Liquid–vapour phase change is a useful and efficient process to transfer energy in nature, as well as in numerous domestic and industrial applications. Relatively recent advances in altering surface chemistry, and in the formation of micro- and nanoscale features on surfaces, have led to exciting improvements in liquid–vapour phase-change performance and better understanding of the underlying science. In this Review, we present an overview of the surface, thermal and material science to illustrate how new materials and designs can improve boiling and condensation. There are many parallels between boiling and condensation, such as nucleation of a phase and its departure from a surface; however, the particular set of challenges associated with each phenomenon results in different material designs used in different manners. We also discuss alternative techniques, such as introducing heterogeneous surface chemistry or direct real-time manipulation of the phase-change process, which can offer further control of heat-transfer processes. Finally, long-term robustness is essential to ensure reliability and feasibility but remains a key challenge.
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Kehlhofer, R. Combined-Cycle Gas and Steam Turbine Power Plants (PennWell, 2009).
Hansen, J. D., Johnson, J. A. & Winter, D. A. History and use of heat in pest control: a review. Int. J. Pest Manag. 57, 267–289 (2011).
Mattila-Sandholm, T. & Wirtanen, G. Biofilm formation in the industry: a review. Food Rev. Int. 8, 573–603 (1992).
Haryanto, A., Fernando, S., Murali, N. & Adhikari, S. Current status of hydrogen production techniques by steam reforming of ethanol: a review. Energy Fuels 19, 2098–2106 (2005).
Humplik, T. et al. Nanostructured materials for water desalination. Nanotechnology 22, 292001 (2011).
Vasiliev, L. L. Heat pipes in modern heat exchangers. Appl. Therm. Eng. 25, 1–19 (2005).
Lee, A., Moon, M. W., Lim, H., Kim, W. D. & Kim, H. Y. Water harvest via dewing. Langmuir 28, 10183–10191 (2012).
Barbosa, J. R., Ribeiro, G. B. & de Oliveira, P. A. A. State-of-the-art review of compact vapor compression refrigeration systems and their applications. Heat Transfer Eng. 33, 356–374 (2012).
Ghasemi, H. et al. Solar steam generation by heat localization. Nat. Commun. 5, 4449 (2014).
Yang, S. et al. Condition monitoring for device reliability in power electronic converters: a review. Power Electron. IEEE Trans. 25, 2734–2752 (2010).
Shakouri, A. Nanoscale thermal transport and microrefrigerators on a chip. Proc. IEEE 94, 1613–1638 (2006).
Bergles, A. E. ExHFT for fourth generation heat transfer technology. Exp. Therm. Fluid Sci. 26, 335–344 (2002).
Hummel, R. L. Means for increasing the heat transfer coefficient between a wall and boiling liquid. US Patent 3207209 (1965).
Kolb, W. B. & Huelsman, G. L. Component separation system including condensing mechanism. US Patent 5980697 (1999).
Hao, C. et al. Bioinspired interfacial materials with enhanced drop mobility: from fundamentals to multifunctional applications. Small 12, 1825–1839 (2016).
Patankar, N. A. Supernucleating surfaces for nucleate boiling and dropwise condensation heat transfer. Soft Matter 6, 1613 (2010).
Carey, V. Liquid–Vapor Phase-Change Phenomena: An Introduction to the Thermophysics of Vaporization and Condensation Processes in Heat Transfer Equipment (CRC Press, 1992).
Fletcher, N. H. Size effect in heterogeneous nucleation. J. Chem. Phys. 29, 572 (1958).
Jones, S. Bubble nucleation from gas cavities — a review. Adv. Colloid Interface Sci. 80, 27–50 (1999).
Wang, C. H. & Dhir, V. K. Effect of surface wettability on active nucleation site density during pool boiling of water on a vertical surface. J. Heat Transfer 115, 659 (1993). This boiling study investigates how the intrinsic contact angle of a smooth surface affects nucleation, HTC and CHF.
Varanasi, K. K., Hsu, M., Bhate, N., Yang, W. S. & Deng, T. Spatial control in the heterogeneous nucleation of water. Appl. Phys. Lett. 95, 94101–94103 (2009). This condensation study is the first to demonstrate spatial control of the nucleation of water.
Son, G. & Dhir, V. K. Dynamics and heat transfer associated with a single bubble during nucleate boiling on a horizontal surface. J. Heat Transfer 121, 623–631 (2015).
Chavan, S. et al. Heat transfer through a condensate droplet on hydrophobic and nanostructured superhydrophobic surfaces. Langmuir 32, 7774–7787 (2016).
Narhe, R. D. & Beysens, D. A. Water condensation on a super-hydrophobic spike surface. Europhys. Lett. 75, 98–104 (2007).
