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Gold unleashes the power of three


Gold in the +3 oxidation state is scarcely used in catalysis, because the oxidants employed to generate it can damage reactants. An oxidant-free route to gold(III) catalysts reveals their potential. See Article p.449

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Figure 1: Preparation and application of a gold(III) catalyst.


  1. Wu, C.-Y., Horibe, T., Jacobsen, C. B. & Toste, F. D. Nature 517, 449–454 (2015).

    ADS  CAS  Article  Google Scholar 

  2. Hickman, A. J. & Sanford, M. S. Nature 484, 177–185 (2012).

    ADS  CAS  Article  Google Scholar 

  3. Corma, A., Leyva-Pérez, A. & Sabater, M. J. Chem. Rev. 111, 1657–1712 (2011).

    CAS  Article  Google Scholar 

  4. Gaillard, S., Salwin, A. M. Z., Bonura, A. T., Stevens, E. D. & Nolan, S. P. Organometallics 29, 394–402 (2010).

    CAS  Article  Google Scholar 

  5. Wolf, W. J., Winston, M. S. & Toste, F. D. Nature Chem. 6, 159–164 (2013).

    ADS  Article  Google Scholar 

  6. Perthuisot, C. et al. J. Mol. Catal. A 189, 157–168 (2002).

    CAS  Article  Google Scholar 

  7. Yamamoto, H. (ed.) Lewis Acids in Organic Synthesis (Wiley, 2000).

    Book  Google Scholar 

  8. Akagawa, K., Sen, J. & Kudo, K. Angew. Chem. Int. Edn 52, 11585–11588 (2013).

    CAS  Article  Google Scholar 

  9. Pennell, M. N., Unthank, M. G., Turner, P. & Sheppard, T. D. J. Org. Chem. 76, 1479–1482 (2011).

    CAS  Article  Google Scholar 

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Correspondence to Nicolai Cramer.

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Kourra, C., Cramer, N. Gold unleashes the power of three. Nature 517, 440–441 (2015).

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