Primitive chondritic meteorites contain material (presolar grains1), at the level of a few parts per million, that predates the formation of our Solar System. Astronomical observations2 and the chemical composition of the Sun3 both suggest that silicates must have been the dominant solids in the protoplanetary disk from which the planets of the Solar System formed, but no presolar silicates have been identified in chondrites4,5,6. Here we report the in situ discovery of presolar silicate grains 0.1–1 µm in size in the matrices of two primitive carbonaceous chondrites. These grains are highly enriched in 17O (δ17OSMOW > 100–400‰), but have solar silicon isotopic compositions within analytical uncertainties, suggesting an origin in an oxygen-rich red giant or an asymptotic giant branch star7,8. The estimated abundance of these presolar silicates (3–30 parts per million) is higher than reported for other types of presolar grains in meteorites1, consistent with their ubiquity in the early Solar System, but is about two orders of magnitude lower than their abundance in anhydrous interplanetary dust particles9. This result is best explained by the destruction of silicates during high-temperature processing in the solar nebula.
Access optionsAccess options
Subscribe to Journal
Get full journal access for 1 year
only $3.90 per issue
All prices are NET prices.
VAT will be added later in the checkout.
Rent or Buy article
Get time limited or full article access on ReadCube.
All prices are NET prices.
The authors declare that they have no competing financial interests.
Nittler, L. R. Presolar stardust in meteorites: recent advances and scientific frontiers. Earth Planet. Sci. Lett. 209, 259–273 (2003)
Waters, L. B. F. M. et al. Mineralogy of oxygen-rich dust shells. Astron. Astrophys. 315, L361–L364 (1996)
Anders, E. & Grevesse, N. Abundances of the elements: meteoritic and solar. Geochim. Cosmochim. Acta 53, 197–214 (1989)
Messenger, S. & Bernatowicz, T. J. Search for presolar silicates in Acfer 094. Meteorit. Planet. Sci. 35, A109 (2000)
Alexander, C. M. O'D., Nittler, L. R. & Tera, F. The search of presolar silicates and the 54Cr carrier. Lunar Planet. Sci. [CD-ROM] XXXII, 2191 (2001)
Mostefaoui, S., Hoppe, P., Marhas, K. K. & Gröner, E. Search for in situ presolar oxygen-rich dust in meteorites. Meteorit. Planet. Sci. 38, A99 (2003)
Nittler, L. R., Alexander, C. M. O'D., Gao, X., Walker, R. M. & Zinner, E. Stellar sapphires: The properties and origins of presolar Al2O3 in meteorites. Astrophys. J. 483, 475–495 (1997)
Lugaro, M., Zinner, E., Gallino, R. & Amari, S. Si isotopic ratios in mainstream presolar SiC grains revisited. Astrophys. J. 527, 369–394 (1999)
Messenger, S., Keller, L. P., Stadermann, F. J., Walker, R. M. & Zinner, E. Samples of stars beyond the solar system: silicate grains in interplanetary dust. Science 300, 105–108 (2003)
Newton, J. et al. Acfer 094, a uniquely primitive carbonaceous chondrite from the Sahara. Meteoritics 30, 47–56 (1995)
Greshake, A. The primitive matrix components of the unique carbonaceous chondrite Acfer 094; a TEM study. Geochim. Cosmochim. Acta 61, 437–452 (1997)
Krot, A. N., Meibom, A., Weisberg, M. K. & Keil, K. The CR chondrite clan: implications for early solar system processes. Meteorit. Planet. Sci. 37, 1451–1490 (2002)
Yurimoto, H., Nagashima, K. & Kunihiro, T. High precision isotope micro-imaging of materials. Appl. Surf. Sci. 203–204, 793–797 (2003)
Kunihiro, T., Nagashima, K. & Yurimoto, H. Microscopic oxygen isotopic homogeneity/heterogeneity in the matrix from the Vigarano CV3 chondrite. Geochim. Cosmochim. Acta (submitted)
Hoppe, P. & Ott, U. in Astrophysical Implications of the Laboratory Study of Presolar Materials (eds Bernatowicz, T. J. & Zinner, E.) 27–58 (AIP Press, New York, 1997)
Huss, G. R., Meshik, A. P., Smith, J. B. & Hohenberg, C. M. Presolar diamond, silicon carbide, and graphite in carbonaceous chondrites: Implications for thermal processing in the solar nebula. Geochim. Cosmochim. Acta 67, 4823–4848 (2003)
Dai, Z. R. et al. Possible in situ formation of meteoritic nanodiamonds in the early Solar System. Nature 418, 157–159 (2002)
Jessberger, E. K. et al. in Interplanetary Dust (eds Grün, E., Gustafson, B. Å. S., Dermott, S. F. & Fechtig, H.) 253–294 (Springer, Berlin, 2001)
Bradley, J. P. & Brownlee, D. E. Cometary particles: thin sectioning and electron beam analysis. Science 231, 1542–1544 (1986)
Hewins, R. H. in Chondrules and the Protoplanetary Disk (eds Hewins, R. H., Jones, R. H. & Scott, E. R. D.) 3–9 (Cambridge Univ. Press, Cambridge, 1996)
Itoh, S. & Yurimoto, H. Contemporaneous formation of chondrules and refractory inclusions in the early Solar System. Nature 423, 728–731 (2003)
Bischoff, A. et al. New carbonaceous and type 3 ordinary chondrites from the Sahara Desert. Meteoritics 26, 318 (1991)
Clayton, R. N. & Mayeda, T. K. Oxygen isotope studies of carbonaceous chondrites. Geochim. Cosmochim. Acta 63, 2089–2104 (1999)
We thank E. R. D. Scott for discussions, and I. Takayanagi, K. Kosaka and Suzushin-Kogyo for assistance with SCAPS development. This work was supported by Monkasho (H.Y.) and NASA (A.N.K.).
About this article
Correlated nanoscale characterization of a unique complex oxygen-rich stardust grain: Implications for circumstellar dust formation
Geochimica et Cosmochimica Acta (2018)
Meteoritics & Planetary Science (2018)
Reviews in Mineralogy and Geochemistry (2018)
Journal of Structural Chemistry (2018)