Narhe, R. D. & Beysens, D. A. Nucleation and growth on a superhydrophobic grooved surface. Phys. Rev. Lett. 93, 076103 (2004).
Narhe, R. D. & Beysens, D. A. Growth dynamics of water drops on a square-pattern rough hydrophobic surface. Langmuir 23, 6486–6489 (2007).
Lafuma, A. & Quéré, D. Superhydrophobic states. Nat. Mater. 2, 457–460 (2003).
Miljkovic, N. & Wang, E. N. Condensation heat transfer on superhydrophobic surfaces. MRS Bull. 38, 397–406 (2013).
Miljkovic, N., Enright, R. & Wang, E. N. Effect of droplet morphology on growth dynamics and heat transfer during condensation on superhydrophobic nanostructured surfaces. ACS Nano 6, 1776–1785 (2012).
Thome, J. R. Boiling in microchannels: a review of experiment and theory. Int. J. Heat Fluid Flow 25, 128–139 (2004).
Son, Y. & Kim, C. Spreading of inkjet droplet of non-Newtonian fluid on solid surface with controlled contact angle at low Weber and Reynolds numbers. J. Non-Newton. Fluid Mech. 162, 78–87 (2009).
Kandlikar, S. G. A theoretical model to predict pool boiling CHF incorporating effects of contact angle and orientation. J. Heat Transfer 123, 1071–1079 (2001).
Wenzel, R. N. Resistance of solid surfaces to wetting by water. Ind. Eng. Chem. 28, 988–994 (1936).
O'Hanley, H. et al. Separate effects of surface roughness, wettability, and porosity on the boiling critical heat flux. Appl. Phys. Lett. 103, 24102 (2013). This parametric boiling study examines the effects of structure, porosity and intrinsic contact angle on CHF.
Li, C. et al. Nanostructured copper interfaces for enhanced boiling. Small 4, 1084–1088 (2008).
Kim, S. et al. Effects of nano-fluid and surfaces with nano structure on the increase of CHF. Exp. Therm. Fluid Sci. 34, 487–495 (2010).
Chen, R. et al. Nanowires for enhanced boiling heat transfer. Nano Lett. 9, 548–553 (2009).
Chu, K.-H., Enright, R. & Wang, E. N. Structured surfaces for enhanced pool boiling heat transfer. Appl. Phys. Lett. 100, 241603 (2012).
Chu, K.-H., Soo Joung, Y., Enright, R., Buie, C. R. & Wang, E. N. Hierarchically structured surfaces for boiling critical heat flux enhancement. Appl. Phys. Lett. 102, 151602 (2013).
Rahman, M. M., Ölçerogˇlu, E. & McCarthy, M. Role of wickability on the critical heat flux of structured superhydrophilic surfaces. Langmuir 30, 11225–11234 (2014). This boiling study introduces the material quantity of ‘wickability‘ and shows that it correlates well with CHF.
Liter, S. G. & Kaviany, M. Pool-boiling CHF enhancement by modulated porous-layer coating: theory and experiment. Int. J. Heat Mass Transfer 44, 4287–4311 (2001).
Kwark, S. M., Kumar, R., Moreno, G., Yoo, J. & You, S. M. Pool boiling characteristics of low concentration nanofluids. Int. J. Heat Mass Transfer 53, 972–981 (2010).
Liu, Z.-h. & Liao, L. Sorption and agglutination phenomenon of nanofluids on a plain heating surface during pool boiling. Int. J. Heat Mass Transfer 51, 2593–2602 (2008).
Attinger, D. et al. Surface engineering for phase change heat transfer: a review. MRS Energy Sustainability 1, E4 (2014). This comprehensive review of boiling and condensation work details much of the surface engineering involved in fabricating various surfaces.
You, S. M., Kim, J. H. & Kim, K. H. Effect of nanoparticles on critical heat flux of water in pool boiling heat transfer. Appl. Phys. Lett. 83, 3374–3376 (2003).
Kim, S. J., Bang, I. C., Buongiorno, J. & Hu, L. W. Surface wettability change during pool boiling of nanofluids and its effect on critical heat flux. Int. J. Heat Mass Transfer 50, 4105–4116 (2007).
Kruse, C. et al. Extraordinary shifts of the Leidenfrost temperature from multiscale micro/nanostructured surfaces. Langmuir 29, 9798–9806 (2013).
Kwon, H., Bird, J. C. & Varanasi, K. K. Increasing Leidenfrost point using micro–nano hierarchical surface structures. Appl. Phys. Lett. 103, 201601 (2013).
Adera, S., Raj, R., Enright, R. & Wang, E. N. Non-wetting droplets on hot superhydrophilic surfaces. Nat. Commun. 4, 2518 (2013).
