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Thermodynamics of the Reversible Oxygenation of N,N-Ethylene bis (Salicylideneiminato) Cobalt(II) in Pyridine

Abstract

INTEREST in the reversible reaction of molecular oxygen with certain chelates of transition metals has recently grown, especially in those synthetic carriers which form one-to-one adducts1-6, because these compounds may be thought of as simple models for the reversible oxygenation of haemproteins.

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References

  1. Crumbliss, A. L., and Basolo, F., Science, 164, 1168 (1969).

    Article  CAS  Google Scholar 

  2. Amiconi, G., Brunori, M., Antonini, E., Tauzher, G., and Costa, G., Nature, 228, 549 (1970).

    Article  CAS  Google Scholar 

  3. Crumbliss, A. L., and Basolo, F., J. Amer. Chem. Soc., 92, 55 (1970).

    Article  CAS  Google Scholar 

  4. Hoffman, B. M., Diemente, D. L., and Basolo, F., J. Amer. Chem. Soc., 92, 61 (1970).

    Article  CAS  Google Scholar 

  5. Vaska, L., Chen, L. S., and Senoff, C. V., Science, 174, 587 (1971).

    Article  CAS  Google Scholar 

  6. Stynes, H. C., and Ibers, J. A., J. Amer. Chem. Soc., 89, 1559 (1972).

    Article  Google Scholar 

  7. Martell, A. E., and Calvin, M., Chemistry of Metal Chelate Compounds (Prentice-Hall, New Jersey, 1952).

    Book  Google Scholar 

  8. Floriani, C., and Calderazzo, F., J. Chem. Soc., A, 946 (1969).

  9. Costa, G., Puxeddu, A., and Nardin Stefani, L., Inorg. Nucl. Chem. Lett., 6, 191 (1970).

    Article  CAS  Google Scholar 

  10. Pfeiffer, P., Breith, E., Lubbe, E., and Tsumaki, T., Ann. Chem. Liebigs, 503, 84 (1933).

    Article  CAS  Google Scholar 

  11. Rossi Fanelli, A., and Antonini, E., Arch. Biochem. Biophys., 80, 229 (1958).

    Google Scholar 

  12. Antonini, E., and Brunori, M., Hemoglobin and Myoglobin in their Reactions with Ligands (North-Holland, Amsterdam, 1971).

    Google Scholar 

  13. Hoffman, B. M., Spilburb, C. A., and Petering, D. H., Cold Spring Harbor Symp. Quant. Biol., 36, 343 (1971).

    Article  CAS  Google Scholar 

Download references

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TAUZHER, G., AMICONI, G., ANTONINI, E. et al. Thermodynamics of the Reversible Oxygenation of N,N-Ethylene bis (Salicylideneiminato) Cobalt(II) in Pyridine. Nature New Biology 241, 222–223 (1973). https://doi.org/10.1038/newbio241222a0

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