Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Organometallic chemistry

Catalyst takes control to heart

Some transition-metal catalysts control organic reactions so that, given a choice of two mirror-image products, only one forms. The metal atom in these catalysts has been ignored as a source of control — until now.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Chiral catalysts for olefin metathesis.

References

  1. Malcomson, S. J., Meek, S. J., Sattely, E. S., Schrock, R. R. & Hoveyda, A. H. Nature 456, 933–937 (2008).

    Article  ADS  Google Scholar 

  2. http://nobelprize.org/nobel_prizes/chemistry/laureates/2005/animation.html

  3. Seiders, T. J., Ward, D. W. & Grubbs, R. H. Org. Lett. 3, 3225–3228 (2001).

    Article  CAS  Google Scholar 

  4. Funk, T. W., Berlin, J. M. & Grubbs, R. H. J. Am. Chem. Soc. 128, 1840–1846 (2006).

    Article  CAS  Google Scholar 

  5. Van Veldhuizen, J. J., Garber, S. B., Kingsbury, J. S. & Hoveyda, A. H. J. Am. Chem. Soc. 124, 4954–4955 (2002).

    Article  CAS  Google Scholar 

  6. Alexander, J. B., La, D. S., Cefalo, D. R., Hoveyda, A. H. & Schrock, R. R. J. Am. Chem. Soc. 120, 4041–4042 (1998).

    Article  CAS  Google Scholar 

  7. Fujimura, O. & Grubbs, R. H. J. Org. Chem. 63, 824–832 (1998).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Diver, S. Catalyst takes control to heart. Nature 456, 883–885 (2008). https://doi.org/10.1038/456883a

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/456883a

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing