Kimberlites are a volumetrically minor component of the Earth’s volcanic record, but are very important as the major commercial source of diamonds and as the deepest samples of the Earth’s mantle. They were predominantly emplaced from ≈2,100 Ma to ≈10 ka ago, into ancient, stable regions of continental crust (cratons), but are also known from continental rifts and mobile belts. Kimberlites have been reported from almost all major cratons on all continents except for Antarctica. Here we report the first bona fide Antarctic kimberlite occurrence, from the northern Prince Charles Mountains, emplaced during the reactivation of the Lambert Graben associated with rifting of India from Australia-Antarctica. The samples are texturally, mineralogically and geochemically typical of Group I kimberlites from more classical localities. Their ≈120 Ma ages overlap with those of many kimberlites from other world-wide localities, extending a vast Cretaceous, Gondwanan kimberlite province, for the first time, into Antarctica.
Kimberlites are rare, highly silica-undersaturated, mantle-derived igneous rocks, which have been emplaced into the crust, particularly in ancient and geologically stable cratons. Their trace element enrichments, small volumes, low silica but highly magnesian and volatile (C–H–O)-rich character argue that they represent melt compositions formed in the presence of H2O and CO2, very close to the carbonate–peridotite solidus1,2,3. The occasional but scientifically and commercially highly significant presence of diamonds suggests that they originated by partial melting of the mantle at extreme depths (>150 km), and some kimberlites (that is, those transporting diamonds with inclusions representing rare transition zone and lower mantle mineral phases) are the most deeply derived materials accessible on Earth. Kimberlites were emplaced over a significant period of geological history, ranging in age from the Palaeoproterozoic to the Cenozoic Eras, and have been reported on all continents except Antarctica4,5.
Here we present mineralogical and geochemical data from three new kimberlite samples obtained from the southeastern slopes of Mt Meredith in the northern Prince Charles Mountains (nPCM) of Antarctica. These rocks represent the first reported occurrence of genuine kimberlite in Antarctica.
Sample locations and petrography and mineralogy
The location from which the samples were recovered is shown in Fig. 1. One sample (77063) was obtained in situ from an outcrop, and the others (77081 and 77082) were recovered from boulders in till several metres from the outcrop. The three samples are classified as Group I kimberlites on the basis of petrography and mineral chemistry. They are strongly porphyritic with rounded to euhedral olivine crystals up to several millimetres across and rare phlogopite macrocrysts in a very fine-grained groundmass. Olivine crystals are partially replaced by serpentine on rims and along fractures (Fig. 2a, b), but all samples retain abundant fresh olivine. Most olivine crystals are rounded to euhedral in shape and up to 200 μm across. Others are larger (>1 mm across) and irregular in shape, and sometimes contain inclusions of phlogopite, orthopyroxene, Cr-diopside-rich clinopyroxene, perovskite and Cr-spinel (Fig. 2c). Olivine crystals vary significantly in major and minor element compositions (from Fo74 to Fo91; 0.02–0.45 wt% NiO and 0.10–0.50 wt% CaO). In some cases, they are interpreted as xenocrysts of lithospheric material rather than as phenocrysts. For example, one large olivine crystal has an embayed and resorbed core of Fo90.5 olivine overgrown by a thin rim of Fo88 olivine. The core contains separate inclusions of Cr- and Na-rich clinopyroxene as well as low Al and Ca orthopyroxene, which are compositionally similar to peridotitic phases from the upper mantle. Phlogopite macrocrysts can be up to several millimetres in length and are irregular to tabular in shape. Phlogopite Mg# [100*Mg/(Mg+∑Fe)] varies from 87.3 to 93.4. Representative mineral compositions are presented in Table 1
The fine-grained groundmass is mainly composed of calcite, olivine, phlogopite, magnesiochromite, Ti-magnetite, perovskite and apatite (Fig. 2c). Spinel exhibits distinctive atoll structures, in which euhedral cores of compositionally zoned magnesiochromite are surrounded by concentrically arranged zones of silicate material, which are in turn surrounded by magnetite. Very similar atoll spinels have been reported in other kimberlites6. Perovskite crystals are up to 100 μm across and perfectly octahedral (Fig. 2c). They formed in the groundmass and are also included in some olivine rims. Abundant anhedral calcite crystallized interstitially to other groundmass phases and makes up 10–12 modal% of the rocks. The association of xenocrystic and phenocrystic olivine and phlogopite macrocrysts set in a matrix containing perovskite, spinel, apatite and carbonate is a distinctive feature of kimberlites4,7. Notably, clinopyroxene does not occur as phenocrysts nor in the groundmass, precluding classification of these samples as ultramafic lamprophyres (UML)8, examples of which have been reported from other localities in the nPCM region9,10,11,12.
