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Magnetoelectrics

Is CdCr2S4 a multiferroic relaxor?

Abstract

Arising from: J. Hemberger et al. Nature 434, 364–367 (2005)10.1038/nature03348; Hemberger et al. reply

Materials showing simultaneous ferroelectric and magnetic ordering are attracting a great deal of interest because of their unusual physics and potential applications1. Hemberger et al.2 have reported relaxor-like dielectric properties and colossal magnetocapacitance (in excess of 500%) for the cubic spinel compound CdCr2S4 and related isomorphs3,4,5, concluding that CdCr2S4 is a multiferroic relaxor. We argue here, however, that their results might also be explained by a conductive artefact.

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Figure 1: Temperature of dielectric maxima as a function of alternating-current frequency.
Figure 2: Maxwell–Wagner equivalent circuit model of a heterogeneous lossy dielectric.

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References

  1. Eerenstein, W., Mathur, N. D. & Scott, J. F. Multiferroic and magnetoelectric materials. Nature 442, 759–765 (2006).

    Article  ADS  CAS  Google Scholar 

  2. Hemberger, J. et al. Relaxor ferroelectricity and colossal magnetocapacitive coupling in ferromagnetic CdCr2S4 . Nature 434, 364–367 (2005).

    Article  ADS  CAS  Google Scholar 

  3. Lunkenheimer, P., Fichtl, R., Hemberger, J., Tsurkan, V. & Loidl, A. Relaxation dynamics and colossal magnetocapacitive effect in CdCr2S4 . Phys. Rev. B 72, 60103 (2005).

    Article  ADS  Google Scholar 

  4. Hemberger, J. et al. Multiferroic behavior in CdCr2X4 (X = S, Se). arXiv:cond-mat/0508014 (2005).

  5. Weber, S. et al. Colossal magnetocapacitance and colossal magnetoresistance in HgCr2S4 . Phys. Rev. Lett. 96, 157202 (2006).

    Article  ADS  CAS  Google Scholar 

  6. Lines, M. E. & Glass, A. M. Principles and Applications of Ferroelectrics and Related Materials (Clarendon, Oxford, 1977).

    Google Scholar 

  7. Pintilie, L. & Alexe, M. Ferroelectric-like hysteresis loop in nonferroelectric systems. Appl. Phys. Lett. 87, 112903 (2005).

    Article  ADS  Google Scholar 

  8. Fennie, C. J. & Rabe, K. M. Polar phonons and intrinsic dielectric response of the ferromagnetic insulating spinel CdCr2S4 from first principles. Phys. Rev. B 72, 214123 (2005).

    Article  ADS  Google Scholar 

  9. Koshizuka, N., Ushiodo, S. & Tsushima, T. Resonance scattering in CdCr2S4: magnetic-circular-polarization properties. Phys. Rev. B 21, 1316–1322 (1980).

    Article  ADS  CAS  Google Scholar 

  10. Gnezdilov, V. et al. Evidence for local lattice distortions in giant magnetocapacitive CdCr2S4 . arXiv:cond-mat 0702362 (2007).

  11. Martin, R. M. & Damen, T. C. Breakdown of selection rules in resonance Raman scattering. Phys. Rev. Lett. 26, 86–88 (1971).

    Article  ADS  CAS  Google Scholar 

  12. Catalan, G., O'Neill, D., Bowman, R. M. & Gregg, J. M. Relaxor features in ferroelectric superlattices: a Maxwell–Wagner approach. Appl. Phys. Lett. 77, 3078–3080 (2000).

    Article  ADS  CAS  Google Scholar 

  13. O'Neill, D., Bowman, R. M. & Gregg, J. M. Dielectric enhancement and Maxwell-Wagner effects in ferroelectric superlattice structures. Appl. Phys. Lett. 77, 1520–1522 (2000).

    Article  ADS  CAS  Google Scholar 

  14. Catalan, G. Magnetocapacitance without magnetoelectric coupling. Appl. Phys. Lett. 88, 102902 (2006).

    Article  ADS  Google Scholar 

  15. Brown, W. F. Jr, Hornreich, R. M. & Shtrikman, S. Upper bound on the magnetoelectric susceptibility. Phys. Rev. 168, 574–577 (1968).

    Article  ADS  Google Scholar 

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Catalan, G., Scott, J. Is CdCr2S4 a multiferroic relaxor?. Nature 448, E4–E5 (2007). https://doi.org/10.1038/nature06156

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