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Catalysis

Dual catalysis at the flick of a switch

Nature volume 519, pages 42–43 (2015)Cite this article

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A combination of two catalysts — one of which is light-activated — has been used to promote new chemical reactivity, opening up fresh opportunities for the synthesis of structurally complex organic molecules. See Letter p.74

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Figure 1: Light-activated arylation of allylic carbon–hydrogen bonds.

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References

  1. Cuthbertson, J. D. & MacMillan, D. W. C. Nature 519, 74–77 (2015).

    Article  ADS  CAS  Google Scholar 

  2. Nelson, N. & Ben-Shem, A. Nature Rev. Mol. Cell Biol. 5, 971–982 (2004).

    Article  CAS  Google Scholar 

  3. Kärkäs, M. D., Verho, O., Johnston, E. V. & Åkermark, B. Chem. Rev. 114, 11863–12001 (2014).

    Article  Google Scholar 

  4. Prier, C. K., Rankic, D. A. & MacMillan, D. W. C. Chem. Rev. 113, 5322–5363 (2013).

    Article  CAS  Google Scholar 

  5. Nicewicz, D. A. & MacMillan, D. W. C. Science 322, 77–80 (2008).

    Article  ADS  CAS  Google Scholar 

  6. Kalyani, D., McMurtrey, K. B., Neufeldt, S. R. & Sanford, M. S. J. Am. Chem. Soc. 133, 18566–18569 (2011).

    Article  CAS  Google Scholar 

  7. DiRocco, D. A. & Rovis, T. J. Am. Chem. Soc. 134, 8094–8097 (2012).

    Article  CAS  Google Scholar 

  8. Hamilton, D. S. & Nicewicz, D. A. J. Am. Chem. Soc. 134, 18577–18580 (2012).

    Article  CAS  Google Scholar 

  9. Bergonzini, G., Schindler, C. S., Wallentin, C.-J., Jacobsen, E. N. & Stephenson, C. R. J. Chem. Sci. 5, 112–116 (2014).

    Article  CAS  Google Scholar 

  10. Du, J., Skubi, K. L., Schultz, D. M. & Yoon, T. P. Science 344, 392–396 (2014).

    Article  ADS  CAS  Google Scholar 

  11. Baguley, P. A. & Walton, J. C. Angew. Chem. Int. Edn 37, 3072–3082 (1998).

    Article  CAS  Google Scholar 

  12. Qvortrup, K., Rankic, D. A. & MacMillan, D. W. C. J. Am. Chem. Soc. 136, 626–629 (2014).

    Article  CAS  Google Scholar 

  13. Hager, D. & MacMillan, D. W. C. J. Am. Chem. Soc. 136, 16986–16989 (2014).

    Article  CAS  Google Scholar 

  14. Newcomb, M. Encyclopedia of Radicals in Chemistry, Biology and Materials (Wiley, 2012).

    Google Scholar 

Download references

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Authors and Affiliations

  1. James J. Devery III and Corey R. J. Stephenson are in the Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.,

    James J. Devery III & Corey R. J. Stephenson

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  1. James J. Devery III
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  2. Corey R. J. Stephenson
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Correspondence to Corey R. J. Stephenson.

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Devery, J., Stephenson, C. Dual catalysis at the flick of a switch. Nature 519, 42–43 (2015). https://doi.org/10.1038/519042a

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