Self-assembly of particles into long-range, three-dimensional, ordered superstructures is crucial for the design of a variety of materials, including plasmonic sensing materials, energy or gas storage systems, catalysts and photonic crystals. Here, we have combined experimental and simulation data to show that truncated rhombic dodecahedral particles of the metal–organic framework (MOF) ZIF-8 can self-assemble into millimetre-sized superstructures with an underlying three-dimensional rhombohedral lattice that behave as photonic crystals. Those superstructures feature a photonic bandgap that can be tuned by controlling the size of the ZIF-8 particles and is also responsive to the adsorption of guest substances in the micropores of the ZIF-8 particles. In addition, superstructures with different lattices can also be assembled by tuning the truncation of ZIF-8 particles, or by using octahedral UiO-66 MOF particles instead. These well-ordered, sub-micrometre-sized superstructures might ultimately facilitate the design of three-dimensional photonic materials for applications in sensing.
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This work was supported by EU FP7 ERC-Co 615954, the Spanish MINECO (projects PN MAT2015-65354-C2-1-R and MAT2015-68075-R [SIFE2]) and the Comunidad de Madrid project S2013/MIT-2740 (PHAMA_2.0). It was also funded by the CERCA Programme/Generalitat de Catalunya. The authors based at ICN2 and ICMAB acknowledge the support of the Spanish MINECO through the Severo Ochoa Centers of Excellence Program (grants SEV-2013-0295 and SEV-2015-0496). The authors thank J. Albalad and J. Saiz for their help in the TGA and reflectance measurements, respectively.
The authors declare no competing financial interests.
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Avci, C., Imaz, I., Carné-Sánchez, A. et al. Self-assembly of polyhedral metal–organic framework particles into three-dimensional ordered superstructures. Nature Chem 10, 78–84 (2018). https://doi.org/10.1038/nchem.2875
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