Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Metal–organic frameworks

Shuttling in the solid state

Incorporating mechanically interlocked molecular shuttles within a metal–organic framework that has enough free space in the crystal lattice to permit volume-conserving translational motion sets the stage for defect-free molecular-electronic device fabrication and more.

This is a preview of subscription content, access via your institution

Relevant articles

Open Access articles citing this article.

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Metal–organic rotaxane frameworks.

References

  1. Kay, E. K., Leigh, D. A. & Zerbetto, F. Angew. Chem. Int. Ed. 46, 72–191 (2007).

    Article  CAS  Google Scholar 

  2. Stoddart, J. F. Chem. Soc. Rev. 38, 1802–1820 (2009).

    Article  CAS  PubMed  Google Scholar 

  3. Balzani, V., Credi, A. & Venturi, M. Molecular Devices and Machines-Concepts and Perspectives for the Nanoworld (Wiley InterScience, 2008).

    Book  Google Scholar 

  4. Schill, G. & Zollenkopf, H. Nachr. Chem. Tech. 15, 149–151 (1967).

    Google Scholar 

  5. Harrison, I. T. & Harrison, S. J. Am. Chem. Soc. 89, 5723–5724 (1967).

    Article  CAS  Google Scholar 

  6. Flood, A. H. et al. Chem. Eur. J. 10, 6558–6564 (2004).

    Article  CAS  PubMed  Google Scholar 

  7. Zhu, K., O'Keefe, C. A., Vukotic, V. N., Schurko, R. W. & Loeb, S. J. Nature Chem. 7, 514–519 (2015).

    Article  CAS  Google Scholar 

  8. Vukotic, V. N., Harris, K. J., Zhu, K., Schurko, R. W. & Loeb, S. J. Nature Chem. 4, 456–460 (2012).

    Article  CAS  Google Scholar 

  9. Deng, H., Olson, M. A., Stoddart, J. F. & Yaghi, O. M. Nature Chem. 2, 439–443 (2010).

    Article  CAS  Google Scholar 

  10. Vogelsberg, C. S. & Garcia-Garibay, M. A. Chem. Soc. Rev. 41, 1892–1910 (2012).

    CAS  PubMed  Google Scholar 

  11. Coskun, A. et al. Chem. Soc. Rev. 41, 4827–4859 (2012).

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mark A. Olson.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Olson, M. Shuttling in the solid state. Nature Chem 7, 470–471 (2015). https://doi.org/10.1038/nchem.2268

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nchem.2268

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing