Latent catalysts require activation, and this is often achieved with either heat, light or an additional chemical agent. By attaching polymer chains to known classes of metal–carbene complexes, it has now been shown that mechanical force can also be used to induce catalytic activity.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Grubbs, R. H. et al. J. Am. Chem. Soc. 120, 1627–1628 (1998).
Noels, A. F. et al. Chem. Commun. 986–987 (2001).
Slugovc, C. et al. Organometallics 24, 2255–2258 (2005).
Piermattei, A., Karthikeyan, S. & Sijbesma, R. P. Nature Chem. 1, 133–137 10.1038/nchem.167 (2009).
Hedrick, J. L. et al. J. Org. Chem. 70, 2391–2393 (2005).
Grubbs, R. H. (ed.) Handbook of Metathesis (Wiley-VCH, 2003).
White, S. R. et al. Nature 409, 794–797 (2001).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rathore, J., Nelson, A. Catalysts feel the force. Nature Chem 1, 102–103 (2009). https://doi.org/10.1038/nchem.189
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.189