Li, J. et al. Directional transport of high-temperature Janus droplets mediated by structural topography. Nat. Phys. 12, 1–8 (2016).
Kim, H., Buongiorno, J., Hu, L.-W. & McKrell, T. Nanoparticle deposition effects on the minimum heat flux point and quench front speed during quenching in water-based alumina nanofluids. Int. J. Heat Mass Transfer 53, 1542–1553 (2010).
Kim, J. Spray cooling heat transfer: the state of the art. Int. J. Heat Fluid Flow 28, 753–767 (2007).
Dhillon, N. S., Buongiorno, J. & Varanasi, K. K. Critical heat flux maxima during boiling crisis on textured surfaces. Nat. Commun. 6, 8247 (2015).
Wang, H. S. & Rose, J. W. Film condensation in horizontal microchannels: effect of channel shape. Int. J. Therm. Sci. 45, 1205–1212 (2006).
Wanniarachchi, A. S., Marto, P. J. & Rose, J. W. Film condensation of steam on horizontal finned tubes: effect of fin spacing. J. Heat Transfer 108, 960–966 (1986).
Yau, K. K., Cooper, J. R. & Rose, J. W. Effect of fin spacing on the performance of horizontal integral-fin condenser tubes. J. Heat Transfer 107, 377–383 (1985).
Tanasawa, I. & Utaka, Y. Measurement of condensation curves for dropwise condensation of steam at atmospheric pressure. J. Heat Transfer 105, 633–638 (1983).
Stylianou, S. A. & Rose, J. W. Dropwise condensation on surfaces having different thermal-conductivities. J. Heat Transfer 102, 477–482 (1980).
Wilmhurst, R. Heat Transfer During Dropwise Condensation of Steam, Ethane 1,2 Diol, Aniline and Nitrobenzene. Thesis, Queen Mary, Univ. London (1979).
Schmidt, E., Schurig, W. & Sellschopp, W. Versuche über die Kondensation von Wasserdampf in Film- und Tropfenform. Tech. Mech. Thermodyn. 1, 53–63 (1930).
Nagle, W., Bays, G., Blenderman, L. & Drew, T. Heat-transfer coefficients during dropwise condensation of steam. Trans. Am. Inst. Chem. Eng. 31, 593–621 (1935).
Gnam, E. Tropfenkondensation von Wasserdampf. VDI Forsch. 382, 17–31 (1937).
Fitzpatrick, J., Baum, S. & McAdams, W. Dropwise condensation of steam on vertical tubes. Trans. Am. Inst. Chem. Eng. 35, 97–107 (1939).
Shea, F. & Krase, N. Drop-wise and film condensation of steam. Trans. Am. Inst. Chem. Eng. 36, 463–490 (1940).
Le Fevre, E. J. & Rose, J. Heat-transfer measurements during dropwise condensation of steam. Int. J. Heat Mass Transfer 7, 272–273 (1964).
Le Fevre, E. J. & Rose, J. W. An experimental study of heat transfer by dropwise condensation. Int. J. Heat Mass Transfer 8, 1117–1133 (1965).
Aksan, S. N. & Rose, J. W. Dropwise condensation: the effect thermal properties of the condenser. Int. J. Heat Mass Transfer 16, 461–467 (1973).
Leipertz, A. & Koch, G. Dropwise condensation of steam on hard coated surfaces. Heat Transfer 6, 379–384 (1998).
Kim, S. & Kim, K. J. Dropwise condensation modeling suitable for superhydrophobic surfaces. J. Heat Transfer 133, 81502 (2011).
Miljkovic, N., Preston, D. J. & Wang, E. N. in Encyclopedia of Two-Phase Heat Transfer and Flow II (eds Thome, J. & Kim, J. ) 85–131 (World Scientific, 2015).
Paxson, A. T., Yague, J. L., Gleason, K. K. & Varanasi, K. K. Stable dropwise condensation for enhancing heat transfer via the initiated chemical vapor deposition (iCVD) of grafted polymer films. Adv. Mater. 26, 418–423 (2013).
Leipertz, A. & Froba, A. P. Improvement of condensation heat transfer by surface modifications. Heat Transfer Eng. 29, 343–356 (2008).
Erb, R. A. Wettability of gold. J. Phys. Chem. 72, 2412–2417 (1968).
Azimi, G., Dhiman, R., Kwon, H.-M., Paxson, A. T. & Varanasi, K. K. Hydrophobicity of rare-earth oxide ceramics. Nat. Mater. 12, 315–320 (2013).
Preston, D. J., Mafra, D. L., Miljkovic, N., Kong, J. & Wang, E. N. Scalable graphene coatings for enhanced condensation heat transfer. Nano Lett. 15, 2902–2909 (2015).
