Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Volcanically emitted sodium chloride as a source for Io's neutral clouds and plasma torus

Abstract

The atmosphere of Jupiter's satellite Io is extremely tenuous, time variable and spatially heterogeneous. Only a few molecules—SO2, SO and S2—have previously been identified as constituents of this atmosphere, and possible sources1,2,3,4 include frost sublimation, surface sputtering and active volcanism. Io has been known5,6 for almost 30 years to be surrounded by a cloud of Na, which requires an as yet unidentified atmospheric source of sodium. Sodium chloride has been recently proposed as an important atmospheric constituent, based on the detection of chlorine in Io's plasma torus7,8 and models of Io's volcanic gases9 . Here we report the detection of NaCl in Io's atmosphere; it constitutes only 0.3% when averaged over the entire disk, but is probably restricted to smaller regions than SO2 because of its rapid photolysis and surface condensation10. Although the inferred abundance of NaCl in volcanic gases is lower than predicted9, those volcanic emissions provide an important source of Na and Cl in Io's neutral clouds and plasma torus.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Overview of the NaCl observations.
Figure 2: The SO2 and NaCl 15 and 17 January observations, compared to various models.

Similar content being viewed by others

References

  1. Spencer, J. R. & Schneider, N. M. Io on the eve of the Galileo mission. Annu. Rev. Earth Planet Sci. 24, 125–190 (1996)

    Article  ADS  CAS  Google Scholar 

  2. Lellouch, E. Io's atmosphere: not yet understood. Icarus 124, 1–21 (1996)

    Article  ADS  CAS  Google Scholar 

  3. McGrath, M. A., Belton, M. J. S., Spencer, J. R. & Sartoretti, P. Spatially resolve spectroscopy of Io's Pele plume and SO2 atmosphere. Icarus 146, 476–493 (2000)

    Article  ADS  CAS  Google Scholar 

  4. Spencer, J. R. et al. Discovery of gaseous S2 in Io's Pele plume. Science 288, 1208–1210 (2000)

    Article  ADS  CAS  Google Scholar 

  5. Brown, R. A. in Exploration of the Solar System (eds Woszczyk, A. & Iwaniszewska, C.) 531–537 (Reider, Hingham, MA, 1974)

    Google Scholar 

  6. Trafton, L., Parkinson, T. & Macy, W. The spatial extent of sodium emission around Io. Astrophys. J. 190, L85–L89 (1974)

    Article  ADS  CAS  Google Scholar 

  7. Kueppers, M. & Schneider, N. M. Discovery of chlorine in the Io torus. Geophys. Res. Lett. 27, 513–516 (2000)

    Article  ADS  Google Scholar 

  8. Feldman, P. D. et al. Detection of chlorine ions in the Far Ultraviolet Spectrum Explorer spectrum of the Io plasma torus. Astrophys. J. 554, L123–L126 (2001)

    Article  ADS  CAS  Google Scholar 

  9. Fegley, B. Jr & Zolotov, M. Yu. Jr Chemistry of sodium, potassium, and chlorine in volcanic gases on Io. Icarus 148, 139–210 (2000)

    Article  Google Scholar 

  10. Moses, J. I., Zolotov, M. Yu. & Fegley, B. Jr Alkali and chlorine photochemistry in a volcanically driven atmosphere on Io. Icarus 156, 107–135 (2000)

    Article  ADS  Google Scholar 

  11. Lellouch, E. et al. The structure, stability, and global distribution of Io's atmosphere. Icarus 98, 271–295 (1992)

    Article  ADS  CAS  Google Scholar 

  12. Lellouch, E. et al. Detection of sulfur monoxide in Io's atmosphere. Astrophys. J. 459, L107–L110 (1996)

    Article  ADS  CAS  Google Scholar 

  13. Pickett, H. M. et al. Submillimeter, millimeter, and microwave spectral line catalog. J. Quant. Spectrosc. Rad. Transfer 60, 883–890 (1998)

