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Inorganic chemistry

Peculiar boron startles again

Boron's unusual properties inspired big advances in chemistry. A compound in which boron binds two carbon monoxide molecules reveals another oddity — the element forms bonds similar to those of transition metals. See Letter p.327

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Figure 1: The electronic structure of boron compounds.

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References

  1. Braunschweig, H. et al. Nature 522, 327–330 (2015).

    Article  CAS  ADS  Google Scholar 

  2. http://www.nobelprize.org/nobel_prizes/chemistry/laureates/1976/

  3. www.nobelprize.org/nobel_prizes/chemistry/laureates/1979/

  4. www.nobelprize.org/nobel_prizes/chemistry/laureates/2010/

  5. Celik, M. A., Sure, R., Klein, S., Kinjo, R., Bertrand, G. & Frenking, G. Chem. Eur. J. 18, 5676–5692 (2012).

    Article  CAS  Google Scholar 

  6. Kinjo, R., Donnadieu, B., Celik, M. A., Frenking, G. & Bertrand, G. Science 333, 610–613 (2011).

    Article  CAS  ADS  Google Scholar 

  7. Soleilhavoup, M. & Bertrand, G. Acc. Chem. Res. 48, 256–266 (2015).

    Article  CAS  Google Scholar 

  8. Dahcheh, F., Martin, D., Stephan, D. W. & Bertrand, G. Angew. Chem. Int. Edn 53, 13159–13163 (2014).

    Article  CAS  Google Scholar 

  9. Himmel, D., Krossing, I. & Schnepf, A. Angew. Chem. Int. Edn 53, 370–374 (2014).

    Article  CAS  Google Scholar 

  10. Frenking, G. Angew. Chem. Int. Edn 53, 6040–6046 (2014).

    Article  CAS  Google Scholar 

  11. Himmel, D., Krossing, I. & Schnepf, A. Angew. Chem. Int. Edn 53, 6047–6048 (2014).

    Article  CAS  Google Scholar 

  12. Diels, O. & Wolf, B. Ber. Dt. Chem. Ges. 39, 689–697 (1906).

    Article  Google Scholar 

  13. Jensen, P. & Johns, J. W. C. J. Mol. Spectrosc. 118, 248–266 (1986).

    Article  CAS  ADS  Google Scholar 

  14. Tonner, R. & Frenking, G. Pure Appl. Chem. 81, 597–611 (2009).

    Article  Google Scholar 

  15. Dyker, C. A., Lavallo, V., Donnadieu, B. & Bertrand, G. Angew. Chem. Int. Edn 47, 3206–3209 (2008).

    Article  CAS  Google Scholar 

  16. Fürstner, A., Alcarazo, M., Goddard, R. & Lehmann, C. W. Angew. Chem. Int. Edn 47, 3210–3214 (2008).

    Article  Google Scholar 

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Correspondence to Gernot Frenking.

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Frenking, G. Peculiar boron startles again. Nature 522, 297–298 (2015). https://doi.org/10.1038/522297a

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