Article | Open | Published:

Quasiparticles and Fermi liquid behaviour in an organic metal

Nature Communications volume 3, Article number: 1089 (2012) | Download Citation

Abstract

Many organic metals display exotic properties such as superconductivity, spin-charge separation and so on and have been described as quasi-one-dimensional Luttinger liquids. However, a genuine Fermi liquid behaviour with quasiparticles and Fermi surfaces have not been reported to date for any organic metal. Here, we report the experimental Fermi surface and band structure of an organic metal (BEDT-TTF)3Br(pBIB) obtained using angle-resolved photoelectron spectroscopy, and show its consistency with first-principles band structure calculations. Our results reveal a quasiparticle renormalization at low energy scales (effective mass m*=1.9 me) and ω2 dependence of the imaginary part of the self energy, limited by a kink at ~50 meV arising from coupling to molecular vibrations. The study unambiguously proves that (BEDT-TTF)3Br(pBIB) is a quasi-2D organic Fermi liquid with a Fermi surface consistent with Shubnikov-de Haas results.

Introduction

Organic metals have an increasingly important role in safe and sustainable applications, ranging from stretchable electronics and photovoltaics to bio-integrated devices1,2. However, in spite of their discovery nearly 40 years ago3, it has not yet been possible to quantify the energy(ω) and momentum(k)-resolved band dispersions and Fermi surfaces of any organic metal in terms of a genuine Fermi liquid4. In contrast, some organic metals possessing quasi-one-dimensional (1D) structure are classified as Luttinger liquids, with missing quasiparticles and a power-law density of states that forbid Fermi surface determination5,6,7,8. Quasi-2D metals bridge the Fermi–Luttinger paradigms and embody novel concepts such as marginal Fermi liquids9 and spin-charge stripes10, but angle-integrated measurements for 2D organic metals have instead suggested Luttinger liquid character11,12,13. Organic materials indeed display a fascinating range of properties14,15,16 including superconductivity, spin- and charge-density waves, photo-induced phase transitions, magnetism and so on. The electronic properties of these materials are derived from the electronic structure near the Fermi level (EF), but it is surprising that it has not yet been possible to describe the spectral function A(k,ω) of any organic metal in terms of basic Fermi liquid behaviour. Angle-resolved photoelectron spectroscopy (ARPES) can directly provide the spectral function A(k,ω) modulo matrix element effects17. However, ARPES studies of organic metals have been reported only for quasi-1D systems and indicate a Luttinger liquid picture in the absence of quasiparticles, as exemplified by studies on the Bechgaard salts5, TTF-TCNQ6,7,8 and so on. (TTF, tetrathiafulvalene; TCNQ, 7,7,8,8-tetracyanoquinodimethane) Earlier attempts to measure A(k,ω) of quasi-2D organic metals have not succeeded to measure quasiparticle bands dispersing across the Fermi level (EF). On the other hand, angle-integrated studies11,12,13 of quasi-2D organic metals have always reported a power law dependence of the density of states, suggestive of Luttinger liquid behaviour like in the quasi-1D organic metals. For example, studies on (BEDT-TTF)2X salts (BEDT-TTF, bis(ethylenedithio)tetrathiafulvalene) reported absence of a Fermi edge and this was attributed to strong correlations12,13, whereas one study also discussed phonon excitations as a possible origin of the behaviour11.