Whole rock geochemistry
The rocks are ultrabasic (29.2 to 32.1 wt% SiO2) and have high MgO (19.1–27.3 wt%), CaO (10.9–28.8 wt%), CaO/Al2O3 (2.7–2.9) and CO2 (5.3–9.0 wt%), but low Al2O3 contents (3.8–6.5 wt%), reflecting the observed olivine- and calcite-rich mineralogy. Large ranges in K2O (1.3–2.8 wt%) and P2O5 (0.59–0.89 wt%) contents mainly reflect varying modal abundances of phlogopite and apatite, respectively. Na2O contents are very low (<0.15 wt%). On a plot of bulk SiO2/MgO versus MgO/CaO (Fig. 3a), the samples lie within a field of representative kimberlites6. Mesozoic UML from nearby Beaver Lake12 have higher SiO2/MgO values (≥2) and are mostly outside the kimberlite field.
Incompatible trace element concentrations tend to be high (generally >100 × Primitive Mantle13 or more). For example, Rare Earth Element (REE) patterns are strongly light REE-enriched ([La/Yb]n=74–136), similar to kimberlites from other continents. K, Pb, Zr, Hf and Ti are depleted relative to trace elements of similar incompatibility (La, Ce, Sm, Eu and Gd) (Fig. 3b). The abundances of all measured incompatible trace elements and the general form of the Primitive Mantle normalized patterns match very closely kimberlites from other world-wide localities (Fig. 3b). Full whole rock analyses for the current samples are reported in Table 2.
Radiometric ages of the samples
Perovskite U–Pb dating by the laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) method yielded apparent ages of 113±13 Ma (2σ) (77063), 125±8 Ma (77081) and 121±13 Ma (77082, see Methods section U–Pb LA-ICP-MS dating of perovskite). Assuming the perovskites are coeval, we obtain a weighted age of 122±6 Ma. This is supported by a 117±1 Ma Rb–Sr age for phlogopite from 77063 (Table 4). On the basis of these ages, it is likely that that samples 77081 and 77082, from boulders within till are related in terms of age, to the kimberlite from which 77063 was sampled. An origin from the same kimberlite pipe, however, is unlikely given the diversity in initial Sr, Nd, Hf and Pb isotope ratios (87Sr/86Sr 0.7042−0.7054, εNd +1.9 to −2.1, εHf +4.6 to −5.5, 206Pb/204Pb 18.04−18.42, see Tables 3, 4, 5). The bulk rock 87Sr/86Sr for 77063 (0.7054±1) is supported by in situ Sr isotope data for perovskite (0.70539±12, see Supplementary Fig. S1). These radiogenic isotope signatures are intermediate between those established for Group I and transitional kimberlites from southern Africa14.
Ultramafic–mafic alkaline, carbonatitic and kimberlite-like rocks of similar age have been reported from elsewhere in the nPCM region, including Else Platform, Radok Lake and on the Fischer Massif, adjacent to the Lambert rift9,10,15. These rocks were classified as UML (alnöites), alkaline picrites, ultrabasic foidites, trachybasalts and carbonatite–kimberlites. In particular, Egorov et al.16 reported the ‘first Antarctic occurrence of a dike kimberlite’ in the nPCM, inferred to be Early Cretaceous in age. However, samples from this dyke are significantly different from the current samples in that olivine macrocrysts (containing mantle-derived clinopyroxene and orthopyroxene inclusions – Fig. 2d), garnet xenocrysts, ilmenite and perovskite are not reported. However, globular ‘syngenetic calcite carbonatite schlieren’ were present. In addition, the dyke is compositionally outside the range for kimberlites with low MgO (17 wt%) and Ni (480 ppm), reflecting the low modal olivine. We argue that this dyke is not a bona fide kimberlite, but more akin to a carbonatite magma that fractionated into a calcite-rich component and an apatite+magnetite+olivine component.
The bona fide kimberlites described here and the other nPCM ultrabasic rock correlates appear to define a N–S linear feature extending 150 km along the margin of the Lambert rift (Fig. 1b). Interestingly, the UML occur in the northern part of the region (mainly around Beaver Lake)9,10,11,12, whereas the current kimberlites and the carbonatite–kimberlite reported by Belyatsky et al.15 occur in the southern part. This may reflect progressive stages of development of the Lambert rift, with the UML representing a greater extent of rifting in the north, more erosion of the base of the lithosphere leading to melting at shallower subcontinental lithospheric levels, relative to the kimberlites in the south. Similar models have been suggested in the Ailik Bay rift17, and in the currently active rift in the western branch of the East African Rift system18.
