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Bioinorganic chemistry

Bond breaking bacteria-style

Chemists envy the ease with which some bacterial enzymes can break carbon–hydrogen bonds. They now imitate the enzyme active site in an oxo-bridged diiron compound that can cleave these strong bonds.

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Figure 1: Strong O–H and C–H bonds cleaved by a diiron(IV) complex.
Figure 2: C–H bond-breaking reactions performed by diiron(IV) complexes.

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Goldman, A. Bond breaking bacteria-style. Nature Chem 1, 109–110 (2009). https://doi.org/10.1038/nchem.191

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