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Covalent organic frameworks

Crossing the channel

The ordered one-dimensional nanochannels found in covalent organic frameworks (COFs) could render them able to conduct protons. However, the frameworks' instability in acid has thus far precluded any practical implementations. Now, a strategy to overcome this instability has enabled proton conduction using a COF for the first time.

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Figure 1: The structure and proton-conducting mechanism of Tp-Azo COF.

References

  1. Schmidt-Rohr, K. & Chen, Q. Nature Mater. 7, 75–83 (2008).

    Article  CAS  Google Scholar 

  2. Yoon, M., Suh, K., Natarajan, S. & Kim, K. Angew. Chem. Int. Ed. 52, 2688–2700 (2013).

    Article  CAS  Google Scholar 

  3. Chandra, S. et al. J. Am. Chem. Soc. 136, 6570–6573 (2014).

    Article  CAS  Google Scholar 

  4. Feng, X., Ding, X. & Jiang, D. Chem. Soc. Rev. 41, 6010–6022 (2012).

    Article  CAS  Google Scholar 

  5. Jin, S. et al. Angew. Chem. Int. Ed. 52, 2017–2021 (2013).

    Article  CAS  Google Scholar 

  6. Xu, H. et al. Chem. Commun. 50, 1292–1294 (2014).

    Article  CAS  Google Scholar 

  7. Kandambeth, S. et al. J. Am. Chem. Soc. 134, 19524–19527 (2012).

    Article  CAS  Google Scholar 

  8. Halasz, I., Lukic, K. & Vancik, H. Acta Crystallogr. C 63, o61–o64 (2007).

    Article  CAS  Google Scholar 

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Correspondence to Donglin Jiang.

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Xu, H., Jiang, D. Crossing the channel. Nature Chem 6, 564–566 (2014). https://doi.org/10.1038/nchem.1984

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