Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates

Abstract

Parallel processes for patterning densely packed nanometre-scale structures are critical for many diverse areas of nanotechnology. Thin films of diblock copolymers1,2,3,4,5,6,7,8,9,10,11 can self-assemble into ordered periodic structures at the molecular scale (5 to 50 nm), and have been used as templates to fabricate quantum dots1,2, nanowires3,4,5, magnetic storage media6, nanopores7 and silicon capacitors8. Unfortunately, perfect periodic domain ordering can only be achieved over micrometre-scale areas at best12,13 and defects exist at the edges of grain boundaries. These limitations preclude the use of block-copolymer lithography for many advanced applications14. Graphoepitaxy12,15, in-plane electric fields3,16, temperature gradients17, and directional solidification14,18 have also been demonstrated to induce orientation or long-range order with varying degrees of success. Here we demonstrate the integration of thin films of block copolymer with advanced lithographic techniques to induce epitaxial self-assembly of domains. The resulting patterns are defect-free, are oriented and registered with the underlying substrate and can be created over arbitrarily large areas. These structures are determined by the size and quality of the lithographically defined surface pattern rather than by the inherent limitations of the self-assembly process. Our results illustrate how hybrid strategies to nanofabrication allow for molecular level control in existing manufacturing processes.

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Figure 1: Schematic representation of the strategy used to create chemically nanopatterned surfaces and investigate the epitaxial assembly of block-copolymer domains.
Figure 2: Top-down SEM images of photoresist and PS-b-PMMA copolymer (Lo = 48 nm, film thickness of 60 nm) patterns.
Figure 3: Top-down SEM images and corresponding Fourier transform analysis of PS-b-PMMA copolymer films (Lo = 48 nm, film thickness of 60 nm) on chemically nanopatterned surfaces.
Figure 4: Cross-sectional SEM images of PS-b-PMMA films (Lo = 48 nm, thickness 60 nm) on unpatterned and chemically nanopatterned surfaces.

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Acknowledgements

We thank F. Cerrina, E. W. Edwards and S. Xiao for discussions, and V. Golovkina and J. Wallace for assistance with the EUV-IL system. This work was supported by the Semiconductor Research Corporation, the National Science Foundation through the Materials Research Science and Engineering Center, and the Camille Dreyfus Teacher-Scholar Award. S.K. acknowledges a research fellowship from the Post-Doctoral Fellowship Program of the Korea Science and Engineering Foundation. Facilities and staff of the CNTech were supported by DARPA and the Intel Corporation, and the Synchrotron Radiation Center is supported by the National Science Foundation.

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Correspondence to Paul F. Nealey.

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Ouk Kim, S., Solak, H., Stoykovich, M. et al. Epitaxial self-assembly of block copolymers on lithographically defined nanopatterned substrates. Nature 424, 411–414 (2003). https://doi.org/10.1038/nature01775

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