Rising levels of nitrogen trifluoride, used to make plasma TVs, have been found in the atmosphere.
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Prather, M. J . & Hsu, J. Geophys. Res. Lett. 35, L12810 (2008).
Weiss, R. F., Mühle, J., Salameh, P. K. & Harth, C. M. Geophys. Res. Lett. (2008) doi:10.1029/2008GL035913.
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Schiermeier, Q. Potent greenhouse gas overlooked. Nature (2008). https://doi.org/10.1038/news.2008.1189