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Phase transformation and nanometric flow cause extreme weakening during fault slip

Abstract

Earthquake instability requires fault weakening during slip. The mechanism of this weakening is central to understanding earthquake sliding and, in many cases, has been attributed to fluids. It is also unclear why major faults such as the San Andreas Fault do not exhibit significant thermal anomalies due to shear heating during sliding and whether or not fault rocks that have been melted—pseudotachylytes—are rare. High-speed friction experiments on a wide variety of rock types have shown that they all exhibit extreme weakening and that the sliding surface is nanometric and contains phases not present at the start. Here we use electron microscopy to examine these two key observations in high-speed friction experiments and compare them with high-pressure faulting experiments. We show that phase transformations occur in both cases and that they are associated with profound weakening. However, fluid is not necessary for such weakening; the nanometric fault filling is inherently weak at seismic sliding rates and it flows by grain boundary sliding. These observations suggest that pseudotachylytes are rare in nature because shear-heating-induced endothermic reactions in fault zones prevent temperature rise to melting. Microstructures preserved in the Punchbowl Fault, an ancestral branch of the San Andreas Fault, suggest similar processes during natural faulting and offer an explanation for the lack of a thermal aureole around major faults.

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Figure 1: Kasota dolomite sliding experiment.
Figure 2: Composition of a sliding surface and TEM microstructures of a cross-section from the high-speed dolomite experiment.
Figure 3: Fault in Mg2GeO4 olivine (1.3 GPa, 1,200 K).
Figure 4: Punchbowl Fault.

References

  1. Scholz, C. H. The Mechanics of Earthquakes and Faulting 2nd edn, 496 (Cambridge Univ. Press, 2002).

    Book  Google Scholar 

  2. Di Toro, G. et al. Fault lubrication during earthquakes. Nature 471, 494–498 (2011).

    Article  Google Scholar 

  3. Tullis, T. E. in Treatise on Geophysics, v.4, Earthquake Seismology (ed. Kanamori, H.) Ch. 5 (Elsevier, 2014, in the press)

  4. Goldsby, D. L. & Tullis, T. E. Low frictional strength of quartz rocks at subseismic slip rates. Geophys. Res. Lett. 29, 1844 (2002).

    Article  Google Scholar 

  5. Di Toro, G., Goldsby, D. L. & Tullis, T. E. Friction falls towards zero in quartz rock as slip velocity approaches seismic rates. Nature 427, 436–439 (2004).

    Article  Google Scholar 

  6. Han, R., Shimamoto, T., Hirose, T., Ree, J-H. & Ando, J-I. Ultralow friction of carbonate faults caused by thermal decomposition. Science 316, 878–881 (2007).

    Article  Google Scholar 

  7. Hirose, T. & Bystricky, M. Extreme dynamic weakening of faults during dehydration by coseismic shear heating. Geophys. Res. Lett. 34, L14311 (2007).

    Article  Google Scholar 

  8. Brantut, N., Schubnel, A., Rouzaud, J-N., Brunet, F. & Shimamoto, T. High-velocity frictional properties of a clay-bearing fault gouge and implications for earthquake mechanics. J. Geophys. Res. 113, B10401 (2008).

    Article  Google Scholar 

  9. Han, R., Hirose, T. & Shimamoto, T. Strong velocity weakening and powder lubrication of simulated carbonate faults at seismic slip rates. J. Geophys. Res. 115, B03412 (2010).

    Google Scholar 

  10. Reches, Z. & Lockner, D. A. Fault weakening and earthquake instability by powder lubrication. Nature 467, 452–455 (2010).

    Article  Google Scholar 

  11. De Paola, N. et al. Fault lubrication and earthquake propagation in thermally unstable rocks. Geology 39, 35–38 (2011).

    Article  Google Scholar 

  12. Chang, J. C., Lockner, D. A. & Reches, Z. Rapid acceleration leads to rapid weakening in earthquake-like laboratory experiments. Science 338, 101–105 (2012).

    Article  Google Scholar 

  13. Burnley, P. C., Green, H. W. II & Prior, D. Faulting associated with the olivine to spinel transformation in Mg2GeO4 and its implications for deep-focus earthquakes. J. Geophys. Res. 96, 425–443 (1991).