Enright, R., Miljkovic, N., Al-Obeidi, A., Thompson, C. V. & Wang, E. N. Condensation on superhydrophobic surfaces: the role of local energy barriers and structure length scale. Langmuir 28, 14424–14432 (2012). This paper introduces the concept of local energy barriers that determine whether suspended or partially wetting regimes are favoured.
Miljkovic, N. et al. Jumping-droplet-enhanced condensation on scalable superhydrophobic nanostructured surfaces. Nano Lett. 13, 179–187 (2013). This condensation study is the first to show experimental heat transfer measurements of jumping-droplet condensation.
Torresin, D., Tiwari, M. K., Del Col, D. & Poulikakos, D. Flow condensation on copper-based nanotextured superhydrophobic surfaces. Langmuir 29, 840–848 (2013).
Cheng, J., Vandadi, A. & Chen, C.-L. Condensation heat transfer on two-tier superhydrophobic surfaces. Appl. Phys. Lett. 101, 131909 (2012).
Enright, R. et al. How coalescing droplets jump. ACS Nano 8, 10352–10362 (2014).
Nam, Y., Kim, H. & Shin, S. Energy and hydrodynamic analyses of coalescence-induced jumping droplets. Appl. Phys. Lett. 103, 161601 (2013).
Liu, T. Q., Sun, W., Sun, X. Y. & Ai, H. R. Mechanism study of condensed drops jumping on super-hydrophobic surfaces. Colloids Surf. A 414, 366–374 (2012).
Wang, F. C., Yang, F. & Zhao, Y. P. Size effect on the coalescence-induced self-propelled droplet. Appl. Phys. Lett. 98, 1–3 (2011).
Cavalli, A. et al. Electrically induced drop detachment and ejection. Phys. Fluids 28, 22101 (2016).
Miljkovic, N., Preston, D. J., Enright, R. & Wang, E. N. Electrostatic charging of jumping droplets. Nat. Commun. 4, 2517 (2013).
Cha, H., Chun, J. M., Sotelo, J. & Miljkovic, N. Focal plane shift imaging for the analysis of dynamic wetting processes. ACS Nano 10, 8223–8232 (2016).
Chen, X., Patel, R. S., Weibel, J. A. & Garimella, S. V. Coalescence-induced jumping of multiple condensate droplets on hierarchical superhydrophobic surfaces. Sci. Rep. 6, 18649 (2016).
Chen, C. H. et al. Dropwise condensation on superhydrophobic surfaces with two-tier roughness. Appl. Phys. Lett. 90, 173103–173108 (2007).
Boreyko, J. B. & Chen, C. H. Self-propelled dropwise condensate on superhydrophobic surfaces. Phys. Rev. Lett. 103, 184501–184504 (2009).
Miljkovic, N., Enright, R. & Wang, E. N. Modeling and optimization of superhydrophobic condensation. J. Heat Transfer 135, 111004 (2013).
Preston, D. J., Miljkovic, N., Enright, R. & Wang, E. N. Jumping droplet electrostatic charging and effect on vapor drag. J. Heat Transfer 136, 80909 (2014).
Miljkovic, N., Preston, D. J., Enright, R. & Wang, E. N. Electric-field-enhanced condensation on superhydrophobic nanostructured surfaces. ACS Nano 7, 11043–11054 (2013).
Yanagisawa, K., Sakai, M., Isobe, T., Matsushita, S. & Nakajima, A. Investigation of droplet jumping on superhydrophobic coatings during dew condensation by the observation from two directions. Appl. Surf. Sci. 315, 212–221 (2014).
Birbarah, P., Li, Z., Pauls, A. & Miljkovic, N. A. Comprehensive model of electric-field-enhanced jumping-droplet condensation on superhydrophobic surfaces. Langmuir 31, 7885–7896 (2015).
Chen, X. M. et al. Nanograssed micropyramidal architectures for continuous dropwise condensation. Adv. Funct. Mater. 21, 4617–4623 (2011).
Rykaczewski, K. et al. Multimode multidrop serial coalescence effects during condensation on hierarchical superhydrophobic surfaces. Langmuir 29, 881–891 (2013).
Boreyko, J. B. & Chen, C. H. Vapor chambers with jumping-drop liquid return from superhydrophobic condensers. Int. J. Heat Mass Transfer 61, 409–418 (2013).
Boreyko, J. B., Zhao, Y. J. & Chen, C. H. Planar jumping-drop thermal diodes. Appl. Phys. Lett. 99, 234105 (2011).
Zhang, K. et al. Self-propelled droplet removal from hydrophobic fiber-based coalescers. Phys. Rev. Lett. 115, 74502 (2015).
