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True performance metrics in beyond-intercalation batteries

Beyond-intercalation batteries promise a step-change in energy storage compared to intercalation-based lithium-ion and sodium-ion batteries. However, only performance metrics that include all cell components and operation parameters can tell whether a true advance over intercalation batteries has been achieved.

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Figure 1: Capacities with respect to the formal storage material and the super-host structure.
Figure 2: True electrode capacity with limited-capacity cycling.


  1. Larcher, D. & Tarascon, J.-M. Nat. Chem. 7, 19–29 (2014).

    Article  Google Scholar 

  2. Choi, J. W. & Aurbach, D. Nat. Rev. Mater. 1, 16013 (2016).

    Article  Google Scholar 

  3. Whittingham, M. S. Chem. Rev. 114, 11414–11443 (2014).

    Article  Google Scholar 

  4. Obrovac, M. N. & Chevrier, V. L. Chem. Rev. 114, 11444–11502 (2014).

    Article  Google Scholar 

  5. Chevrier, V. L. & Ceder, G. J. Electrochem. Soc. 158, A1011–A1014 (2011).

    Article  Google Scholar 

  6. Beaulieu, L. Y., Eberman, K. W., Turner, R. L., Krause, L. J. & Dahn, J. R. Electrochem. Solid State Lett. 4, A137–A140 (2001).

    Article  Google Scholar 

  7. Cabana, J., Monconduit, L., Larcher, D. & Palacín, M. R. Adv. Mater. 22, E170–E192 (2010).

    Article  Google Scholar 

  8. Yabuuchi, N. et al. ChemElectroChem 1, 580–589 (2014).

    Article  Google Scholar 

  9. Sun, Y., Liu, N. & Cui, Y. Nat. Energy 1, 16071 (2016).

    Article  Google Scholar 

  10. Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J.-M. Nat. Mater. 11, 19–29 (2012).

    Article  Google Scholar 

  11. Luntz, A. C. & McCloskey, B. D. Chem. Rev. 114, 11721–11750 (2014).

    Article  Google Scholar 

  12. Pang, Q., Liang, X., Kwok, C. Y. & Nazar, L. F. Nat. Energy 1, 16132 (2016).

    Article  Google Scholar 

  13. Aurbach, D., McCloskey, B. D., Nazar, L. F. & Bruce, P. G. Nat. Energy 1, 16128 (2016).

    Article  Google Scholar 

  14. Gogotsi, Y. & Simon, P. Science 334, 917–918 (2011).

    Article  Google Scholar 

  15. Liu, T. et al. Science 350, 530–533 (2015).

    Article  Google Scholar 

  16. Oh, S. H., Black, R., Pomerantseva, E., Lee, J.-H. & Nazar, L. F. Nat. Chem. 4, 1004–1010 (2012).

    Article  Google Scholar 

  17. McCloskey, B. D. J. Phys. Chem. Lett. 6, 4581–4588 (2015).

    Article  Google Scholar 

  18. Eroglu, D., Zavadil, K. R. & Gallagher, K. G. J. Electrochem. Soc. 162, A982–A990 (2015).

    Article  Google Scholar 

  19. Clément, R. J., Bruce, P. G. & Grey, C. P. J. Electrochem. Soc. 162, A2589–A2604 (2015).

    Article  Google Scholar 

  20. Chan, M. K. Y., Wolverton, C. & Greeley, J. P. J. Am. Chem. Soc. 134, 14362–14374 (2012).

    Article  Google Scholar 

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Correspondence to Stefan A. Freunberger.

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Freunberger, S. True performance metrics in beyond-intercalation batteries. Nat Energy 2, 17091 (2017).

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