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Chemistry

A catalytic knight's move

The reactivity of inert hydrocarbons can be transformed by a catalytic double act. With the ability to manipulate the lengths of the resulting carbon chains, this development opens up fresh vistas.

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Figure 1: Individual steps of the Goldman–Brookhart reaction3.

References

  1. Wasilke, J. C., Obrey, S. J., Baker, R. T. & Bazan, G. C. Chem. Rev. 105, 1001–1020 (2005).

    Article  CAS  PubMed  Google Scholar 

  2. Fogg, D. E. & dos Santos, E. N. Coord. Chem. Rev. 248, 2365–2379 (2004).

    Article  CAS  Google Scholar 

  3. Goldman, A. S., Roy, A. H., Huang, Z., Ahuja, R., Schinski, W. & Brookhart, M. Science 312, 257–261 (2006).

    Article  ADS  CAS  PubMed  Google Scholar 

  4. http://nobelprize.org

  5. Shilov, A. E. & Shul'pin, G. B. Activation and Catalytic Reactions of Saturated Hydrocarbons (Kluwer, Dordrecht, 2000).

    Google Scholar 

  6. Hérisson, J. L. & Chauvin, Y. Makromol. Chem. 141, 161–164 (1971).

    Article  Google Scholar 

  7. Trnka, T. M. & Grubbs, R. H. Acc. Chem. Res. 34, 18–29 (2001).

    Article  CAS  PubMed  Google Scholar 

  8. Schrock, R. R. Acc. Chem. Res. 23, 158–165 (1990).

    Article  CAS  Google Scholar 

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Crabtree, R. A catalytic knight's move. Nature 441, 165–166 (2006). https://doi.org/10.1038/441165a

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