Abstract
Grains of dust that pre-date the Sun provide insights into their formation around other stars and into the early evolution of the Solar System1,2,3,4. Nanodiamonds recovered from meteorites, which originate in asteroids, have been thought to be the most abundant type of presolar grain3,4. If that is true, then nanodiamonds should be at least as abundant in comets, because they are thought to have formed further out in the early Solar System than the asteroid parent bodies, and because they should be more pristine5,6,7. Here we report that nanodiamonds are absent or very depleted in fragile, carbon-rich interplanetary dust particles, some of which enter the atmosphere at speeds within the range of cometary meteors8,9. One interpretation of the results is that some (perhaps most) nanodiamonds formed within the inner Solar System and are not presolar at all, consistent with the recent detection of nanodiamonds within the accretion discs of other young stars10. An alternative explanation is that all meteoritic nanodiamonds are indeed presolar, but that their abundance decreases with heliocentric distance, in which case our understanding of large-scale transport and circulation within the early Solar System is incomplete11.
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References
Hoppe, P. & Zinner, E. Presolar dust grains from meteorites and their stellar sources. J. Geophys. Res. 510, 10371–10385 (2000)
Daulton, T. L., Eisenhour, D. D., Bernatowicz, T. J., Lewis, R. S. & Buseck, P. R. Genesis of presolar diamonds: comparative high-resolution transmission electron microscopy study of meteoritic and terrestrial nano-diamonds. Geochim. Cosmochim. Acta 60, 4853–4872 (1996)
Anders, E. & Zinner, E. Interstellar grains in primitive meteorites: diamond, silicon carbide, and graphite. Meteoritics 28, 490–514 (1993)
Bernatowicz, T. J. & Walker, R. M. Ancient stardust in the laboratory. Phys. Today 50, 26–32 (1997)
Farinella, P., Gonzi, R. & Froeschle, C. The injection of asteroid fragments into resonances. Icarus 101, 174–187 (1993)
Greenberg, J. M. in Comets (ed. Wilkening, L. L.) 131–162 (Univ. Arizona Press, Tucson, 1982)
Huss, G. in Astrophysical Implications of the Laboratory Study of Presolar Materials (eds Bernatowicz, T. & Zinner, E.) 721–748 (AIP Press, New York, 1997)
Bradley, J. P. & Brownlee, D. E. Cometary particles: thin-sectioning and electron-beam analysis. Science 231, 1542–1544 (1984)
Brownlee, D. E. et al. Identification of individual cometary IDPs by thermally stepped He release. Lunar Planet Sci. XXVI, 183–184 (1995)
Van Kerckhoven, C., Tielens, A. G. G. M. & Waelkens, C. Nanodiamonds around HD 97048 and Elias 1. Astron. Astrophys. 384, 568–584 (2002)
Hill, H. G. M., Grady, C. A., Nuth, J. A., Hallenbeck, S. L. & Sitko, M. L. Constraints on nebular dynamics and chemistry based on observations of annealed magnesium silicate grains in comets and in disks around Herbig Ae and Be stars. Proc. Natl Acad. Sci. USA 98, 2182–2187 (2001)
Bernatowicz, T. J. & Gibbons, P. C. Electron energy-loss spectroscopy of interstellar diamonds. Astrophys. J. 359, 246–255 (1990)
Brownlee, D. E., Joswiak, D. J., Bradley, J. P., Gezo, J. C. & Hill, H. G. M. Spatially resolved acid dissolution of IDPs: the state of carbon and the abundance of diamonds in the dust. Lunar Planet. Sci. XXXI, 1921–1922 (2000)
Messenger, S. Identification of molecular cloud material in interplanetary dust particles. Nature 404, 968–971 (2000)
Bradley, J. P. & Brownlee, D. E. An interplanetary dust particle linked to type CM meteorites and an asteroidal origin. Science 251, 489–596 (1992)
Thomas, K. L. et al. An asteroidal breccia: The anatomy of a cluster IDP. Geochim. Cosmochim. Acta 59, 2797–2815 (1995)
Luu, J. X. Spectral diversity among the nuclei of comets. Icarus 104, 138–148 (1993)
Russell, S. S., Arden, J. W. & Pillinger, C. T. A carbon and nitrogen isotope study of diamond from primitive meteorites. Meteorit. Planet. Sci. 31, 343–355 (1996)
Huss, G. R. & Lewis, R. S. Noble gases in presolar diamonds. I, Three distinct components and their implications for diamond origins. Meteoritics 29, 791–810 (1994)
Sylvester, R. J. in Solid Interstellar Matter: The ISO Revolution (eds d'Hendecourt, L., Joblin, C. & Jones, A.) 263–276 (Springer, New York, 1999)
Hill, H. G. M., Jones, A. P. & d'Hendecourt, L. B. Diamonds in carbon-rich proto-planetary nebulae. Astron. Astrophys. 336, L41–L44 (1998)
Guillois, O., Ledoux, G. & Reynaud, C. Diamond infrared emission bands in circumstellar media. Astrophys. J. 521, L133–L136 (1999)
Lodders, K. & Palme, H. in Protostars and Planets IV (eds Krot, A. N. & Fegley, B.) 1019–1053 (Univ. Arizona Press, Tucson, 2000)
Howard, W. et al. Synthesis of diamond powder in acetylene oxygen plasma. J. Appl. Phys. 68, 1247–1251 (1990)
Liou, J.-C., Zook, H. A. & Dermott, S. F. Kuiper belt dust grains as a source of interplanetary dust particles. Icarus 124, 429–440 (1996)
Bradley, J. P. Chemically anomalous, pre-accretionally irradiated grains in interplanetary dust particles from comets. Science 265, 925–927 (1992)
Thomas, K. L., Blanford, G. E., Keller, L. P., Klöck, W. & McKay, D. S. Carbon abundance and silicate mineralogy of anhydrous interplanetary dust particles. Geochim. Cosmochim. Acta 57, 1551–1566 (1993)
Schramm, L. S., Brownlee, D. E. & Wheelock, M. M. Major element compositions of stratospheric micrometeorites. Meteoritics 24, 99–112 (1989)
Acknowledgements
We thank T. Bernatowicz for bulk nanodiamond extracts, A.W. Phelps for discussions, and G. Huss for comments and suggestions. This work was supported by NASA and the Georgia Tech Electron Microscopy Center. H.G.M.H. acknowledges support from the NAS/NRC RRA programme.
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Dai, Z., Bradley, J., Joswiak, D. et al. Possible in situ formation of meteoritic nanodiamonds in the early Solar System. Nature 418, 157–159 (2002). https://doi.org/10.1038/nature00897
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DOI: https://doi.org/10.1038/nature00897
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