Most of the BEDT-TTF-based two-dimensional organic materials are 2:1 salts of the formula (BEDT-TTF)2X, with a structure of alternating BEDT-TTF and anion X layers14,15,16. The formal charge of BEDT-TTF is +1/2 in these systems and the conduction band is quarter-filled. If the structure results in a dimerization, as in the β- and κ-phase salts (with two dimers of BEDT-TTF molecules in a unit cell), the electron configuration leads to an 'effectively' half-filled strongly correlated electron system. These effects make organic materials very interesting and indeed, realizations include Mott insulators and superconductivity, as well as specific details such as pseudogap behaviour, a mid-infrared feature and electronic transport properties quite like the strongly correlated layered copper oxide superconductors18. Consequently, exotic phases can indeed be realized owing to choice of the anion, amount of band filling and the role of correlations, and extensive work has focused on the quasi-2D (BEDT-TTF)2X series of compounds14,15,16,19,20. Most importantly, Shubnikov-de Haas (SdH) quantum oscillations have identified a closed Fermi surface for some BEDT-TTF-based systems21. This indicates a contradiction because the angle-integrated photoemission spectroscopy (PES) studies concluded a Luttinger liquid behaviour in the absence of a Fermi edge11,12,13.

In this work, we study the electronic structure of a quasi-2D compound (BEDT-TTF)3Br(pBIB) (pBIB, p-bis(iodoethynyl)benzene), which can be considered to be a good metal in terms of electrical resistivity ρ (T=4 K) ~100 μ Ωcm. The formal charge of the donor is not +1/2 but +1/3 and the crystal structure consists of the a,c lattice parameters being nearly equal (a=10.187 Å, c=9.418 Å) and a substantially larger b lattice parameter (b=15.420 Å). The crystal structure is shown in Fig. 1a and it satisfies a lattice matching between the BEDT-TTF layer and the infinite anionic chain made of pBIBs and bromide ions without a dimerization of the BEDT-TTF molecules. Electronic structure calculations indicate a quasi-2D behaviour22 and indeed, a quasi-2D-closed Fermi surface has been confirmed by cyclotron resonance and SdH oscillations21, as well as angular-dependent magneto-resistance oscillations23,24 at T=1.4 K. In the following, we present PES as well as ARPES studies of the electronic structure of (BEDT-TTF)3Br(pBIB). The experimental geometry is shown in Fig. 1b. Also, in spite of its large unit cell with a volume of 1,371.5 Å3, it was possible to carry out reliable first-principles band structure calculations. The ARPES results reveal band dispersions and the experimental Fermi surface, consistent with first-principles band structure calculations. The highest occupied molecular orbital (HOMO) electrons have S 3p character and undergo band renormalization consistent with SdH results. Laser ARPES results indicate Fermi liquid behaviour, with a kink at ~50 meV arising from coupling to molecular vibrations.

Figure 1: Crystal structure and experimental geometry.
Figure 1

(a) Crystal structure of (BEDT-TTF)3Br(pBIB). (b) Schematic diagram of experimental geometry showing the orientation of the incident Laser and He Iα sources with respect to the detector. The analyser slit is parallel to c*, where c* is the reciprocal lattice vector of c axis of (BEDT-TTF)3Br(pBIB)22.

Results

Valence band measurements and first-principles calculations

Figure 2a shows the wide-energy angle-integrated valence band spectrum of (BEDT-TTF)3Br(pBIB) obtained at 4 K using He Iα photons (21.218 eV) compared with the density of states obtained from first-principles band structure calculations. The features labelled A–I in the experimental spectra show a one–one correspondence with features A′–I′ in the calculated spectra, although small discrepancies can be seen in the features. The spectrum plotted on a magnified y-scale (×10) shows a clear Fermi edge. Figure 2b shows the near EF spectrum obtained at T=4 K using a laser source (6.994 eV)25 and a high-energy resolution (14 meV), confirming a clear Fermi edge. The states at and near the Fermi level constituting the HOMO have S 3p character, as obtained from band structure calculations. As discussed in the introduction, a Fermi edge in a quasi-2D organic metal has not been observed in earlier studies. In the following, we investigate band dispersions and the Fermi surface responsible for the metallicity.