Kimberlites and related alkaline igneous rocks occur in all major Gondwanan continents (Africa, India, South America and Australia), but have not previously been reported from Antarctica. Kimberlite emplacement ages show well-developed clustering throughout the Mesoproterozoic, early Paleozoic, Mesozoic and Cenozoic5. In the Mesozoic, major emplacement events occurred 240, 145, 120, 85 and 73 Ma ago. The ca. 120 Ma episode was distributed particularly widely across the Gondwanan continents, and discovery of 120 Ma kimberlites in East Antarctica further extends this vast Cretaceous kimberlite province (Fig. 1a).
At 120 Ma India and amalgamated Antarctica-Australia had already begun to drift apart, with early sea-floor spreading forming the proto-Indian Ocean19. The graben, on the margin of which the current kimberlites were emplaced, is a 700 km long zone of thinned continental crust believed to represent either a failed, trans-tensional basin that was activated 120 Ma ago during early extension associated with break-up of India and Antarctica-Australia20,21, or an accommodation zone related to a Carboniferous-Permian intracontinental rift between India and Antarctica, which was reactivated in the Cretaceous during continental dispersion22. Whichever the case, the nPCM kimberlites (and related alkali rocks of similar age at nearby locations10,12,15 – Fig. 1) are most likely a magmatic expression of reactivation of pre-existing lithospheric discontinuities associated with the Lambert Graben during opening of the proto-Indian ocean. Kent23 reported orangeites of age 109–116 Ma peripheral to the Bay of Bengal, India (Damodar Valley), which may relate to the same Cretaceous kimberlite province. Jelsma et al.5 have shown that the time intervals in which kimberlite emplacement events were concentrated, coincided with fundamental plate reorganizations, such as supercontinent break-up. Thus, as well as constituting the first-known bona fide Antarctic kimberlite occurrence, the location of the nPCM kimberlites is consistent with models relating kimberlite distribution to reactivation of major trans-lithospheric structures during continental scale tectonic events5, and likely marks the onset of the reactivation of continental rifting zones, that is, similar to suggestions for other rift-related continental mantle-derived magmas such as carbonatites, UML and kamafugites (this study and refs 17, 18). Thus, the Antarctic kimberlites and previously reported UML as well as other alkaline volcanics in the nPCM region potentially provide rare insights into large-scale tectonic mantle processes during the Cretaceous.
Constituent mineral phases in the samples were analysed for major and minor elements using a Cameca SX-50 WDS electronprobe microanalyser at Macquarie University. The accelerating voltage was 15 kV and beam current was 20 nA. Count times varied from 20 s on major elements to 60 s on minor elements. Calibration was performed on natural mineral standards. Representative data is presented in Table 1.
X-ray fluorescence analysis
Whole rock major and minor element abundances were determined on powdered samples using X-ray fluorescence (XRF) microscopy, at Macquarie University (Table 2).
Solution – ICP-MS analysis
Trace element abundances in the chilled margins were measured by solution – ICP-MS at the Australian National University (ANU) following procedures similar to those described by Norman et al.24 (Table 2).
Rb–Sr and Sm–Nd isotope analyses were performed on leachate–residue pairs. Sample 77063 (105 mg, fine crush) was leached with cold 2M HCl (12 h), whereas rock powders for 77081A and 77082A were leached with cold 6M HCl. After removal of the clear solution, the residues were dried and re-weighed to determine weight loss during acid leaching. The residues were dissolved at low pressure using HF/HNO3 and HCl. Following preliminary semi-quantitative trace element analysis, all fractions were spiked with 85Rb–84Sr and 149Sm–150Nd tracers, followed by extraction of Rb, Sr and LREE using conventional cation exchange and EICHROM Sr and LN resins25. Total analytical blanks (<0.1 ng) were negligible. Isotopic analyses were carried out on a NU Plasma multi-collector ICP-MS coupled to a CETAC Aridus desolvator. As part of an online iterative spike removal/mass bias correction procedure, instrumental mass bias was corrected by internal normalization to 88Sr/86Sr=8.37521 and 146Nd/145Nd=2.0719425 (equivalent to 146Nd/144Nd=0.7219 (ref. 26)); data are reported relative to SRM987=0.710230 and La Jolla Nd=0.511860. Typical in-run precisions (two standard errors) are ±0.000020 (Sr) and ≤±0.000010 (Nd), whereas external (2σ) precisions – based on rock standards – are ±0.000020 (Nd) and ±0.000040 (Sr). External precision (2σ) for 87Rb/86Sr and 147Sm/144Nd is ±0.5% and ±0.2%, respectively. 147Sm/144Nd and 143Nd/144Nd in modern CHUR is 0.1967 and 0.512638. Initial 87Sr/86Sr(t) and εNd(t) were calculated for t=120 Ma. Results for standards (±2 s.d.) are as follows: BCR-2 (n=2); Rb 46.8 ppm, Sr 339 ppm, 87Rb/86Sr 0.400, 87Sr/86Sr 0.70502, Sm 6.48 ppm, Nd 28.32 ppm, 147Sm/144Nd 0.1382, 143Nd/144Nd 0.512629; 0.512640±17 (mean of 21 runs of BCR-2 in 2010), 0.705015±34 (mean of 8 runs of BCR-2 in 2010–2011: JNd-1; 0.512114±23 (mean of 9 runs in 2010); BHVO-2 0.512992±17 (mean of 6 runs in 2010). Results are consistent with Thermal Ionisation Mass Spectrometry (TIMS) reference values. Uncertainties in initial ratios are: 87Sr/86Sr ±0.00010; εNd ±0.5 units. The decay constants are: 87Rb 1.42 10−11/yr, 147Sm 6.54 10−12/yr.
