Thin streams of liquid commonly break up into characteristic droplet patterns owing to the surface-tension-driven Plateau–Rayleigh instability1,2,3. Very similar patterns are observed when initially uniform streams of dry granular material break up into clusters of grains4,5,6, even though flows of macroscopic particles are considered to lack surface tension7,8. Recent studies on freely falling granular streams tracked fluctuations in the stream profile9, but the clustering mechanism remained unresolved because the full evolution of the instability could not be observed. Here we demonstrate that the cluster formation is driven by minute, nanoNewton cohesive forces that arise from a combination of van der Waals interactions and capillary bridges between nanometre-scale surface asperities. Our experiments involve high-speed video imaging of the granular stream in the co-moving frame, control over the properties of the grain surfaces and the use of atomic force microscopy to measure grain–grain interactions. The cohesive forces that we measure correspond to an equivalent surface tension five orders of magnitude below that of ordinary liquids. We find that the shapes of these weakly cohesive, non-thermal clusters of macroscopic particles closely resemble droplets resulting from thermally induced rupture of liquid nanojets10,11,12.
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We thank X. Cheng, R. Cocco, E. Corwin, R. Karri, N. Keim, T. Knowlton, S. Nagel, T. Witten and W. Zhang for discussions and J. Jureller for AFM training and assistance. This work was supported by NSF through its MRSEC programme and the Inter-American Materials Collaboration Chicago-Chile, and by the Keck Initiative for Ultrafast Imaging at the University of Chicago.
This file contains Supplementary Notes and Data, Supplementary Figures 1-4 with Legends and Supplementary References. (PDF 1966 kb)
This file shows a high-speed movie of the break up of a granular stream. The camera falls with the stream to capture the break up of a stream of d = (107 ± 19) μm diameter glass grains falling out of a D0 = 4.0 mm nozzle. The nozzle and reservoir of grains are housed in a 2.5 m tall acrylic tube, which is sealed and evacuated to 0.03 kPa (gas mean free path ~ 200 μm) to reduce air drag. (MOV 3598 kb)
This file shows a high-speed movie of a stream of d = (130 ± 30) μm diameter copper grains. Conditions are otherwise identical to those in Supplementary Movie 1. (MOV 2376 kb)
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Royer, J., Evans, D., Oyarte, L. et al. High-speed tracking of rupture and clustering in freely falling granular streams. Nature 459, 1110–1113 (2009). https://doi.org/10.1038/nature08115
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