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Gas-phase chemical kinetics

Three is the magic number

Nature Chemistry volume 9, pages 1038–1039 (2017)Cite this article

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Although predicted many years ago, chemically reactive termolecular reactions were thought to be unimportant in defining the behaviour of combustion systems. Now, calculations have shown that such reactions between radicals and long-lived bimolecular complexes can actually play an important role in hydrogen combustion.

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Figure 1: A schematic diagram showing the kinetic processes involving the reaction of the transient HO2** species.

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  1. Department of Chemistry and Biochemistry, University of Boulder, 215 UCB Boulder, 80309-0215, Colorado, USA

    Rex T. Skodje

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  1. Rex T. Skodje
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Correspondence to Rex T. Skodje.

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Skodje, R. Three is the magic number. Nature Chem 9, 1038–1039 (2017). https://doi.org/10.1038/nchem.2880

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