere was rich in auxiliary greenhouse gases and that Patm fluctuated over geologic time to a previously unrecognized extent.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Geology of the Beasley River field area, southwestern Pilbara, and sampling localities.
Figure 2: Beasley River locality (‘br’ in Fig. 1) with the locations of five conformable subaerial lava flows, along with the location of collected samples.
Figure 3: Beasley River geologic context and flow detail.

Similar content being viewed by others

References

  1. Holland, H. D. The oxygenation of the atmosphere and oceans. Phil. Trans. R. Soc. B 361, 903–915 (2006).

    Article  Google Scholar 

  2. Sheldon, N. D. Precambrian paleosols and atmospheric CO2 levels. Precambr. Res. 147, 148–155 (2006).

    Article  Google Scholar 

  3. Kasting, J. F. & Siefert, J. L. Life and the evolution of Earth’s atmosphere. Science 296, 1066–1068 (2002).

    Article  Google Scholar 

  4. Goldblatt, C. et al. Nitrogen-enhanced greenhouse warming on early Earth. Nature Geosci. 2, 891–896 (2009).

    Article  Google Scholar 

  5. Som, S. M., Catling, D. C., Harnmeijer, J. P., Polivka, P. M. & Buick, R. Air density 2.7 billion years ago limited to less than twice modern levels by fossil raindrop imprints. Nature 484, 359–362 (2012).

    Article  Google Scholar 

  6. Marty, B., Zimmermann, L., Pujol, M., Burgess, R. & Philippot, P. Nitrogen isotopic composition and density of the Archean atmosphere. Science 342, 101–104 (2013).

    Article  Google Scholar 

  7. Sahagian, D. L. & Maus, J. E. Basalt vesicularity as a measure of atmospheric pressure and palaeoelevation. Nature 372, 449–451 (1994).

    Article  Google Scholar 

  8. Sahagian, D., Proussevitch, A. & Carlson, W. Analysis of vesicular basalts and lava emplacement processes for application as a paleobarometer/paleoaltimeter. J. Geol. 110, 671–685 (2002).

    Article  Google Scholar 

  9. Sahagian, D., Proussevitch, A. & Carlson, W. Timing of Colorado Plateau uplift: initial constraints from vesicular basalt-derived paleoelevations. Geology 30, 807–810 (2002).

    Article  Google Scholar 

  10. Flowers, R. & Farley, K. Apatite 4He/3He and (U-Th)/He evidence for an ancient Grand Canyon. Science 338, 1616–1619 (2012).

    Article  Google Scholar 

  11. Xia, G. Q., Yi, H. S., Zhao, X. X., Gong, D. X. & Ji, C. J. A late Mesozoic high plateau in eastern China: evidence from basalt vesicular paleoaltimetry. Chin. Sci. Bull. 57, 2767–2777 (2012).

    Article  Google Scholar 

  12. Aydar, E. et al. Central Anatolian Plateau, Turkey: incision and paleoaltimetry recorded from volcanic rocks. Turk. J. Earth Sci. 22, 739–746 (2013).

    Article  Google Scholar 

  13. Aubele, J. C., Crumpler, L. & Elston, W. E. Vesicle zonation and vertical structure of basalt flows. J. Volcanol. Geotherm. Res. 35, 349–374 (1988).

    Article  Google Scholar 

  14. Hon, K., Kauahikaua, J., Denlinger, R. & Mackay, K. Emplacement and inflation of pahoehoe sheet flows: observations and measurements of active lava flows on Kilauea Volcano, Hawaii. Geol. Soc. Am. Bull. 106, 351–370 (1994).

    Article  Google Scholar 

  15. Moore, J. G. Density of basalt core from Hilo drill hole, Hawaii. J. Volcanol. Geotherm. Res. 112, 221–230 (2001).

    Article  Google Scholar 

  16. Blake, T. S. Late Archaean crustal extension, sedimentary basin formation, flood basalt volcanism and continental rifting: the Nullagine and Mount Jope Supersequences, Western Australia. Precambr. Res. 60, 185–241 (1993).

    Article  Google Scholar 

  17. Som, S. M. et al. Quantitative discrimination between geological materials with variable density contrast by high resolution X-ray computed tomography: an example using amygdule size-distribution in ancient lava flows. Comput. Geosci. 54, 231–238 (2013).

    Article  Google Scholar 

  18. Ketcham, R. A. Computational methods for quantitative analysis of three-dimensional features in geological specimens. Geosphere 1, 32–41 (2005).