Wisdom, K. M. et al. Self-cleaning of superhydrophobic surfaces by self-propelled jumping condensate. Proc. Natl Acad. Sci. USA 116, 7992–7997 (2013).
Watson, G. S., Gellender, M. & Watson, J. A. Self-propulsion of dew drops on lotus leaves: a potential mechanism for self cleaning. Biofouling 30, 427–434 (2014).
Feng, J., Qin, Z. Q. & Yao, S. H. Factors affecting the spontaneous motion of condensate drops on superhydrophobic copper surfaces. Langmuir 28, 6067–6075 (2012).
Feng, J., Pang, Y., Qin, Z., Ma, R. & Yao, S. Why condensate drops can spontaneously move away on some superhydrophobic surfaces but not on others. ACS Appl. Mater. Interfaces 4, 6618–6625 (2012).
Lo, C.-W., Wang, C.-C. & Lu, M.-C. Scale effect on dropwise condensation on superhydrophobic surfaces. ACS Appl. Mater. Interfaces 6, 14353–14359 (2014).
Yao, C. W., Alvarado, J. L., Marsh, C. P., Jones, B. G. & Collins, M. K. Wetting behavior on hybrid surfaces with hydrophobic and hydrophilic properties. Appl. Surf. Sci. 290, 59–65 (2014).
Tian, J. et al. Efficient self-propelling of small-scale condensed microdrops by closely packed ZnO nanoneedles. J. Phys. Chem. Lett. 5, 2084–2088 (2014).
Chen, X., Weibel, J. A. & Garimella, S. V. Exploiting microscale roughness on hierarchical superhydrophobic copper surfaces for enhanced dropwise condensation. Adv. Mater. Interfaces 2, 2–7 (2015).
Zhao, Y. et al. Condensate microdrop self-propelling aluminum surfaces based on controllable fabrication of alumina rod-capped nanopores. ACS Appl. Mater. Interfaces 7, 11079–11082 (2015).
Lv, C., Hao, P., Zhang, X. & He, F. Dewetting transitions of dropwise condensation on nanotexture-enhanced superhydrophobic surfaces. ACS Nano 9, 12311–12319 (2015).
Ölçerogˇlu, E., Hsieh, C.-Y., Rahman, M. M., Lau, K. K. S. & McCarthy, M. Full-field dynamic characterization of superhydrophobic condensation on biotemplated nanostructured surfaces. Langmuir 30, 7556–7566 (2014).
Enright, R., Miljkovic, N., Dou, N., Nam, Y. & Wang, E. N. Condensation on superhydrophobic copper oxide nanostructures. J. Heat Transfer 135, 91304 (2013).
Rykaczewski, K. & Scott, J. H. J. Methodology for imaging nano-to-microscale water condensation dynamics on complex nanostructures. ACS Nano 5, 5962–5968 (2011).
Paxson, A. T. & Varanasi, K. K. Self-similarity of contact line depinning from textured surfaces. Nat. Commun. 4, 1492 (2013).
Schellenberger, F., Encrinas, N., Vollmer, D. & Butt, H. J. How water advances on superhydrophobic surfaces. Phys. Rev. Lett. 116, 096101 (2016).
Kim, H. & Nam, Y. Condensation behaviors and resulting heat transfer performance of nano-engineered copper surfaces. Int. J. Heat Mass Transfer 93, 286–292 (2016).
Zhu, J., Luo, Y., Tian, J., Li, J. & Gao, X. Clustered ribbed-nanoneedle structured copper surfaces with high-efficiency dropwise condensation heat transfer performance. ACS Appl. Mater. Interfaces 7, 10660–10665 (2015).
Graham, C. The Limiting Heat Transfer Mechanisms of Dropwise Condensation. Thesis, Massachusetts Institute of Technology (1969).
Ma, X. H., Zhou, X. D., Lan, Z., Li, Y. M. & Zhang, Y. Condensation heat transfer enhancement in the presence of non-condensable gas using the interfacial effect of dropwise condensation. Int. J. Heat Mass Transfer 51, 1728–1737 (2008). This condensation study experimentally demonstrates the detrimental effect of NCGs on heat transfer performance.
Rafiee, J. et al. Wetting transparency of graphene. Nat. Mater. 11, 217–222 (2012).
Lv, C. et al. Condensation and jumping relay of droplets on lotus leaf. Appl. Phys. Lett. 103, 16–21 (2013).
Lv, C., Hao, P., Yao, Z. & Niu, F. Departure of condensation droplets on superhydrophobic surfaces. Langmuir 31, 2414–2420 (2015).
Kim, M. K. et al. Enhanced jumping-droplet departure. Langmuir 31, 13452–13466 (2015).
