Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

Structure prediction

Encoding evolution of porous solids

The design and prediction of network topology is challenging, even when the components' principle interactions are strong. Now, frameworks with relatively weak 'chiral recognition' between organic building blocks have been synthesized and rationalized in silico — an important development in the reticular synthesis of molecular crystals.

This is a preview of subscription content, access via your institution

Access options

Buy article

Get time limited or full article access on ReadCube.

$32.00

All prices are NET prices.

Figure 1: Illustrative models of crystal structures amongst key families of porous solids.
Figure 2: Porous solids assembled from linear and tetrahedral tectons.

References

  1. Cheetham, A. K., Férey, G. & Loiseau, T. Angew. Chem. Int. Ed. 38, 3268–3292 (1999).

    Article  CAS  Google Scholar 

  2. Brunet, P., Simard, M. & Wuest, J. D. J. Am. Chem. Soc. 119, 2737–2738 (1997).

    Article  CAS  Google Scholar 

  3. Férey, G. et al. Science 309, 2040–2042 (2005).

    Article  Google Scholar 

  4. Banerjee, R. et al. Science 319, 939–943 (2008).

    Article  CAS  Google Scholar 

  5. Eddaoudi, M. et al. Science 295, 469–472 (2002).

    Article  CAS  Google Scholar 

  6. Tan, J. C., Bennett, T. D. & Cheetham, A. K. Proc. Natl Acad. Sci. USA 107, 9938–9943 (2010).

    Article  CAS  Google Scholar 

  7. Slater, A. G. et al. Nat. Chem. 9, 17–25 (2017).

    Article  CAS  Google Scholar 

  8. Dolbecq, A. et al. J. Am. Chem. Soc. 131, 16078–16087 (2009).

    Article  Google Scholar 

  9. Woodley, S. M. & Catlow, R. Nat. Mater. 7, 937–946 (2008).

    Article  CAS  Google Scholar 

  10. Mellot-Draznieks, C., Dutour, J. & Férey, G. Angew. Chem. Int. Ed. 43, 6290–6296 (2004).

    Article  CAS  Google Scholar 

  11. Wilmer, C.E. et al. Nat. Chem. 4, 83–89 (2012)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Caroline Mellot-Draznieks or Anthony K. Cheetham.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Mellot-Draznieks, C., Cheetham, A. Encoding evolution of porous solids. Nature Chem 9, 6–8 (2017). https://doi.org/10.1038/nchem.2700

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nchem.2700

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing