Abstract
Electronic devices have advanced from their heavy, bulky origins to become smart, mobile appliances. Nevertheless, they remain rigid, which precludes their intimate integration into everyday life. Flexible, textile and stretchable electronics are emerging research areas and may yield mainstream technologies1,2,3. Rollable and unbreakable backplanes with amorphous silicon field-effect transistors on steel substrates only 3 μm thick have been demonstrated4. On polymer substrates, bending radii of 0.1 mm have been achieved in flexible electronic devices5,6,7. Concurrently, the need for compliant electronics that can not only be flexed but also conform to three-dimensional shapes has emerged3. Approaches include the transfer of ultrathin polyimide layers encapsulating silicon CMOS circuits onto pre-stretched elastomers8, the use of conductive elastomers integrated with organic field-effect transistors (OFETs) on polyimide islands9, and fabrication of OFETs and gold interconnects on elastic substrates10 to realize pressure, temperature and optical sensors11,12,13,14. Here we present a platform that makes electronics both virtually unbreakable4 and imperceptible. Fabricated directly on ultrathin (1 μm) polymer foils, our electronic circuits are light (3 g m−2) and ultraflexible and conform to their ambient, dynamic environment. Organic transistors with an ultra-dense oxide gate dielectric a few nanometres thick formed at room temperature enable sophisticated large-area electronic foils with unprecedented mechanical and environmental stability: they withstand repeated bending to radii of 5 μm and less, can be crumpled like paper, accommodate stretching up to 230% on prestrained elastomers, and can be operated at high temperatures and in aqueous environments. Because manufacturing costs of organic electronics are potentially low, imperceptible electronic foils may be as common in the future as plastic wrap is today. Applications include matrix-addressed tactile sensor foils for health care and monitoring, thin-film heaters, temperature and infrared sensors, displays15, and organic solar cells16.
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References
Wong W. S., Salleo A., eds. Flexible Electronics: Materials and Applications (Springer, 2010)
Cherenack, K. & van Pieterson, L. Smart textiles: challenges and opportunities. J. Appl. Phys. 112, 091301 (2012)
Wagner, S. & Bauer, S. Materials for stretchable electronics. MRS Bull. 37 (special issue), 207–213 (2012)
Ma, E. Y. & Wagner, S. Amorphous silicon transistors on ultrathin steel foil substrates. Appl. Phys. Lett. 74, 2661–2662 (1999)
Sekitani, T. et al. Ultraflexible organic field-effect transistors embedded at a neutral strain position. Appl. Phys. Lett. 87, 173502 (2005)
Sekitani, T., Zschieschang, U., Klauk, H. & Someya, T. Flexible organic transistors and circuits with extreme bending stability. Nature Mater. 9, 1015–1022 (2010)
Shahrjerdi, D. & Bedell, S. W. Extremely flexible nanoscale ultrathin body silicon integrated circuits on plastic. Nano Lett. 13, 315–320 (2013)
Kim, D. H. et al. Stretchable and foldable silicon integrated circuits. Science 320, 507–511 (2008)
Sekitani, T. et al. A rubberlike stretchable active matrix using elastic conductors. Science 321, 1468–1472 (2008)
Graz, I. M., Cotton, D. P. J., Robinson, A. & Lacour, S. P. Silicone substrate with in situ strain relief for stretchable thin-film transistors. Appl. Phys. Lett. 98, 124101 (2011)
Someya, T. et al. Conformable, flexible, large-area networks of pressure and thermal sensors with organic transistor active matrixes. Proc. Natl Acad. Sci. USA 102, 12321–12325 (2005)
Kim, D. H. et al. Epidermal electronics. Science 333, 838–843 (2011)
Sokolov, A. N., Tee, B. C. K., Bettinger, C. J., Tok, J. B. H. & Bao, Z. Chemical and engineering approaches to enable organic field-effect transistors for electronic skin applications. Acc. Chem. Res. 45, 361–371 (2012)
Lipomi, D. J. et al. Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes. Nature Nanotechnol. 6, 788–792 (2011)
White, M. S. et al. Ultrathin, highly flexible and stretchable PLEDs. Nature Photonics (in the press)
Kaltenbrunner, M. et al. Ultrathin and lightweight organic solar cells with high flexibility. Nature Commun. 3, 770–777 (2012)
Mardare, A. I., Kaltenbrunner, M., Sariciftci, N. S., Bauer, S. & Hassel, A. W. Ultra-thin anodic alumina capacitor films for plastic electronics. Phys. Status Solidi, A Appl. Res. 209, 813–818 (2012)
Lohrengel, M. M. Thin anodic oxide layers on aluminum and other valve metals—high-field regime. Mater. Sci. Eng. Rep. 11, 243–294 (1993)
Klauk, H., Zschieschang, U., Pflaum, J. & Halik, M. Ultralow-power organic complementary circuits. Nature 445, 745–748 (2007)
Yamamoto, T. & Takimiya, K. Facile synthesis of highly pi-extended heteroarenes, dinaphtho[2,3-b:2′,3′-f]chalcogenopheno[3,2-b]chalcogenophenes, and their application to field-effect transistors. J. Am. Chem. Soc. 129, 2224–2225 (2007)
de Almeida, L. A. L. et al. Modeling and performance of vanadium–oxide transition edge microbolometers. Appl. Phys. Lett. 85, 3605–3607 (2004)
Wang, B., Lai, J., Li, H., Hu, H. & Chen, S. Nanostructured vanadium oxide thin film with high TCR at room temperature for microbolometer. Infrared Phys. Technol. 57C, 8–13 (2013)
Oh, D.-W., Kim, S., Rogers, J. A., Cahill, D. G. & Sinha, S. Interfacial thermal conductance of transfer-printed metal films. Adv. Mater. 23, 5028–5033 (2011)
Gonzalez, M. et al. in 11th International Conference on Thermal, Mechanical and Multi-Physics Simulation and Experiments in Microelectronics and Microsystems (EuroSimE 2010) (eds Ernst, L. J. et al.) 1–7 (IEEE, 2010)
Tu, K. N. Recent advances on electromigration in very-large-scale-integration of interconnects. J. Appl. Phys. 94, 5451–5473 (2003)
Zschieschang, U. et al. Flexible low-voltage organic thin-film transistors and circuits based on C10-DNTT. J. Mater. Chem. 22, 4273–4277 (2012)
Khang, D., Jiang, H., Huang, Y. & Rogers, J. A stretchable form of single-crystal silicon for high-performance electronics on rubber substrates. Science 311, 208–212 (2006)
Suo, Z., Ma, E., Gleskova, H. & Wagner, S. Mechanics of rollable and foldable film-on-foil electronics. Appl. Phys. Lett. 74, 1177–1179 (1999)
Rogers, J. A., Someya, T. & Huang, Y. Materials and mechanics for stretchable electronics. Science 327, 1603–1607 (2010)
Zang, J. et al. Multifunctionality and control of the crumpling and unfolding of large-area graphene. Nature Mater. 12, 1–5 (2013)
Gärditz, C., Winnacker, A., Schindler, F. & Paetzold, R. Impact of Joule heating on the brightness homogeneity of organic light emitting devices. Appl. Phys. Lett. 90, 103506 (2007)
Bauer, S. & Ploss, B. A method for the measurement of the thermal, dielectric, and pyroelectric properties of thin pyroelectric films and their applications for integrated heat sensors. J. Appl. Phys. 68, 6361–6367 (1990)
Facchetti, A., Yoon, M. H. & Marks, T. J. Gate dielectrics for organic field-effect transistors: new opportunities for organic electronics. Adv. Mater. 17, 1705–1725 (2005)
Yan, H. et al. A high-mobility electron-transporting polymer for printed transistors. Nature 457, 679–686 (2008)
Usta, H., Facchetti, A. & Marks, T. J. Air-stable, solution-processable n-channel and ambipolar semiconductors for thin-film transistors based on the indenofluorenebis(dicyanovinylene) core. J. Am. Chem. Soc. 130, 8580–8581 (2008)
Oh, J. H. et al. High-performance air-stable n-type organic transistors based on core-chlorinated naphthalene tetracarboxylic diimides. Adv. Funct. Mater. 20, 2148–2156 (2010)
Jung, B. J., Lee, K., Sun, J., Andreou, A. G. & Katz, H. E. Air-operable, high-mobility organic transistors with semifluorinated side chains and unsubstituted naphthalenetetracarboxylic diimide cores: high mobility and environmental and bias stress stability from the perfluorooctylpropyl side chain. Adv. Funct. Mater. 20, 2930–2944 (2010)
Zhang, X.-H., Potscavage, W. J., Choi, S. & Kippelen, B. Low-voltage flexible organic complementary inverters with high noise margin and high dc gain. Appl. Phys. Lett. 94, 043312 (2009)
Geib, S. et al. Core-brominated tetraazaperopyrenes as n-channel semiconductors for organic complementary circuits on flexible substrates. Adv. Funct. Mater.. http://dx.doi.org/10.1002/adfm.201203600 (27 May 2013)
Baeg, K.-J. et al. High speeds complementary integrated circuits fabricated with all-printed polymeric semiconductors. J. Polym. Sci. B 49, 62–67 (2010)
Acknowledgements
We thank I. Abfalter for discussions. This work was supported by the JST Someya Bio-Harmonized ERATO grant and the ERC Advanced Investigators Grant ‘Soft-Map’ of S. Bauer. M.K. acknowledges financial support from the Wilhelm Macke Foundation and the mobility programme of the Johannes Kepler University Linz (KIP).
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M.K. and T.Se. designed, fabricated and characterized the transistors and active matrices. J.R., T.Y., K.K. and T.T. performed device fabrication and characterization. S.B.-G., R.S. and S.B. performed the bolometer measurements. I.G., M.D. and S.B. characterized the temperature sensors and thin-film heaters. M.K., J.R., I.G., S.B.-G., S.B., T.Se. and T.So. analysed data and prepared figures with contributions from all authors. M.K., J.R., S.B., T.Se. and T.So. wrote the manuscript with comments from all authors. T.Se., S.B. and T.So. supervised the project and advised on device optimization.
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Supplementary Information
This file contains Supplementary Text, Supplementary Figures 1-17 and additional references. (PDF 12986 kb)
Free-floating, indestructible electronic foil
In the video, an 8 cm by 8 cm tactile sensing foil falls from a height of approximately 2 m together with a goose feather (approximately 12 cm long and 3.5 cm wide, 0.11 g) for comparison. The extreme lightweight design of the electronic foil allows floating in air, the device almost instantly reaches its terminal velocity of only 0.2 m/s. In that way, no damage is caused to the electronic circuit, even when dropped from arbitrary heights. (MOV 3596 kb)
Stop-motion video of a stretchable transistor
Still images were composed into a stop-motion movie showing an ultrathin transistor atop the prestretched VHB elastomer, undergoing repeated compression to 50 % and re-stretching. (MOV 2870 kb)
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Kaltenbrunner, M., Sekitani, T., Reeder, J. et al. An ultra-lightweight design for imperceptible plastic electronics. Nature 499, 458–463 (2013). https://doi.org/10.1038/nature12314
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DOI: https://doi.org/10.1038/nature12314
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