Letter | Published:

Chirality-specific growth of single-walled carbon nanotubes on solid alloy catalysts

Nature volume 510, pages 522524 (26 June 2014) | Download Citation


Carbon nanotubes have many material properties that make them attractive for applications1,2. In the context of nanoelectronics3, interest has focused on single-walled carbon nanotubes4 (SWNTs) because slight changes in tube diameter and wrapping angle, defined by the chirality indices (n, m), will shift their electrical conductivity from one characteristic of a metallic state to one characteristic of a semiconducting state, and will also change the bandgap. However, this structure–function relationship can be fully exploited only with structurally pure SWNTs. Solution-based separation methods5 yield tubes within a narrow structure range, but the ultimate goal of producing just one type of SWNT by controlling its structure during growth has proved to be a considerable challenge over the last two decades6,7,8,9. Such efforts aim to optimize the composition6,10,11,12,13,14,15,16,17 or shape18,19,20,21 of the catalyst particles that are used in the chemical vapour deposition synthesis process to decompose the carbon feedstock and influence SWNT nucleation and growth22,23,24,25. This approach resulted in the highest reported proportion, 55 per cent, of single-chirality SWNTs in an as-grown sample11. Here we show that SWNTs of a single chirality, (12, 6), can be produced directly with an abundance higher than 92 per cent when using tungsten-based bimetallic alloy nanocrystals as catalysts. These, unlike other catalysts used so far, have such high melting points that they maintain their crystalline structure during the chemical vapour deposition process. This feature seems crucial because experiment and simulation both suggest that the highly selective growth of (12, 6) SWNTs is the result of a good structural match between the carbon atom arrangement around the nanotube circumference and the arrangement of the catalytically active atoms in one of the planes of the nanocrystal catalyst. We anticipate that using high-melting-point alloy nanocrystals with optimized structures as catalysts paves the way for total chirality control in SWNT growth and will thus promote the development of SWNT applications.

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We thank S. Iijima, S. Maruyama and J. Liu for advice on the manuscript; K. Lu, Y. Wang, E. Wang and S. Yao for discussions on catalyst preparation and properties; D. P. Nackashi, J. Ju, Y. Li and Protochips Inc. for in situ TEM measurements; H. Xu, H. Yang, K. Jiang and S. Wang for Raman measurements. This research was financially supported by MoST (project 2011CB933003), the NSFC of China (projects 21125103, 91333105, 21321001, 11179011 and 21273189) and a Hong Kong GRF research grant (G-YX4Q).

Author information


  1. Beijing National Laboratory for Molecular Science, Key Laboratory for the Physics and Chemistry of Nanodevices, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

    • Feng Yang
    • , Xiao Wang
    • , Daqi Zhang
    • , Juan Yang
    • , Da Luo
    • , Fei Peng
    • , Ruoming Li
    • , Yilun Li
    • , Meihui Li
    •  & Yan Li
  2. Institute of Textiles and Clothing, Hong Kong Polytechnic University, Kowloon, Hong Kong, China

    • Ziwei Xu
    •  & Feng Ding
  3. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

    • Jiake Wei
    • , Zhi Xu
    •  & Xuedong Bai
  4. Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China

    • Jian-Qiang Wang
  5. Electron Microscopy Laboratory, Peking University, Beijing 100871, China

    • Xuemei Li


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Yan Li and F.Y. had the idea for and designed the experiments, analysed the results and wrote the manuscript. F.Y., D.Z., J.Y., D.L., J.W., J.-Q.W., Zhi Xu, X.L., F.P., Yilun Li, R.L., M.L. and X.B. performed the experiments and analysed the results. X.W., Ziwei Xu and F.D. contributed to theoretical calculations.

Competing interests

Yan Li and F.Y. declare a financial interest: patents related to this research have been filed by Peking University. The University’s policy is to share financial rewards from the exploitation of patents with the inventors.

Corresponding author

Correspondence to Yan Li.

Extended data

Supplementary information

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  1. 1.

    Supplementary Information

    This file contains Supplementary Methods, Supplementary Figures 1-10, Supplementary Tables 1-4, Supplementary Equations 1-2 and Supplementary References. The Supplementary experimental methods include the preparation of catalysts and growth of SWNTs, characterizations of SWNTs grown with W-Co catalysts and the W-Co catalyst nanoparticles as well as the DFT simulation methods; Supplementary data shows the selective growth of more chiralities and with more W-based alloys.


  1. 1.

    Video 1: Real-time continuous Raman mapping of SWNTs

    A real-time continuous Raman mapping of SWNTs grown at 1030oC with W6Co7 catalysts taken at excitation of 633 nm, laser beam spot of 3μm and integration time of 4 s within the detected range of 15μm × 30μm.

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