Figure 2: Angle-integrated results and first-principles calculations.
Figure 2

Angle-integrated photoemission spectra of (BEDT-TTF)3Br(pBIB) measured at 4 K using the photon source of (a) He Iα (bold line), plotted along with first-principles band structure calculations broadened by convolving with a Gaussian corresponding to the experimental energy resolution (thin line). Labels A–I and A′–I′ mark features in the experimental spectrum and first-principles band calculations, respectively. (b) The laser-PES data measured for (BEDT-TTF)3Br(pBIB) up to a binding energy of 1 eV below the Fermi level (solid line). Inset shows the spectrum near EF indicating the existence of a metallic Fermi edge (circle), which can be well reproduced by a Fermi–Dirac function convolved with a Gaussian corresponding to the experimental energy resolution (broken line).

Angle-resolved band maps and Fermi surface

Figure 3 shows ARPES spectra at 4 K along Γ–Z high-symmetry line using (a) He Iα and (b) laser photon source. The calculated band dispersions are overlaid as lines on the experimental band maps. The experimentally determined band dispersions are also overlaid as symbols for the He Iα measurements (red circles) and for the laser measurements (blue circles). Although the overall behaviour is quite consistent with the calculated band dispersions, small but finite deviations can be observed in the experimental band structure. However, the deviations do not depend on the photon energy and although the difference in incident photon energies is significantly large, the energy- and momentum-distribution curves (EDCs and MDCs) show very similar behaviour. Moreover, the EF crossing occurs at exactly the same Fermi momentum (kF=0.27±0.005 Å−1) as seen from the MDCs at EF plotted in Fig. 3c. This also confirms that the electronic structure is quasi-2D and there is negligible dispersion perpendicular to the conducting ac-plane. From angle-dependent measurements using He Iα, we have mapped the Fermi surface in the a*c*-plane. The experimental Fermi surface is plotted in Fig. 3d along with the calculated Fermi surface22. While the calculated Fermi surface is elliptical, it is difficult to determine whether the experimental Fermi surface is elliptical or circular because of the low angular resolution perpendicular to Γ–Z direction. However, the observed Fermi surface crossing is consistent with SdH results21,23,24 which indicated a circular Fermi surface with kF=0.27 Å−1. The estimated cross-sectional area is 47% of the first Brillouin zone in ARPES, whereas it was estimated to be ~51% from the SdH results. Although inter- and intra-molecular band dispersions were recently reported for an insulating sexiphenyl film using ARPES26, the present result constitutes the only case of an experimentally measured k-resolved Fermi surface of an organic metal.

Figure 3: Angle-resolved band map and Fermi surface.
Figure 3

ARPES band dispersion map as a function of binding energy and momentum. Maps obtained using (a) He Iα and (b) Laser. The experimentally determined band dispersions are overlaid as symbols for He Iα (red circles) and for the laser (blue circles). Solid lines are the result of first-principles band calculations. (c) MDC at EF obtained from the He Iα ARPES map shown in panel (a), plotted as a red line, and from the laser-ARPES map of panel (b), plotted as a blue line. Both MDCs show the same kF, confirming quasi-2D behaviour (d) Fermi surface mapping using He Iα photon source. Light blue lines are the Brillouin zone and the Fermi surface calculated by a tight binding method22. Green broken line is the Fermi surface obtained from ARPES measurements.

EDCs, MDCs and self energy of quasiparticles

Figure 4a,b shows the EDCs and MDCs obtained from the laser ARPES band map of Fig. 3b, respectively. While the EDCs do not show a clear dispersive quasiparticle peak, the MDCs show a clear peak structure as a function of momentum. From a careful comparison of the experimental data with a parabolic band (Fig. 4c), we could identify a weak kink structure and were able to quantify the real (Re) and imaginary (Im) parts of the self energy (Σ). The results of such an analysis are shown in Fig. 4d. The Re Σ shows a peak structure centred at 40~50 meV associated with the kink structure observed in Fig. 4c. In addition, the Im Σ shows a clear ω2 dependence (dotted line). It is noted that the ω2 dependence is theoretically well known for a 3D metal with electron–electron correlations, whereas for a 2D metal with electron–electron correlations, the expected behaviour is Im Σ ω2{1+βln(ω/EF)} and for a 2D electron–phonon coupled system it is known to show an ω2 dependence due to many body effects27. As our ARPES studies as well as earlier SdH results indicate a quasi 2D electronic structure, we need to address the importance of electron–phonon coupling in (BEDT-TTF)3Br(pBIB). To do so, we note that the ω2 dependence occurs up to an energy scale of the kink structure. The kink structure arises from coupling of electrons to a bosonic mode, which could be phononic, magnetic and so on17. We could estimate the electron–boson dimensionless coupling parameter λ=0.9 from the experimental data using standard procedures17. The estimated effective mass for the carriers is m*=1.9 me, whereas the SdH results indicated an effective mass (m*=2.0 me), indicating very good agreement between the two techniques.

