Metal-coordinating groups are widely used to direct C–H functionalization. Now the combination of an alkene hydrosilylation, C–H activation and C–Si oxidation has been used to achieve a formal 1,4-dioxygenation of alkenes.
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References
Gutekunst, W. R. & Baran, P. S. Chem. Soc. Rev. 40, 1976–1991 (2011).
McMurray, L., O'Hara, F. & Gaunt, M. J. Chem. Soc. Rev. 40, 1885–1898 (2011).
Chen, M. S. & White, M. C. Science 327, 566–571 (2010).
Engle, K. M., Mei, T.-S., Wasa, M. & Yu, J.-Q. Acc. Chem. Res. 45, 788–802 (2012).
He, G. & Chen, G. Angew. Chem. Int. Ed. 50, 5192–5196 (2011).
Huang, C., Ghavtadze, N., Chattopadhyay, B. & Gevorgyan, V. J. Am. Chem. Soc. 133, 17630–17633 (2011).
Huang, C., Chattopadhyay, B. & Gevorgyan, V. J. Am. Chem. Soc. 133, 12406–12409 (2011).
Ren, Z., Mo, F. & Dong, G. J. Am. Chem. Soc. 134, 16991–16994 (2012).
Ghavtadze, N., Melkonyan, F. S., Gulevich, A. V., Huang, C. & Gevorgyan, V. Nature Chem. 6, 122–125 10.1038/nchem.1841(2014).
Simmons, E. M. & Hartwig, J. F. Nature 483, 70–73 (2012).
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Ferreira, E. A surrogate for selectivity. Nature Chem 6, 94–96 (2014). https://doi.org/10.1038/nchem.1851
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DOI: https://doi.org/10.1038/nchem.1851