Abstract
Roughly half of the heavy elements (atomic mass greater than that of iron) are believed to be synthesized in the late evolutionary stages of stars with masses between 0.8 and 8 solar masses. Deep inside the star, nuclei (mainly iron) capture neutrons and progressively build up (through the slow-neutron-capture process1,2, or s-process) heavier elements that are subsequently brought to the stellar surface by convection. Two neutron sources, activated at distinct temperatures, have been proposed: 13C and 22Ne, each releasing one neutron per α-particle (4He) captured1,2,3,4. To explain the measured stellar abundances1,2,3,4,5,6,7, stellar evolution models invoking the 13C neutron source (which operates at temperatures of about one hundred million kelvin) are favoured. Isotopic ratios in primitive meteorites, however, reflecting nucleosynthesis in the previous generations of stars that contributed material to the Solar System, point to higher temperatures (more than three hundred million kelvin), requiring at least a late activation of 22Ne (ref. 1). Here we report a determination of the s-process temperature directly in evolved low-mass giant stars, using zirconium and niobium abundances, independently of stellar evolution models. The derived temperature supports 13C as the s-process neutron source. The radioactive pair 93Zr–93Nb used to estimate the s-process temperature also provides, together with the pair 99Tc–99Ru, chronometric information on the time elapsed since the start of the s-process, which we determine to be one million to three million years.
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References
Käppeler, F. The origin of the heavy elements: the s process. Prog. Part. Nucl. Phys. 43, 419–483 (1999)
Käppeler, F., Gallino, R., Bisterzo, S. & Aoki, W. The s process: nuclear physics, stellar models, and observations. Rev. Mod. Phys. 83, 157–193 (2011)
Straniero, O. et al. Radiative C-13 burning in asymptotic giant branch stars and s-processing. Astrophys. J. 440, L85–L87 (1995)
Goriely, S. & Mowlavi, N. Neutron-capture nucleosynthesis in AGB stars. Astron. Astrophys. 362, 599–614 (2000)
Van Eck, S., Goriely, S., Jorissen, A. & Plez, B. Discovery of three lead-rich stars. Nature 412, 793–795 (2001)
Cristallo, S. et al. Evolution, nucleosynthesis, and yields of low-mass asymptotic giant branch stars at different metallicities. II. The FRUITY Database. Astrophys. J. Suppl. Ser. 197, 17 (2011)
Trippella, O., Busso, M., Maiorca, E., Käppeler, F. & Palmerini, S. s-processing in AGB stars revisited. I. Does the main component constrain the neutron source in the 13C pocket? Astrophys. J. 787, 41 (2014)
Raskin, G. et al. HERMES: a high-resolution fibre-fed spectrograph for the Mercator telescope. Astron. Astrophys. 526, A69 (2011)
Neyskens, P. Exploring S Stars. PhD thesis, Univ. Libre de Bruxelles. (2014)
Gustafsson, B. et al. A grid of MARCS model atmospheres for late-type stars. I. Methods and general properties. Astron. Astrophys. 486, 951–970 (2008)
Van Eck, S. et al. A grid of S stars MARCS model atmospheres. J. Phys. Conf. Ser. 328, 012009 (2011)
Van Eck, S. & Jorissen, A. The Henize sample of S stars. I. The technetium dichotomy. Astron. Astrophys. 345, 127–136 (1999)
Jorissen, A., Frayer, D. T., Johnson, H. R., Mayor, M. & Smith, V. V. S stars: infrared colors, technetium, and binarity. Astron. Astrophys. 271, 463–481 (1993)
Bao, Z. Y. et al. Neutron cross sections for nucleosynthesis studies. At. Data Nucl. Data Tables 76, 70–154 (2000)
Tagliente, G. et al. The 93Zr(n,γ) reaction up to 8 keV neutron energy. Phys. Rev. C 87, 014622 (2013)
Merrill, P. W. Spectroscopic observations of stars of class S. Astrophys. J. 116, 21–26 (1952)
Smith, V. V. & Wallerstein, G. Quantitative technetium and niobium abundances in heavy-element stars. Astrophys. J. 273, 742–748 (1983)
Mathews, G. J., Takahashi, K., Ward, R. A. & Howard, W. M. Stellar technetium and niobium abundances as a measure of the lifetime of AGB stars in the third dredge-up phase. Astrophys. J. 302, 410–414 (1986)
Vassiliadis, E. & Wood, P. R. Evolution of low- and intermediate-mass stars to the end of the asymptotic giant branch with mass loss. Astrophys. J. 413, 641–657 (1993)
Schröder, K.-P. & Cuntz, M. A new version of Reimers’ law of mass loss based on a physical approach. Astrophys. J. 630, L73–L76 (2005)
Van Eck, S., Jorissen, A., Udry, S., Mayor, M. & Pernier, B. The HIPPARCOS Hertzsprung-Russell diagram of S stars: probing nucleosynthesis and dredge-up. Astron. Astrophys. 329, 971–985 (1998)
Joint IRAS Science Working Group. IRAS Catalogue of Point Sources, Version 2.0 (IPAC, 1986)
Kupka, F., Piskunov, N., Ryabchikova, T. A., Stempels, H. C. & Weiss, W. W. VALD-2: Progress of the Vienna atomic line data base. Astron. Astrophys. 138, 119–133 (1999)
Alvarez, R. & Plez, B. Near-infrared narrow-band photometry of M-giant and Mira stars: models meet observations. Astron. Astrophys. 330, 1109–1119 (1998)
de Laverny, P. et al. Chemical analysis of carbon stars in the Local Group. Astron. Astrophys. 446, 1107–1118 (2006)
Lambert, D. L., Smith, V. V., Busso, M., Gallino, R. & Straniero, O. The chemical composition of red giants. IV. The neutron density at the s-process site. Astrophys. J. 450, 302–317 (1995)
Siess, L. Evolution of massive AGB stars. I. Carbon burning phase. Astron. Astrophys. 448, 717–729 (2006)