    Article  Google Scholar 

  19. Berner, R. Geological nitrogen cycle and atmospheric N2 over Phanerozoic time. Geology 34, 413–415 (2006).

    Article  Google Scholar 

  20. Busigny, V., Cartigny, P. & Philippot, P. Nitrogen isotopes in ophiolitic metagabbros: a re-evaluation of modern nitrogen fluxes in subduction zones and implication for the early Earth atmosphere. Geochim. Cosmochim. Acta 75, 7502–7521 (2011).

    Article  Google Scholar 

  21. Turner, G. The outgassing history of the Earth’s atmosphere. J. Geol. Soc. Lond. 146, 147–154 (1989).

    Article  Google Scholar 

  22. Navarro-González, R., McKay, C. P. & Mvondo, D. N. A possible nitrogen crisis for Archaean life due to reduced nitrogen fixation by lightning. Nature 412, 61–64 (2001).

    Article  Google Scholar 

  23. Zahnle, K. J. Photochemistry of methane and the formation of hydrocyanic acid (HCN) in the Earth’s early atmosphere. J. Geophys. Res. 91, 2819–2834 (1986).

    Article  Google Scholar 

  24. Kasting, J. F. & Siefert, J. L. The nitrogen fix. Nature 412, 26–27 (2001).

    Article  Google Scholar 

  25. Stüeken, E., Buick, R., Guy, B. & Koehler, M. C. Isotopic evidence for biological nitrogen fixation by molybdenum-nitrogenase from 3.2 Gyr. Nature 520, 666–669 (2015).

    Article  Google Scholar 

  26. Papineau, D., Mojzsis, S., Karhu, J. & Marty, B. Nitrogen isotopic composition of ammoniated phyllosilicates: case studies from Precambrian metamorphosed sedimentary rocks. Chem. Geol. 216, 37–58 (2005).

    Article  Google Scholar 

  27. Holland, H. Volcanic gases, black smokers, and the Great Oxidation Event. Geochim. Cosmochim. Acta 66, 3811–3826 (2002).

    Article  Google Scholar 

  28. Honma, H. High ammonium contents in the 3800 Ma Isua supracrustal rocks, central West Greenland. Geochim. Cosmochim. Acta 60, 2173–2178 (1996).

    Article  Google Scholar 

  29. Mikhail, S. & Sverjensky, D. A. Nitrogen speciation in upper mantle fluids and the origin of Earth’s nitrogen-rich atmosphere. Nature Geosci. 7, 2–5 (2014).

    Article  Google Scholar 

  30. Hersterberg, T., Moore, D. S., Monaghan, S., Clipson, A. & Epstein, R. in Introduction to the Practice of Statistics (eds Moore, D. S. & McCabe, G. P.) (W. H. Freeman, 2012).

    Google Scholar 

Download references

Acknowledgements

This work was supported by NASA Exobiology/Astrobiology grant NNX08AP56G to R.B. Additional support came from NASA Astrobiology Institute grant NNA13AA93A. The Washington State University Geoanalytical Laboratory performed the major- and trace-element analyses. S.M.S. thanks E. Stüeken for insightful conversations on K+ replacement in clays. We thank S. Mikhail, D. Sahagian and B. Marty for helpful reviews.

Author information

Authors and Affiliations

Authors

Contributions

R.B. conceived the project and led the field work in Western Australia, T.S.B. discovered the locality, J.P.H. assisted in mapping the locality, D.C.C. supervised the data analysis and contributed to the geologic N cycle interpretation, J.W.H. supervised the X-ray work, J.M.P. assisted in extracting amygdale dimensions, S.M.S. assisted in the Beasley River field work, prepared samples for analysis, X-rayed the cores, developed the algorithm to analyse the X-ray images, led the amygdale dimension extraction task, analysed the data, and contributed to the geologic N cycle interpretation. S.M.S., R.B. and D.C.C. wrote the manuscript.

Corresponding author

Correspondence to Sanjoy M. Som.

Ethics declarations

Competing interests

The authors declare no competing financial interests.

Supplementary information

Supplementary Information

Supplementary Information (PDF 4882 kb)

Supplementary Information

Supplementary Information (ZIP 383 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Som, S., Buick, R., Hagadorn, J. et al. Earth's air pressure 2.7 billion years ago constrained to less than half of modern levels. Nature Geosci 9, 448–451 (2016). https://doi.org/10.1038/ngeo2713

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/ngeo2713

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing