Abstract
Arising from J. A. Scholl, A. L. Koh, & J. A. Dionne Nature 483, 421–427 ()(2012)10.1038/nature10904
The size-dependent properties of a nanoscale object can be studied in two ways. In the top-down approach the nanoscale object is made smaller and smaller. In the bottom–up approach one starts from the smallest possible size—sometimes an atom. Scholl et al.1 studied the electronic properties of silver particles using the top–down approach1. However, experimental2,3,4 and theoretical2,5,6,7,8 results are available from several bottom–up approaches and these results do not support the results of ref. 1.
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References
Scholl, J. A., Koh, A. L. & Dionne, J. A. Quantum plasmon resonances of individual metallic nanoparticles. Nature 483, 421–427 (2012)
Tiggesbäumker, J., Köller, L., Meiwes-Broer, K. H. & Liebsch, A. Blue shift of the Mie plasma frequency in Ag clusters and particles. Phys. Rev. A 48, R1749–R1752 (1993)
Harbich, W., Federigo, S. & Buttet, J. The optical absorption spectra of small silver clusters (n = 8–39) embedded in rare gas matrices. Z. Phys. D 26, 138–140 (1993)
Charlé, K.-P., König, L. & Nepijko, S. Rabin, I. & Schulze, W. The surface plasmon resonance of free and embedded Ag-clusters in the size range 1.5 nm < D < 30 nm. Cryst. Res. Technol. 33, 1085–1096 (1998)
Kasperovich, V. & Kresin, V. V. Ultraviolet absorption spectra of silver and gold nanoclusters. Phil. Mag. 78, 385–396 (1998)
Lermé, J. Size evolution of the surface plasmon resonance damping in nanoparticles: confinement and dielectric effects. J. Phys. Chem. C 115, 14098–14110 (2011)
Bonačić-Koutecky`, V., Veyret, V. & Mitrić, R. Ab initio study of the absorption spectrum of Agn (n = 5–8) clusters. J. Chem. Phys. 114, 10450–10460 (2001)
Yabana, K. & Bertsch, G. F. Optical response of small silver clusters. Phys. Rev. A 60, 3809–3814 (1999)
Kreibig, U. & Vollmer, M. Optical Properties of Metal Clusters (Springer, 1995)
Schmidt, M., Ellert, E., Kronmüller, W. & Haberland, H. Temperature dependence of the optical response of sodium cluster ions Nan + with 4≤n≤16. Phys. Rev. B 59, 10970–10979 (1999)
Bonačić-Koutecky`, V. et al. Ab initio predictions of structural and optical response properties of Nan + clusters: interpretation of depletion spectra at low temperature. J. Chem. Phys. 104, 1427–1440 (1996)
Moseler, M., Hakkinen, H. & Landman, U. Photoabsorption spectra of Nan + clusters: thermal line-broadening mechanisms. Phys. Rev. Lett. 87, 053401 (2001)
Federmann, F., Hoffmann, K., Quaas, N. & Toennies, J.-P. Spectroscopy of extremely cold silver clusters in helium droplets. Eur. Phys. D 9, 11–14 (1999)
Schmidt, M., Cahuzac, Bréchignac, C. & Cheng, H.-P. The stability of free and oxidized silver clusters. J. Chem. Phys. 118, 10956–10962 (2003)
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Haberland, H. Looking from both sides. Nature 494, E1–E2 (2013). https://doi.org/10.1038/nature11886
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DOI: https://doi.org/10.1038/nature11886
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