Rb–Sr dating of megacrystic phlogopite from sample 77063 was done on euhedral (1–3 mm) mineral flakes. Two handpicked fractions (2–4 mg) were cleaned in 0.1M HNO3, spiked with 87Rb–84Sr tracer and dissolved on a hotplate. Sr was extracted and purified using two passes over a small (0.1 ml) column of EICHROM Sr-resin (50–100 μm). Rb was extracted using cation resin chromatography (4 ml of AG50-X8, 200–400 mesh). Sr isotope data were measured as described above, whereas Rb isotope dilution analyses were done using the Zr-doping method28. Rb–Sr mica ages were derived by combining each phlogopite analysis with the Rb–Sr data for 77063L and R; calculations were done in ISOPLOT29. External precision (2 s.d.) for 87Rb/86Sr is 0.5%, and for 87Sr/86Sr is 0.01%. 87Sr/86Sr is reported relative to SRM987=0.710230. Rb–Sr model ages (±2 s.d.) for glauconite standard GLO-1 (89.3±0.8 Ma, n=16 over 7 years, assumed initial 87Sr/86Sr 0.7074) and SRM607 feldspar (1424±7 Ma, n=11 over 7 years, assumed initial 87Sr/86Sr 0.705) obtained using the same spike and techniques as those used for the phlogopites are consistent with Ar-Ar reference ages. Biotite GA1550 from Mount Dromedary (SE Australia) yields a Rb–Sr isochron age of 98.0±0.3 Ma (n=9, 0.70445±6, MSWD (mean square weighted deviation) 1.6), consistent with Ar–Ar ages of 98.5±0.8 Ma32 and 98.8±0.5 Ma33. Results are given in Table 4.
Semiquantitative trace element data for leachate–residue pairs (see above) indicate that most of the Hf resides in the residue (>90%), whereas Lu favours the leachates, consistent with their mineralogy and Bizimis et al.34. Overall, Lu–Hf budgets are dominated by the residue. Lu–Hf isotope analyses were therefore done on unleached whole rock powders. After dissolution at high pressure, a ~90% split of the solutions was spiked with a 176Lu–180Hf tracer. Lu and Hf were isolated using a single-column technique35 and measured by Multi-Collector-ICP-MS. The smaller split was equilibrated with a 233U–205Pb tracer, followed by extraction of Pb and U on small columns of AG1-X8 (100–200 mesh, HBr-HCl) and EICHROM TRU resin (100–150 μm), respectively. Pb and U isotope ratios were measured by MC-ICP-MS25. Isotope dilution calculations for U–Pb were done with the EarthTime Excel U–Pb data reduction module36. 176Hf/177Hf was normalized to 179Hf/177Hf=0.7325 and reported relative to JMC475=0.282160. Internal precision (2se) for 176Hf/177Hf is ≤±0.000008, external precision ±0.000015 (2 s.d.). External precision for 176Lu/177Hf is ±1%. USGS standards BCR-2 and BHVO-2, analysed together with the kimberlite samples, yielded the following results: BCR-2, 0.50 ppm Lu, 4.94 ppm, 176Lu/177Hf 0.01439, 176Hf/177Hf 0.282868, 0.282875 and 0.282883; BHVO-2, 0.274 ppm Lu, 4.45 ppm Hf, 176Lu/177Hf 0.00877 and 176Hf/177Hf 0.283104. Modern CHUR has 176Lu/177Hf = 0.0332 and 176Hf/177Hf = 0.282772. The decay constant for 176Lu is 1.865 10−11/year. Mass bias during U and Pb runs was corrected using internal normalisation to the natural U ratio and standard bracketing, respectively. External precision for 238U/204Pb is ±1% (2 s.d.). 232Th/204Pb was derived from 238U/204Pb measured by isotope dilution and Th/U from quadrupole ICP-MS trace element data on different splits of the same powders; expected errors ±10%. External precision for Pb isotope data is ≈±0.1−0.2% (2s.d.); data reported are corrected for mass bias and blank (20±10 pg Pb). Uncertainties for calculated initial Pb isotope ratios, obtained by Monte Carlo simulation with the stated analytical uncertainties and an assumed age uncertainty of ±5 Ma: 206Pb/204Pb ±0.02, 207Pb/204Pb ±0.01, 208Pb/204Pb ≤±0.17. The decay constants are: 238U 0.155125 × 10−9/year, 235U 0.98485 × 10−9/year and 232Th 0.049485 × 10−9/year. Lu-Hf and U-Pb isotope results are given in Table 5.