Figure 4: Band dispersion and the self energy of quasiparticles.
Figure 4

(a) Normalized EDCs obtained from the laser ARPES band map of Fig. 3b showing a weak but definite quasiparticle band crossing (red curve). (b) MDCs obtained from the laser ARPES band map of Fig. 3b. Solid lines are the Lorentz function fits for each MDC. (c) Experimental band dispersion from Fig. 3b (blue circles) with the parabolic band (dashed line) assuming a free electron band. (d) Self-energy extracted from MDCs in Fig. 4b. Results for ReΣ and ImΣ are shown as red squares and blue circles with experimental error bar, respectively. Dashed line indicates ω2 behaviour, which well reproduces the ImΣ upto ~50 meV, corresponding to the kink energy observed in ReΣ as a peak.

Discussion

In the absence of experimental studies of phonons in (BEDT-TTF)3Br(pBIB), we have compared with molecular vibration modes known from optical spectroscopy of superconducting (BEDT-TTF)2Cu(NCS)2. Such a comparison helps to quantify the electron–phonon coupling strength of molecular vibration modes in (BEDT-TTF)3Br(pBIB) in relation to superconducting (BEDT-TTF)2Cu(NCS)2. The optical spectra of (BEDT-TTF)2Cu(NCS)2 reported earlier was analysed on the basis of neutral BEDT-TTF molecules28. The spectra of (BEDT-TTF)2Cu(NCS)2 indicated several modes with main features at about 20, 40, 60, 112 meV and a doublet at 182 and 187 meV. Using a simplified tight-binding analysis for the HOMO electrons and their coupling to the vibrational modes of the BEDT-TTF molecule, an electron–phonon coupling parameter of λph=0.37–0.45 was estimated29. The results also showed that the electron–phonon coupling is the strongest for the ~60-meV mode and it does not change across the superconducting transition. Thus, the presently obtained value of λ=0.9 from ARPES studies is about twice the value estimated from optical studies of BEDT-TTF-based organic superconductors. This indicates that the intra-molecule vibrations couple quite strongly to the carriers forming the Fermi surface and have an important role in the electronic structure of (BEDT-TTF)3Br(pBIB) also.

Based on the above characteristics and the fact that the kink energy matches with low-energy vibration mode known from optical studies, we attribute the kink feature observed in our ARPES data to electron–phonon coupling, although we cannot definitively rule out the role of electron–electron correlations in 2D. From the EF band crossing, the Fermi velocity is estimated to be vF=2.0 eVÅ. This indicates a relatively high Fermi velocity renormalized metal for (BEDT-TTF)3Br(pBIB) belonging to the BEDT-TTF family of exotic metals.

Methods

Synthesis and the crystal structure

High-quality single crystals of (BEDT-TTF)3Br(pBIB) were grown by electrochemical oxidation of BEDT-TTF in the presence of tetraphenylphosphonium bromide and pBIB dissolved in chlorobenzene (5% MeOH)22. The crystal structure data were measured under the same conditions of cooling rate and temperature as for the ARPES measurements so as to ensure a reliable comparison between experimental results and the first-principles band calculations.