Qu, X. et al. Self-propelled sweeping removal of dropwise condensate. Appl. Phys. Lett. 106, 1–5 (2015).
Liu, J. et al. Guided self-propelled leaping of droplets on a micro-anisotropic superhydrophobic surface. Angew. Chem. Int. Ed. 55, 4265–4269 (2016).
Li, C. & Peterson, G. P. Parametric study of pool boiling on horizontal highly conductive microporous coated surfaces. J. Heat Transfer 129, 1465 (2007).
Li, C., Peterson, G. P. & Wang, Y. Evaporation/boiling in thin capillary wicks (l) — wick thickness effects. J. Heat Transfer 128, 1312 (2006).
Betz, A. R., Xu, J., Qiu, H. & Attinger, D. Do surfaces with mixed hydrophilic and hydrophobic areas enhance pool boiling? Appl. Phys. Lett. 97, 141909 (2010).
Betz, A. R., Jenkins, J., Kim, C.-J. & Attinger, D. Boiling heat transfer on superhydrophilic, superhydrophobic, and superbiphilic surfaces. Int. J. Heat Mass Transfer 57, 733–741 (2013). This boiling study demonstrates the high CHF and high HTC behaviour of superbiphilic surfaces.
Rahman, M. M., Pollack, J. & McCarthy, M. Increasing boiling heat transfer using low conductivity materials. Sci. Rep. 5, 13145 (2015). This boiling study demonstrates the high CHF and high HTC behaviour of biconductive surfaces.
Cooke, D. & Kandlikar, S. G. Pool boiling heat transfer and bubble dynamics over plain and enhanced microchannels. J. Heat Transfer 133, 52902 (2011).
Jaikumar, A. & Kandlikar, S. G. Ultra-high pool boiling performance and effect of channel width with selectively coated open microchannels. Int. J. Heat Mass Transfer 95, 795–805 (2016). This boiling study demonstrates the high CHF and high HTC behaviour of coated microchannels.
Cheng, L., Mewes, D. & Luke, A. Boiling phenomena with surfactants and polymeric additives: a state-of-the-art review. Int. J. Heat Mass Transfer 50, 2744–2771 (2007).
Zhang, J. & Manglik, R. M. Additive adsorption and interfacial characteristics of nucleate pool boiling in aqueous surfactant solutions. J. Heat Transfer 127, 684–691 (2005).
Cho, H. J., Sresht, V., Blankschtein, D. & Wang, E. N. in Proc. ASME 2013 Heat Transfer Summer Conf. http://dx.doi.org/10.1115/HT2013-17497 (ASME, 2013).
Cho, H. J., Mizerak, J. P. & Wang, E. N. Turning bubbles on and off during boiling using charged surfactants. Nat. Commun. 6, 8599 (2015).
Jones, T. B. in Advances in Heat Transfer Vol. 14, 107–148 (Elsevier, 1979).
Kandlikar, S. G., Shoji, M. & Dhir, V. K. Handbook of Phase Change: Boiling and Condensation (Taylor & Francis, 1999).
Choi, J. H. et al. Hydrophilic dots on hydrophobic nanopatterned surfaces as a flexible gas barrier. Langmuir 25, 7156–7160 (2009).
Boreyko, J. B. et al. Controlling condensation and frost growth with chemical micropatterns. Sci. Rep. 6, 19131 (2016).
Parker, A. R. & Lawrence, C. R. Water capture by a desert beetle. Nature 414, 33–34 (2001).
Guadarrama-Cetina, J. et al. Dew condensation on desert beetle skin. Eur. Phys. J. 37, 109 (2014).
Zhai, L. et al. Patterned superhydrophobic surfaces: toward a synthetic mimic of the Namib Desert beetle. Nano Lett. 6, 1213–1217 (2006).
Garrod, R. P. et al. Mimicking a stenocara beetle's back for microcondensation using plasmachemical patterned superhydrophobic–superhydrophilic surfaces. Langmuir 23, 689–693 (2007).
Dorrer, C. & Rühe, J. Mimicking the stenocara beetle — dewetting of drops from a patterned superhydrophobic surface. Langmuir 24, 6154–6158 (2008).
Her, E. K., Ko, T. J., Lee, K. R., Oh, K. H. & Moon, M. W. Bioinspired steel surfaces with extreme wettability contrast. Nanoscale 4, 2900–2905 (2012).
Mishchenko, L., Khan, M., Aizenberg, J. & Hatton, B. D. Spatial control of condensation and freezing on superhydrophobic surfaces with hydrophilic patches. Adv. Funct. Mater. 23, 4577–4584 (2013).