U–Pb LA-ICP-MS dating of perovskite
U–Pb dating work on perovskite was performed during two analytical sessions: the first was done on polished grains in situ in blocks of fresh kimberlite samples 77063, 77081 and 77082; the second analytical session on the sample 77063 was performed on separated perovskite grains mounted in an epoxy block.
The U–Pb analyses were performed at Macquarie University using a NewWave UP-213 laser ablation microprobe attached to an Agilent 7700 ICP-MS. The analytical technique was described in ref. 37. Ablation occurs in He, permitting efficient sample transport, signal stability and reproducibility of U/Pb fractionation. The spot size varied between 30 μm for perovskite from the polished blocks and 40 μm for separated grains. Because of the smaller spot sizes used on the grains from the polished blocks, the analytical uncertainties are much higher for these grains.
Samples were analysed in runs of 16 analyses comprising 12 analyses of unknowns bracketed by two analyses of a standard zircon (GEMOC GJ1, age 609 Ma) at the beginning and end of each run. The ‘unknowns’ include two near-concordant reference zircons, 91500 (ref. 38) and Mud Tank39, which are analysed before the samples and are used as independent control on reproducibility and instrument stability.
The major problem of the U–Pb analysis of perovskite is the presence of high contents of common Pb. Instead of applying a common-Pb correction, we have used a regression technique, treating population of analyses from a single sample as representing mixtures between the common-Pb and radiogenic-Pb components. The intercepts of the regression line through the raw data on an inverse-Concordia (Tera-Wasserburg) plot thus provide both an estimate of the 207Pb/206Pb of the common-Pb component (upper intercept) and the inferred crystallization age (lower intercept).
A total of 40 perovskites from sample 77063 were analysed during two sessions in April and June 2010. After rejection of 12 analyses with the largest analytical errors, the lower intercept of the regression line through the rest of the data (n=28) gave an age of 113±13 Ma, which we consider as the best estimate for the crystallization age of this kimberlite (Supplementary Fig. S1).
Only 12 perovskites were found and analysed from sample 77081. These produce a high MSWD of 2.7 due to a scatter about the regression line. The rejection of four analyses had reduced this scatter (MSWD=0.63), giving the lower intercept age at 125±8 Ma and the best estimate for the crystallization age for this sample (Supplementary Fig. S2).
Sixteen out of 17 analyses done for sample 77082 produced a lower intercept age of 121±13 Ma, interpreted as crystallization age for this sample (Supplementary Fig. S3).
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G.T.N. thanks R.F. Flint and ANARE expeditioners for assistance during the summers of 1987–88, 1988–89 and 1989–90. C. Lawson and N. Pearson (Macquarie University) provided XRF analyses and electron microprobe time, respectively. We acknowledge funding from the Australian Research Council (V.S.K. and G.M.Y.), the University of Tasmania (V.S.K.) and a Marie Curie International Incoming Fellowship (302637) to A.R. This is contribution 312 from the ARC Centre of Excellence for Core to Crust Fluid Systems ( http://www/ccfs/mq/.edu.au) and 878 in the GEMOC Key Centre ( http://www.gemoc.mq.edu.au).
The authors declare no competing financial interests.
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Yaxley, G., Kamenetsky, V., Nichols, G. et al. The discovery of kimberlites in Antarctica extends the vast Gondwanan Cretaceous province. Nat Commun 4, 2921 (2013). https://doi.org/10.1038/ncomms3921
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