First-principles band calculation

The calculation method and details are basically the same as those reported in ref. 30. The calculations are based on the density functional theory within the generalized gradient approximation. The experimentally determined low-temperature crystal structure was used for the first-principles band structure calculations. Planewave basis sets are used with the ultrasoft pseudopotential technique. The cutoff energy for wave functions is 25 Ry and 256 Ry for charge density.

ARPES experiment

The He Iα ARPES measurements were performed on a spectrometer built using a hemispherical electron analyser (GAMMADATA-SCIENTA SES2002) and a high-flux He discharge lamp with a toroidal grating monochromator, which gives partially polarized photons. The schematic of the spectrometer geometry is shown in Fig. 1b. Although the geometry allows symmetry-selective polarization-dependent ARPES using laser source, the geometry is not suitable for symmetry-selective ARPES using the He discharge lamp. The spectra were measured with He Iα resonance line (21.218 eV) at a vacuum of ~1×10−10 Torr during measurements and a base vacuum of <5×10−11 Torr. The laser-ARPES measurements were carried out using a hemispherical electron analyser (VG-SCIENTA R4000) and a quasi-continuous wave narrowband ultraviolet laser (6.994 eV), with an operating vacuum of ~5×10−11 Torr during measurements and a base vacuum of <2×10−11 Torr. The total energy resolution (analyser and light) was set to 36±2 meV for He Iα measurements and 14±2 meV for laser measurements. The angular resolution was set to 0.33° corresponding to k resolution of ±0.012 Å−1 for He Iα measurements and 0.36° corresponding to k resolution of ±0.0052 Å−1 for laser measurements. Samples were mounted on an original-designed double-walled gold-plated thermally shielded sample holder, and the sample temperature was measured using a calibrated silicon diode sensor mounted just below the sample, with an accuracy of ±0.1 K. Normalization of spectra was done with scan time. All the spectra reported here were measured on clean surfaces obtained by fresh in situ cleaves on the same sample, or for samples from the same batch. The samples were cleaved in situ at 4 K and resulted in flat, shiny metallic surfaces. The sample orientation was determined using X-ray diffraction and confirmed by the symmetry of the measured ARPES spectra. We have confirmed the absence of degradation effects and highly reproducible spectra over a period of 3 h after cleaving. The reproducibility of the ARPES spectra was established by repeated measurements on freshly cleaved surfaces. Also, the reproducibility of the He Iα and laser-ARPES measurements for the Fermi surface crossing shows that the surface sensitivity is not a problem and the obtained spectra represent the intrinsic electronic structure of (BEDT-TTF)3Br(pBIB). The Fermi edge (EF) of samples was referenced to that of a gold film evaporated onto the sample substrate.

The total energy resolution is determined by fitting the EF spectrum of (BEDT-TTF)3Br(pBIB) to the Fermi–Dirac distribution function at 4 K convolved with a Gaussian. The accuracy in position of EF is ±1–2 meV.

Self-energy analysis

The self energy Σ was obtained using the method described in ref. 17, which uses a spectral function of the form A(k,ω) ImΣ(ω)/([ω−ReΣ(ω)]2+[ImΣ(ω)]2), where is the non-interacting bare dispersion. ReΣ(ω) and ImΣ(ω) are directly extracted from MDCs. MDC fits were carried out using Lorentz functions and a least-squares method. For the bare dispersion, we have used a parabolic band instead of the calculated band dispersion result. However, we ensured that the parabolic band reproduces the experimental kF as well as the band dispersion at binding energies higher than the kink structure. ImΣ(ω) are calculated from multiplying MDC width and bare band velocity.

Additional information

How to cite this article: Kiss, T. et al. Quasiparticles and Fermi liquid behaviour in an organic metal. Nat. Commun. 3:1089 doi: 10.1038/ncomms2079 (2012).

References

  1. 1.

    et al. A rubberlike stretchable active matrix using elastic conductors. Science 321, 1468–1472 (2008).

  2. 2.

    , & Exotic materials for bio-organic electronics. J. Mater. Chem. 21, 1350–1361 (2011).

  3. 3.

    , , & Electron transfer in a new highly conducting donor-acceptor complex. J. Am. Chem. Soc. 95, 948–949 (1973).

  4. 4.

    & The Theory of Quantum Liquids (Addison Wesley, 1966).

  5. 5.

    et al. Absence of quasiparticles in the photoemission spectra of quasi-one-dimensional Bechgaard salts. Phys. Rev. Lett. 79, 3982–3985 (1997).

  6. 6.

    et al. Band mapping and quasiparticle suppression in the one-dimensional organic conductor TTF-TCNQ. Phys. Rev. Lett. 81, 2974–2977 (1998).

  7. 7.

    et al. Spectroscopic signatures of spin-charge separation in the quasi-one-dimensional organic conductor TTF-TCNQ. Phys. Rev. Lett. 88, 096402 (2002).

  8. 8.

    et al. Temperature-dependent luttinger surfaces. Phys. Rev. Lett. 95, 246402 (2005).

  9. 9.

    , , , & Phenomenology of the normal state of Cu-O high-temperature superconductors. Phys. Rev. Lett. 63, 1996–1999 (1989).

  10. 10.

    & Charged magnetic domain lines and the magnetism of high-Tc oxides. Phys. Rev. B 40, 7391–7394 (1989).

  11. 11.

    et al. Unusual electronic structure near EF in the organic superconductor κ-[bis(ethylenedithio)tetrathiafulvalene]2Cu[N(CN)2]Br. Phys. Rev. B 51, 6155–6158 (1995).

  12. 12.

    et al. Electronic structure of organic superconductors κ-(ET)2Cu[N(CN)2]Br, κ-(ET)2Cu(NCS)2, and β-(ET)2I3 studied by photoelectron spectroscopy. Phys. Rev. B 51, 13000–13304 (1995).

  13. 13.

    et al. High-resolution photoemission study of metallic, insulating, and superconducting BEDT-TTF salts. Phys. Rev. B 56, 9082–9090 (1997).

  14. 14.

    & Organic conductors and superconductors. Adv. Phys. 31, 299–490 (1982).

  15. 15.

    et al. Organic Superconductor (Prentice Hall, NJ, 1992).

  16. 16.

    , & Organic Superconductors 2nd edn (Springer, Berlin, 1998).

  17. 17.

    , & Angle-resolved photoemisson studies of the cuprate superconductors. Rev. Mod. Phys. 75, 473–541 (2003).

  18. 18.

    Similarities between organic and cuprate superconductors. Science 278, 820–821 (1997).

  19. 19.

    Organic conductors with unusual band fillings. Chem. Rev. 104, 4947–4969 (2004).

  20. 20.

    , & NMR studies on two-dimensional molecular conductors and superconductors: mott transition in κ-(BEDT-TTF)2X. Chem. Rev. 104, 5635–5653 (2004).

  21. 21.

    et al. Fermi surface study of quasi-two-dimensional organic conductors by magnetooptical measurements. J. Phys. Soc. Jpn. 72, 143–148 (2003).

  22. 22.

    , , & Structural and physical properties of conducting cation radical salts containing supramolecular assemblies based on p-bis(iodoethynyl)benzene derivatives. J. Mater. Chem. 11, 1034–1041 (2001).

  23. 23.

    et al. Fermi surface in new layered organic conductors (BEDT-TTF)3Br(pBIB) and (BEDT-TTF)3Cl(DFBIB). Synth. Met. 133–134, 169–171 (2003).

  24. 24.

    et al. Shubnikov-de Haas effect and angular-dependent magnetoresistance in new layered organic conductors ET3Cl(DFBIB) and ET3Br(pBIB). J. Phys. Soc. Jpn. 74, 679–685 (2005).

  25. 25.

    et al. A versatile system for ultrahigh resolution, low temperature, and polarization dependent Laser-angle-resolved photoemission spectroscopy. Rev. Sci. Instrum. 79, 023106 (2008).