Asplund, M., Grevesse, N. & Sauval, A. J. in Cosmic Abundances as Records of Stellar Evolution and Nucleosynthesis (eds Barnes, T. G. III & Bash, F. N. ) 25–38 (Astonomical Society of the Pacific, 2005)
Goriely, S. & Siess, L. S-process in hot AGB stars: a complex interplay between diffusive mixing and nuclear burning. Astron. Astrophys. 421, L25–L28 (2004)
Garcìa-Hernàndez, D. A. et al. Rubidium-rich asymptotic giant branch stars. Science 314, 1751–1754 (2006)
Takahashi, K. & Yokoi, K. Beta-decay rates of highly ionized heavy atoms in stellar interiors. At. Data Nucl. Data Tables 36, 375–409 (1987)
Wallerstein, G., Balick, B., Alcolea, J., Bujarrabal, V. & Vanture, A. D. Carbon isotopic abundance ratios in S-type stars. Astron. Astrophys. 535, A101 (2011)
Savina, M. R. et al. Extinct technetium in silicon carbide stardust grains: implications for stellar nucleosynthesis. Science 303, 649–652 (2004)
Kashiv, Y. et al. Extinct 93Zr in single presolar SiC Grains from low mass asymptotic giant branch stars and condensation from Zr-depleted gas. Astrophys. J. 713, 212–219 (2010)
Stephenson, C. B. A General Catalogue of Galactic S Stars 2nd edn, Publications of the Warner & Swasey Observatory 3 (1984)
Biémont, E., Grevesse, N., Hannaford, P. & Lowe, R. M. Oscillator strengths for Zr I and Zr II and a new determination of the solar abundance of zirconium. Astrophys. J. 248, 867–873 (1981)
Acknowledgements
P.N. acknowledges the support of a FRIA (FNRS) fellowship. S.G., L.S. and S.V.E. are FRS-FNRS Research Associates. B.P. is supported in part by the CNRS Programme National de Physique Stellaire. This work has been partly funded by an Action de recherche concertée (ARC) from the Direction générale de l’Enseignement non obligatoire et de la Recherche scientifique, Communauté française de Belgique. It was based on observations obtained using the HERMES spectrograph, which is supported by the Fund for Scientific Research of Flanders (FWO); the Research Council of K.U. Leuven; the Fonds National de la Recherche Scientifique (FRS-FNRS), Belgium; the Royal Observatory of Belgium; the Observatoire de Genève, Switzerland; and the Thüringer Landessternwarte Tautenburg, Germany.
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S.V.E. and A.J. initiated the project. S.V.E. was supervisor of the PhD thesis of P.N., who computed the stellar atmospheric parameters, the abundances and the grid of S star model atmospheres, with help from B.P. The stellar models were computed by L.S., and the nucleosynthesis predictions were made by S.G. The text was written by S.V.E. and A.J., and edited by the other authors.
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Extended data figures and tables
Extended Data Figure 1 Observed and synthetic spectra around the Tc i 426.227 nm line.
a, Observed spectrum of the intrinsic, Tc-rich star NQ Pup (dots) along with spectral syntheses with log(εTc) = log(N(Tc)/N(H)) + 12.0 = −0.20 (continuous line; see Extended Data Table 3) and no Tc (dashed line). b, Same as a, but for the extrinsic, Tc-poor star V613 Mon; spectral syntheses correspond to log(εTc) = −0.30 (continuous line) and no Tc (dashed line).
Extended Data Figure 2 Predicted versus measured abundances.
We show that Nb and Zr abundances for intrinsic S stars and carbon stars (with only upper limits on the Nb abundance25) are consistent with nucleosynthesis predictions (shaded areas) for a model with a solar initial Nb abundance (±0.15 dex) and different λpm values29 (as labelled). Once all 93Zr has decayed to 93Nb, the models (dotted lines) reproduce the extrinsic S stars. The error bars represent the line-to-line dispersion and the systematic uncertainty from the models. The dashed line is a fit of equation (9) through the two most enriched extrinsic stars.
Extended Data Figure 3 Location of intrinsic S stars in the Hertzsprung–Russell diagram.
We show the location of intrinsic (that is, Tc-rich) S stars (triangles) from our sample in the stellar luminosity/effective temperature diagram21, along with low-mass evolutionary tracks (starting at the zero-age main sequence). The main sequence (MS) is indicated. The black diamond on each evolutionary track indicates where the third dredge-up event starts.
Extended Data Figure 4 Timescale determination for HIP 103476.
a, b, N(Tc)/N(Zr) (a) and [Nb/Zr] (b) predictions from the best-matching model (as judged from panel d, with the same meaning as in Fig. 2). For reasons of clarity we plot only these predictions. c, The deviation between predicted (solid line) and observed (dashed line) abundances in a and b, converted into weight functions fTc,i(t) (blue) and fNb,i(t) (red) (equation (4)). d, The maximum value reached by their product (green) (equation (5)) provides the best age estimate (vertical line). Weight product functions corresponding to less satisfactory models are plotted as grey lines.
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Neyskens, P., Van Eck, S., Jorissen, A. et al. The temperature and chronology of heavy-element synthesis in low-mass stars. Nature 517, 174–176 (2015). https://doi.org/10.1038/nature14050
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DOI: https://doi.org/10.1038/nature14050
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