    Article  Google Scholar 

  14. Tingle, T. N., Green, H. W. II, Scholz, C. H. & Koczynski, T. A. The rheology of faults triggered by the olivine-spinel transformation in Mg2GeO4 and its implications for the mechanism of deep-focus earthquakes. J. Struct. Geol. 15, 1249–1256 (1993).

    Article  Google Scholar 

  15. Green, H. W. II & Burnley, P. C. A new self-organizing mechanism for deep-focus earthquakes. Nature 341, 733–737 (1989).

    Article  Google Scholar 

  16. Green, H. W. II & Houston, H. The mechanics of deep earthquakes. Annu. Rev. Earth Planet. Sci. 23, 169–213 (1995).

    Article  Google Scholar 

  17. Green, H. W. II Shearing instabilities accompanying high-pressure phase transformations and the mechanics of deep earthquakes. Proc. Natl Acad. Sci. USA 104, 9133–9138 (2007).

    Article  Google Scholar 

  18. Jung, H., Green, H. W. II & Dobrzhinetskaya, L. F. Intermediate-depth earthquake faulting by dehydration embrittlement with negative volume change. Nature 428, 545–549 (2004).

    Article  Google Scholar 

  19. Xia, G. Experimental studies on dehydration embrittlement of serpentinized peridotite and effect of pressure on creep of olivine. PhD thesis, Univ. California, 134 (2014)

  20. Green, H. W. II, Young, T. E., Walker, D. & Scholz, C. H. Anticrack-associated faulting at very high pressure in natural olivine. Nature 348, 720–722 (1990).

    Article  Google Scholar 

  21. Zhang, J., Green, H. W. II, Bozhilov, K. & Jin, Z-M. Faulting induced by precipitation of water at grain boundaries in hot subducting oceanic crust. Nature 428, 633–636 (2004).

    Article  Google Scholar 

  22. Green, H. W. et al. Nanometric Gouge in High-Speed Shearing Experiments: Superplasticity? Abs. #T31D-08 (Amer. Geophys. Union Fall Meeting San Francisco, 2010)

  23. Chester, F. M. & Logan, J. M. Implications for mechanical properties of brittle faults from observations of the Punchbowl Fault zone, California. PAGEOPH 124, 79–106 (1986).

    Article  Google Scholar 

  24. Chester, F. M. & Chester, J. S. Ultracataclasite structure and friction processes of the Punchbowl Fault, San Andreas system, California. Tectonophysics 295, 199–221 (1998).

    Article  Google Scholar 

  25. Chester, J. S., Chester, F. M. & Kronenberg, A. K. Fracture surface energy of the Punchbowl Fault, San Andreas system. Nature 437, 133–136 (2005).

    Article  Google Scholar 

  26. Chen, X., Madden, A. S., Bickmore, B. R. & Reches, Z. E. Dynamic weakening by nanoscale smoothing during high-velocity fault slip. Geology 41, 739–742 (2013).

    Article  Google Scholar 

  27. Green, H. W. II, Scholz, C. H., Tingle, T. N., Young, T. E. & Koczynski, T. Acoustic emissions produced by anticrack faulting during the olivine–spinel transformation. Geophys. Res. Lett. 19, 789–792 (1992).

    Article  Google Scholar 

  28. Schubnel, A. et al. Deep focus earthquake analogs recorded at high pressure and temperature in the laboratory. Science 341, 1377–1380 (2013).

    Article  Google Scholar 

  29. Rice, J. R. Heating and weakening of faults during earthquake slip. J. Geophys. Res. 111, B05311 (2006).

    Article  Google Scholar 

  30. Riggs, E. & Green, H. W. II A new class of microstructures which lead to transformation-induced faulting in magnesium germanate. J. Geophys. Res. 110, B03202 (2005).

    Article  Google Scholar 

  31. Chokshi, A. H., Mukherjee, A. K. & Langdon, T. G. Superplasticity in advanced materials. Mater. Sci. Eng. R10, 237–274 (1993).

    Article  Google Scholar 

  32. Padmanabhan, K. A. & Basariya, M. R. Mesoscopic grain boundary sliding as the rate controlling process for high strain rate superplastic deformation. Mater. Sci. Eng. A 527, 225–234 (2009).

    Article  Google Scholar 

  33. Mohamed, F. A. Deformation mechanism maps for micro-grained, ultrafine-grained, and nano-grained materials. Mater. Sci. Eng. A 528, 1431–1435 (2011).