Yamada, Y., Ikuta, T., Nishiyama, T., Takahashi, K. & Takata, Y. Droplet nucleation on a well-defined hydrophilic–hydrophobic surface of 10 nm order resolution. Langmuir 30, 14532–14537 (2014).
Lo, C., Wang, C. & Lu, M. Spatial control of heterogeneous nucleation on the superhydrophobic nanowire array. Adv. Funct. Mater. 24, 1211–1217 (2014).
Choo, S., Choi, H. J. & Lee, H. Water-collecting behavior of nanostructured surfaces with special wettability. Appl. Surf. Sci. 324, 563–568 (2015).
Hou, Y., Yu, M., Chen, X., Wang, Z. & Yao, S. Recurrent filmwise and dropwise condensation on a beetle mimetic surface. ACS Nano 9, 71–81 (2015).
Ölçerogˇlu, E. & McCarthy, M. Self-organization of microscale condensate for delayed flooding of nanostructured superhydrophobic surfaces. ACS Appl. Mater. Interfaces 8, 5729–5736 (2016).
Tuteja, A. et al. Designing superoleophobic surfaces. Science 318, 1618–1622 (2007).
Tuteja, A., Choi, W., McKinley, G. H., Cohen, R. E. & Rubner, M. F. Design parameters for superhydrophobicity and superoleophobicity. MRS Bull. 33, 752–758 (2008).
Cavalli, A., Boggild, P. & Okkels, F. Parametric optimization of inverse trapezoid oleophobic surfaces. Langmuir 28, 17545–17551 (2012).
Liu, T. L. & Kim, C.-J. C. Turning a surface superrepellent even to completely wetting liquids. Science 346, 1096–1100 (2014).
Anderson, D. M. et al. Using amphiphilic nanostructures to enable long-range ensemble coalescence and surface rejuvenation in dropwise condensation. ACS Nano 6, 3262–3268 (2012).
Anand, S., Paxson, A. T., Dhiman, R., Smith, D. J. & Varanasi, K. K. Enhanced condensation on lubricant-impregnated nanotextured surfaces. ACS Nano 6, 10122–10129 (2012).
Vaaler, L. E. Impregnated porous condenser surfaces. US Patent 2919115 (1959).
Verheijen, H. J. J. & Prins, M. W. J. Reversible electrowetting and trapping of charge: model and experiments. Langmuir 15, 6616–6620 (1999).
Quéré, D. Non-sticking drops. Rep. Prog. Phys. 68, 2495–2532 (2005).
Wong, T.-S. et al. Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity. Nature 477, 443–447 (2011).
Lafuma, A. & Quéré, D. Slippery pre-suffused surfaces. Europhys. Lett. 96, 56001 (2011).
Xiao, R., Miljkovic, N., Enright, R. & Wang, E. N. Immersion condensation on oil-infused heterogeneous surfaces for enhanced heat transfer. Sci. Rep. 3, 1988 (2013). This condensation study is the first to show experimental results of HTC enhancement on a SLIPS condensation surface.
Rykaczewski, K. et al. Dropwise condensation of low surface tension fluids on omniphobic surfaces. Sci. Rep. 4, 4158 (2014).
Anand, S., Rykaczewski, K., Subramanyam, S. B., Beysens, D. & Varanasi, K. K. How droplets nucleate and grow on liquids and liquid impregnated surfaces. Soft Matter 11, 69–80 (2014).
Park, K.-C. et al. Condensation on slippery asymmetric bumps. Nature 531, 78–82 (2016).
Mancio Reis, F. M., Lavieille, P. & Miscevic, M. Toward enhancement of water vapour condensation using wettability gradient surface. Exp. Therm. Fluid Sci. 67, 70–74 (2015).
Bai, H. et al. Efficient water collection on integrative bioinspired surfaces with star-shaped wettability patterns. Adv. Mater. 26, 5025–5030 (2014).
Zheng, Y. et al. Directional water collection on wetted spider silk. Nature 463, 640–643 (2010).
Keysar, S., Semiat, R., Hasson, D. & Yahalom, J. Effect of surface roughness on the morphology of calcite crystallizing on mild steel. J. Colloid Interface Sci. 162, 311–319 (1994).
Macadam, J. & Parsons, S. A. Calcium carbonate scale control, effect of material and inhibitors. Water Sci. Technol. 49, 153–159 (2004).
Kreder, M. J., Alvarenga, J., Kim, P. & Aizenberg, J. Design of anti-icing surfaces: smooth, textured or slippery? Nat. Rev. Mater. 1, 15003 (2016).
Jakob, M. Heat Transfer (Wiley, 1949).
Webb, R. L. The evolution of enhanced surface geometries for nucleate boiling. Heat Transfer Eng. 2, 46–69 (1981).