    Article  ADS  CAS  Google Scholar 

  14. Ewing, C. T. & Stern, K. H. Equilibrium vaporization rates and vapor pressures of solid and liquid sodium chloride, potassium chloride, potassium bromide, cesium iodide, and lithium fluoride. J. Phys. Chem. 78, 1998–2005 (1974)

    Article  CAS  Google Scholar 

  15. Lanzerotti, L. J. et al. Laboratory studies of charged particle erosion of SO2 ice and applications to the frosts of Io. Astrophys. J. 259, 920–929 (1982)

    Article  ADS  CAS  Google Scholar 

  16. Moses, J. I., Zolotov, M. Yu. & Fegley, B. Jr Photochemistry of a volcanically driven atmosphere on Io: sulfur and oxygen species from a Pele-type eruption. Icarus 156, 76–106 (2000)

    Article  ADS  Google Scholar 

  17. Ingersoll, A. P., Summers, M. E. & Schlipf, S. G. Supersonic meteorology of Io: sublimation driven flow of SO2 . Icarus 64, 375–390 (1985)

    Article  ADS  CAS  Google Scholar 

  18. Summers, M. E. & Strobel, D. F. Photochemistry and vertical transport in Io's atmosphere and ionosphere. Icarus 120, 290–316 (1996)

    Article  ADS  CAS  Google Scholar 

  19. Strobel, D. F. & Wolven, B. C. The atmosphere of Io: abundances and sources of sulfur dioxide and atomic hydrogen. Astrophys. Space Sci. 277, 271–287 (2000)

    Article  ADS  Google Scholar 

  20. Kuskov, O. & Kronrod, V. A. Core sizes and internal structure of Earth's and Jupiter's satellites. Icarus 151, 204–227 (2001)

    Article  ADS  CAS  Google Scholar 

  21. Thomas, N. Optical observations of Io's neutral clouds and plasma torus. Surv. Geophys. 13, 91–164 (1992)

    Article  ADS  Google Scholar 

  22. Schneider, N. M. et al. Molecular origin for Io's fast sodium. Science 253, 1394–1397 (1991)

    Article  ADS  CAS  Google Scholar 

  23. Wilson, J. K. & Schneider, N. M. Io's fast sodium: implications for molecular and atomic atmospheric escape. Icarus 111, 31–44 (1994)

    Article  ADS  CAS  Google Scholar 

  24. Johnson, R. E. Formation of Na-containing molecular ions at Io. Icarus 111, 65–72 (1994)

    Article  ADS  CAS  Google Scholar 

  25. Schneider, N. M., Park, A. H. & Kueppers, M. Spectroscopic studies of the Io torus during Galileo encounters: remote plasma diagnostics and the detection of Cl++. Bull. Am. Astron. Soc. 32, 35.03 (2000)

    Google Scholar 

  26. Bagenal, F. & Sullivan, J. D. Direct plasma measurements in the Io torus and inner magnetosphere of Jupiter. J. Geophys. Res. 86, 8447–8466 (1981)

    Article  ADS  CAS  Google Scholar 

  27. Altenhoff, W. J. et al. First radio astronomical estimate of the temperature of Pluto. Astron. Astrophys. 190, L15–L17 (1988)

    ADS  Google Scholar 

  28. Brown, M. E. Potassium in Europa's atmosphere. Icarus 151, 190–195 (2001)

    Article  ADS  CAS  Google Scholar 

Download references

Acknowledgements

We thank W. Thuillot for providing us with the topocentric velocities of Io necessary for the data reduction.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. Lellouch.

Ethics declarations

Competing interests

The authors declare that they have no competing financial interests.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lellouch, E., Paubert, G., Moses, J. et al. Volcanically emitted sodium chloride as a source for Io's neutral clouds and plasma torus. Nature 421, 45–47 (2003). https://doi.org/10.1038/nature01292

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nature01292

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing