The size and uniformity of polymer molecules makes it difficult to modify them at just one selected site. But a single chemical group can be attached at the end of a polymer if part of the starting material is forfeited.
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Hilf, S., Berger-Nicoletti, E., Grubbs, R. H. & Kilbinger, A. F. M. Angew. Chem. Int. Edn 45, 8045–8048 (2006).
Chauvin, Y. Angew. Chem. Int. Edn 45, 3740–3747 (2006).
Schrock, R. R. Angew. Chem. Int. Edn 45, 3748–3759 (2006).
Grubbs, R. H. Angew. Chem. Int. Edn 45, 3760–3765 (2006).
Grubbs, R. H. (ed.) Handbook of Metathesis Vol. 3 (Wiley-VCH, Weinheim, 2003).
Szwarc, M. Nature 178, 1168–1169 (1956).
Matyjaszewski, K. (ed.) Controlled/Living Radical Polymerization: from Synthesis to Materials (American Chemical Society, Washington DC, 2006).
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Perrier, S., Wang, X. Sacrificial synthesis. Nature 445, 271–272 (2007). https://doi.org/10.1038/445271a
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