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Metal-cluster catalysts

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Nature Chemistry volume 2, pages 10051006 (2010) | Download Citation

Enzymes keep their catalytic reactivity under fine control, letting appropriate molecules approach their active sites to perform reactions. Now, studies of calixarenes attached to gold clusters to emulate this behaviour in synthetic systems suggest that the key to accessibility could be a matter of the relative sizes of ligands and metal clusters.

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References

  1. 1.

    & Chem. Soc. Rev. 37, 2096–2126 (2008).

  2. 2.

    & Hutchings G. J. Angew. Chem. Int. Ed. 45, 7896–7936 (2006).

  3. 3.

    et al. Nature Chem. 2, 1062–1068 (2010).

  4. 4.

    , & J. Am. Chem. Soc. 100, 5085–5089 (1978).

  5. 5.

    , & Langmuir 25, 10548–10553 (2009).

  6. 6.

    , , & Nature 404, 376–379 (2000).

  7. 7.

    Chem. Commun. 301–306 (1999).

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Affiliations

  1. Graham J. Hutchings is at the Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK.  hutch@cardiff.ac.uk

    • Graham J. Hutchings

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https://doi.org/10.1038/nchem.868

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