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Structure prediction

Encoding evolution of porous solids

The design and prediction of network topology is challenging, even when the components' principle interactions are strong. Now, frameworks with relatively weak 'chiral recognition' between organic building blocks have been synthesized and rationalized in silico — an important development in the reticular synthesis of molecular crystals.

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Figure 1: Illustrative models of crystal structures amongst key families of porous solids.
Figure 2: Porous solids assembled from linear and tetrahedral tectons.

References

  1. Cheetham, A. K., Férey, G. & Loiseau, T. Angew. Chem. Int. Ed. 38, 3268–3292 (1999).

    Article  CAS  Google Scholar 

  2. Brunet, P., Simard, M. & Wuest, J. D. J. Am. Chem. Soc. 119, 2737–2738 (1997).

    Article  CAS  Google Scholar 

  3. Férey, G. et al. Science 309, 2040–2042 (2005).

    Article  Google Scholar 

  4. Banerjee, R. et al. Science 319, 939–943 (2008).

    Article  CAS  Google Scholar 

  5. Eddaoudi, M. et al. Science 295, 469–472 (2002).

    Article  CAS  Google Scholar 

  6. Tan, J. C., Bennett, T. D. & Cheetham, A. K. Proc. Natl Acad. Sci. USA 107, 9938–9943 (2010).

    Article  CAS  Google Scholar 

  7. Slater, A. G. et al. Nat. Chem. 9, 17–25 (2017).

    Article  CAS  Google Scholar 

  8. Dolbecq, A. et al. J. Am. Chem. Soc. 131, 16078–16087 (2009).

    Article  Google Scholar 

  9. Woodley, S. M. & Catlow, R. Nat. Mater. 7, 937–946 (2008).

    Article  CAS  Google Scholar 

  10. Mellot-Draznieks, C., Dutour, J. & Férey, G. Angew. Chem. Int. Ed. 43, 6290–6296 (2004).

    Article  CAS  Google Scholar 

  11. Wilmer, C.E. et al. Nat. Chem. 4, 83–89 (2012)

    Article  CAS  Google Scholar 

Download references

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Correspondence to Caroline Mellot-Draznieks or Anthony K. Cheetham.

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Mellot-Draznieks, C., Cheetham, A. Encoding evolution of porous solids. Nature Chem 9, 6–8 (2017). https://doi.org/10.1038/nchem.2700

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