Figure 3: Ellipsoid plots derived from single-crystal X-ray diffraction data. | Nature Communications

Figure 3: Ellipsoid plots derived from single-crystal X-ray diffraction data.

From: A monotopic aluminum telluride with an Al=Te double bond stabilized by N-heterocyclic carbenes

Figure 3

Molecular structures of 3 (a) and 5 (b) in the solid state. Hydrogen atoms, isopropyl groups and non-N-bonded methyl groups have been omitted for reasons of clarity. Thermal ellipsoids are at the 30% probability level. Selected bond lengths (Å) and bond angles (°): 3: Al1–Te1=2.5130(14), Al1–N1=1.804(4), Al1–C28=2.084(5), Al1–C37=2.077(5), N1–C1=1.259(6); Te1–Al1–N1=118.34(14), Te1–Al1–C28=102.65(13), Te1–Al1–C37=119.08(14), Al1–N1–C1=139.8(4). 5: Al1–Te1=2.6211(15), Al1–Te1′=2.6143(14), Al1–N1=1.765(5), Al1–C28=2.086(5), N1–C1=1.253(7); Al1–Te1–Al1′=80.86(5), Te1–Al1–Te1′=99.14(5), N1–Al1–Te1=115.83(15), N1–Al1–Te1′=121.13(16), Al1–N1–C1=164.3(4).

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