Lewis, L. G. & Sather, N. F. OTEC performance tests of the Union Carbide flooded-bundle evaporator. http://dx.doi.org/10.2172/6357238 (Argonne National Laboratory, 1978).
Bergles, A. E. & Chyu, M. C. Characteristics of nucleate pool boiling from porous metallic coatings. J. Heat Transfer 104, 279 (1982).
MacAdam, J. & Parsons, S. A. Calcium carbonate scale formation and control. Rev. Environ. Sci. Biotechnol. 3, 159–169 (2004).
Wang, L. L. & Liu, M. Y. Pool boiling fouling and corrosion properties on liquid-phase-deposition TiO2 coatings with copper substrate. AIChE J. 57, 1710–1718 (2011).
Zhao, Q., Liu, Y., Wang, C., Wang, S. & Müller-Steinhagen, H. Effect of surface free energy on the adhesion of biofouling and crystalline fouling. Chem. Eng. Sci. 60, 4858–4865 (2005).
Buongiorno, J. Can corrosion and CRUD actually improve safety margins in LWRs? Ann. Nucl. Energy 63, 9–21 (2014).
He, M. et al. Hierarchically structured porous aluminum surfaces for high-efficient removal of condensed water. Soft Matter 8, 6680 (2012).
Son, H. H., Jeong, U., Seo, G. H. & Kim, S. J. Oxidation effect on the pool boiling critical heat flux of the carbon steel substrates. Int. J. Heat Mass Transfer 93, 1008–1019 (2016).
Das, A. K., Kilty, H. P., Marto, P. J., Andeen, G. B. & Kumar, A. The use of an organic self-assembled monolayer coating to promote dropwise condensation of steam on horizontal tubes. J. Heat Transfer 122, 278–286 (2000).
Rose, J. W. Dropwise condensation theory and experiment: a review. Proc. Inst. Mech. Eng. Part A 216, 115–128 (2002). This is a comprehensive review of dropwise condensation research since 1930.
Boinovich, L. B. & Emelyanenko, A. M. Hydrophobic materials and coatings: principles of design, properties and applications. Russ. Chem. Rev. 77, 583–600 (2008).
Citakoglu, E. & Rose, J. W. Dropwise condensation — some factors influencing the validity of heat-transfer measurements. Int. J. Heat Mass Transfer 11, 523–537 (1968).
Azimi, G., Kwon, H.-M. & Varanasi, K. K. Superhydrophobic surfaces by laser ablation of rare-earth oxide ceramics. MRS Commun. 4, 1–5 (2014).
Khan, S., Azimi, G., Yildiz, B. & Varanasi, K. K. Role of surface oxygen-to-metal ratio on the wettability of rare-earth oxides. Appl. Phys. Lett. 106, 061601(2015).
Preston, D. J. et al. Effect of hydrocarbon adsorption on the wettability of rare earth oxide ceramics. Appl. Phys. Lett. 105, 11601 (2014).
Prakash, S. Wettability of Oxide Thin Films Prepared by Pulsed Laser Deposition: New Insights. Thesis, National Univ. Singapore (2015).
Hassebrook, A. et al. in Proc. Int. Tech. Conf. Exhib. Packag. Integr. Electron. Photonic Microsyst. http://dx.doi.org/0.1115/ICNMM2015-48459 (ASME, 2015).
Young, T. An essay on the cohesion of fluids. Phil. Trans. R. Soc. 95, 65–87 (1805).
Cassie, A. B. D. & Baxter, S. Wettability of porous surfaces. Trans. Faraday Soc. 40, 546 (1944).
Cassie, A. B. D. & Baxter, S. Large contact angles of plant and animal surfaces. Nature 155, 21–22 (1945).
This work was partially funded by Singapore–MIT Alliance for Research and Technology (SMART) and the Office of Naval Research (ONR) with M. Spector as program manager (Contract Nos. N00014-15-1-2483 and N00014-12-1-0624). D.J.P. acknowledges funding received from the National Science Foundation Graduate Research Fellowship under Grant No. 1122374. Any opinion, findings, conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation.
The authors declare no competing interests.
Classical Nucleation Theory. (PDF 386 kb)
Recent developments in pool-boiling performance. (PDF 559 kb)
Summary of Boiling and Condensation Data used in Figures S2 and S4. (PDF 214 kb)
Recent developments in condensation heat-transfer performance. (PDF 530 kb)
Data adjustment and extrapolation. (PDF 852 kb)
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Cho, H., Preston, D., Zhu, Y. et al. Nanoengineered materials for liquid–vapour phase-change heat transfer. Nat Rev Mater 2, 16092 (2017). https://doi.org/10.1038/natrevmats.2016.92
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