    Article  Google Scholar 

  34. Ovid’ko, I. A. & Sheinerman, A. G. Kinetics of grain boundary sliding and rotational deformation in nanocrystalline materials. Rev. Adv. Mater. Sci. 35, 48–58 (2013).

    Google Scholar 

  35. Niemeijer, A. et al. Inferring earthquake physics and chemistry using an integrated field and laboratory approach (Review). J. Struct. Geol. 39, 2–36 (2012).

    Article  Google Scholar 

  36. Rice, C. M. et al. A Devonian auriferous hot spring system, Rhynie, Scotland. J. Geol. Soc. 152, 229–250 (2013).

    Article  Google Scholar 

  37. Meyer, C. & Hemley, J. Hydrothermal alteration of some granodiorites. Sixth National Conference On Clays and Clay Minerals 89–100 (Pergamon Press, 1959)

  38. Han, R., Hirose, T., Shimamoto, T., Lee, Y. & Ando, J. Granular nanoparticles lubricate faults during seismic slip. Geology 39, 599–602 (2011).

    Article  Google Scholar 

  39. Dominguez-Rodriguez, A., Gomez-Garcia, D., Zapata-Solvas, E., Shen, J. Z. & Chaim, R. Making ceramics ductile at low homologous temperatures. Scr. Mater. 56, 89–91 (2007).

    Article  Google Scholar 

  40. Yund, R. A., Blanpied, M. L., Tullis, T. E. & Weeks, J. D. Amorphous material in high strain experimental fault gouges. J. Geophys. Res. 95, 15589–15602 (1990).

    Article  Google Scholar 

  41. Wilson, B., Dewers, T., Reches, Z. & Brune, J. Particle size and energetics of gouge from earthquake rupture zones. Nature 434, 749–752 (2005).

    Article  Google Scholar 

  42. Brantut, N., Han, R., Shimamoto, T., Findling, N. & Schubnel, A. Fast slip with inhibited temperature rise due to mineral dehydration: Evidence from experiments on gypsum. Geology 39, 59–62 (2011).

    Article  Google Scholar 

  43. Green, H. W. II & Borch, R. S. A new molten salt cell for precision stress measurement at high pressure. Eur. J. Mineral. 1, 213–219 (1989).

    Article  Google Scholar 

  44. Dobrzhinetskaya, L. F. et al. Focused ion beam technique and transmission electron microscope studies of microdiamonds from the Saxonian Erzgebirge, Germany. Earth Planet. Sci. Lett. 210, 399–410 (2003).

    Article  Google Scholar 

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Acknowledgements

Discussions with D. Lockner and N. Beeler over several years provided important suggestions that significantly contributed to the evolving ideas now presented here. J. Zhang contributed helpful comments on experimental techniques. We also thank FEI Corporation for cutting FIB foils and for assistance with the highest-resolution scanning electron microscopy. In particular, Fig. 3d was obtained on the Magellan microscope at the FEI research facility in Portland, Oregon. F.S. acknowledges the China University of Geosciences and China Scholarship Council for a fellowship to pursue his Ph.D research at UC Riverside. Formal reviews by D. Moore and T. Tullis greatly improved the manuscript. This paper is based on work supported by the National Science Foundation under Grant #1247951 to H.W.G. II and Z.R. and #1015264 to H.W.G. II. The study was also supported by the NSF Geosciences, Equipment and Facilities, Grant No. 0732715, and partial support of NSF, Geosciences, Geophysics, Grant No. 1045414, both to Z.R.

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Contributions

H.W.G. II conceived the project, contributed the primary ideas and wrote the manuscript. F.S. conducted the specific high-pressure faulting experiment and succeeded in preserving fault contents intact (Fig. 3). K.B contributed critical SEM and TEM imaging and analysis. G.X participated in electron microscopy (Supplementary Fig. 3c) and in the hunt for critical images of the Punchbowl Fault. Z.R. conducted the high-speed experiments (Figs 1 and 2 and Supplementary Fig. 3a, b) and contributed to the development of the ideas. All authors contributed to manuscript preparation.

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Correspondence to H. W. Green II.

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Green II, H., Shi, F., Bozhilov, K. et al. Phase transformation and nanometric flow cause extreme weakening during fault slip. Nature Geosci 8, 484–489 (2015). https://doi.org/10.1038/ngeo2436

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