  26. 26.

    et al. Intra- and intermolecular band dispersion in an organic crystal. Science 317, 351–355 (2007).

  27. 27.

    , , , & Electron-phonon coupling in photoemission spectra. Phys. Rev. B. 60, 10796–10802 (1999).

  28. 28.

    , , & Raman active molecular vibrations in the organic superconductor (BEDT-TTF)2Cu(NCS)2. Phys. Rev. B. 47, 14374–14379 (1993).

  29. 29.

    , & Electron states and electron-phonon coupling in the (BEDT-TTF)-based organic superconductors. Phys. Rev. B. 53, 6677–6681 (1996).

  30. 30.

    & Atomic and electronic structures of the high-pressure superconductor β′-(BEDT-TTF)2ICl2: a first-principles study of the pressure effects. Phys. Rev. B. 68, 220511 (2003).

Download references

Acknowledgements

We thank M. Kobayashi for growing high-quality samples. This work was supported by grants from the Ministry of Education, Culture and Science of Japan (Grant-in-Aid for Scientific Research(S) No. 22224006 from JSPS) and JSPS through its Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST) Program.

Author information

Author notes

    • T. Kiss

    Present address: Graduate school of engineering science, Osaka University, Toyonaka, Osaka 560-8531, Japan;

    • T. Shimojima
    •  & K. Ishizaka

    Present address: Department of Applied Physics, University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan.

Affiliations

  1. Institute for Solid State Physics (ISSP), University of Tokyo, Kashiwa, Chiba 277-8581, Japan.

    • T. Kiss
    • , T. Akimoto
    • , T. Shimojima
    • , K. Ishizaka
    • , S. Watanabe
    •  & S. Shin
  2. The Institute of Physical and Chemical Research (RIKEN), Wako, Saitama 351-0198, Japan.

    • T. Kiss
    • , H.M. Yamamoto
    • , A. Fukaya
    •  & R. Kato
  3. CREST, JST, Chiyoda-ku, Tokyo 102-0075, Japan.

    • T. Kiss
    • , K. Ishizaka
    •  & S. Shin
  4. The Institute of Physical and Chemical Research (RIKEN), Sayo-gun, Hyogo 679-5148, Japan.

    • A. Chainani
    •  & S. Shin
  5. JST-PRESTO, Kawaguchi, Saitama 332-0012, Japan.

    • H.M. Yamamoto
  6. Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan.

    • H.M. Yamamoto
  7. National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan.

    • T. Miyazaki
  8. Beijing Center for Crystal R&D, Chinese Academy of Science, Zhongguancun, Beijing 100190, China.

    • C.-T. Chen

Authors

  1. Search for T. Kiss in:

  2. Search for A. Chainani in:

  3. Search for H.M. Yamamoto in:

  4. Search for T. Miyazaki in:

  5. Search for T. Akimoto in:

  6. Search for T. Shimojima in:

  7. Search for K. Ishizaka in:

  8. Search for S. Watanabe in:

  9. Search for C.-T. Chen in:

  10. Search for A. Fukaya in:

  11. Search for R. Kato in:

  12. Search for S. Shin in:

Contributions

T.K., A.C., R.K. and S.S. designed the research. T.K. and T.A. performed the angle-integrated and angle-resolved PES measurements. H.M.Y., A.F. and R.K. synthesized the material and characterized its crystal structure. T.M. performed the first-principles band structure calculations. T.K., T.A. and A.C. analysed the data. T.K., T.S., K.I., S.W., C.T.C. and S.S. set up the ARPES apparatus. T.K. and A.C. wrote the paper with inputs from H.M.Y., T.M., T.A., T.S., K.I., R.K. and S.S.

Competing interests

The authors declare no competing financial interests.

Corresponding author

Correspondence to T. Kiss.

About this article

Publication history

Received

Accepted

Published

DOI

https://doi.org/10.1038/ncomms2079

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.