This is a preview of subscription content, access via your institution
Relevant articles
Open Access articles citing this article.
-
Ferroelectric 2D ice under graphene confinement
Nature Communications Open Access 01 November 2021
-
Dielectric ordering of water molecules arranged in a dipolar lattice
Nature Communications Open Access 06 August 2020
-
Integrated watershed management: evolution, development and emerging trends
Journal of Forestry Research Open Access 30 June 2016
Access options
Subscribe to Journal
Get full journal access for 1 year
$199.00
only $3.90 per issue
All prices are NET prices.
VAT will be added later in the checkout.
Tax calculation will be finalised during checkout.
Buy article
Get time limited or full article access on ReadCube.
$32.00
All prices are NET prices.

References
Algara-Siller, G. et al. Square ice in graphene nanocapillaries. Nature 519, 443–445 (2015)
Wang, C., Qiao, Q., Shokuhfar, T. & Klie, R. F. High-resolution electron microscopy and spectroscopy of ferritin in biocompatible graphene liquid cells and graphene sandwiches. Adv. Mater. 26, 3410–3414 (2014)
Zhao, W., Bai, J., Yuan, L., Yang, J. & Zeng, X. Ferroelectric hexagonal and rhombic monolayer ice phases. Chem. Sci. 5, 1757–1764 (2014)
Takaiwa, D., Hatano, I., Koga, K. & Tanaka, H. Phase diagram of water in carbon nanotubes. Proc. Natl Acad. Sci. USA 105, 39–43 (2008)
Bragg, W. H. & Bragg, W. L. The reflection of X-rays by crystals. Proc. R. Soc. Lond. A 88, 428–438 (1913)
Kirkland, E. J. Advanced Computing in Electron Microscopy (Springer, 2010)
Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77, 3865–3868 (1996)
Sun, H. COMPASS: an ab initio force-field optimized for condensed-phase applications—overview with details on alkane and benzene compounds. J. Phys. Chem. B 102, 7338–7364 (1998)
Kobayashi, K., Koshino, M. & Suenaga, K. Atomically resolved images of I h ice single crystals in the solid phase. Phys. Rev. Lett. 106, 206101 (2011)
Author information
Authors and Affiliations
Contributions
W.Z., C.W. and A.R.L. wrote this Comment with help from the other authors. W.Z., K.Y., C.W. and T.X. performed the experiment. Y.Z. and S.T.P. performed the calculations. C.W., T.X. and L.S. prepared the graphene samples. All authors discussed the paper and contributed to data analysis.
Corresponding author
Ethics declarations
Competing interests
Declared none.
PowerPoint slides
Rights and permissions
About this article
Cite this article
Zhou, W., Yin, K., Wang, C. et al. The observation of square ice in graphene questioned. Nature 528, E1–E2 (2015). https://doi.org/10.1038/nature16145
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1038/nature16145
This article is cited by
-
Molecular transport under extreme confinement
Science China Physics, Mechanics & Astronomy (2022)
-
Ferroelectric 2D ice under graphene confinement
Nature Communications (2021)
-
Dielectric ordering of water molecules arranged in a dipolar lattice
Nature Communications (2020)
-
Atomistic simulations on the axial nanowelding configuration and contact behavior between Ag nanowire and single-walled carbon nanotubes
Journal of Nanoparticle Research (2017)
-
Enhanced ordering reduces electric susceptibility of liquids confined to graphene slit pores
Scientific Reports (2016)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.