How scientists sought to explain the colour of the heavens.
Sky in a Bottle
By Peter Pesic
The central question that Sky in a Bottle by Peter Pesic seeks to answer is why the cloudless daytime sky is blue. The bottle in the title alludes to experiments that have been performed over the ages in an attempt to capture or explain the blue colour. This all sounded tempting to me, as the past 45 years of my professional life have been devoted to a parallel enquiry, that of atmospheric chemistry as studied ‘in a bottle’.
It is humbling to find in the book a diagram of a photochemical flow apparatus that John Tyndall used to produce and study photochemical smog in 1871; most present-day atmospheric chemists doubtless believe that such experiments are a modern development. One particularly nice touch is the inclusion of recipes for some of the most important ‘sky in a bottle’ experiments, suitably modified by Pesic to conform to present-day ideas about safety. Several of the earlier experiments used liquids rather than gases, but some provided clear hints that selective scattering of radiation, rather than selective absorption, might provide the key to understanding the sky's colour.
Pesic, a musician who holds a doctorate in physics, sets out on an enthralling and entertaining journey. He follows in the footsteps of the many artists, philosophers and mystics who have taken an interest in the blue of the sky, thus complementing the curiosity of scientists. Artists who appear in the book range from Leonardo da Vinci to Wassily Kandinsky, whose love of the colour brought the Blue Rider group of artists into being. Curiously, the sky does not seem to have been painted blue much before the time of Giotto's fresco in Padua in 1305–6. This late arrival of blue was partly, but not entirely, the result of a lack of affordable blue pigments; ground-up lapis lazuli, which Giotto used, was ruinously expensive and came from ‘beyond the seas’ (hence ‘ultramarine’).
Starting in the tenth century, long after Pesic begins his tale, some of the scientists who made notable achievements include the founder of modern optics, Ibn al-Haytham, Roger Bacon, Leonardo again, René Descartes, Isaac Newton and Robert Hooke (who sometimes seemed to see more clearly than Newton). Thomas Young contributed with his use of slits, and William Herschel (originally a musician) and his son John played their part, as did Augustin Fresnel, Siméon-Denis Poisson and Jean Perrin. More recent additions to the list are James Clerk Maxwell, Lord Kelvin, the Rayleighs, Einstein and Max Planck.
Bit by bit, it became clear that the sky's blue colour resulted from some kind of phenomenon involving the scattering of light. But what could be doing the scattering? Particles, presumably, but of what? Dust or water were initially favoured. In this context, it is noteworthy how many of the artists, philosophers and scientists were enthusiastic mountaineers or lovers of mountains, at a time when few people thought mountains had any beauty or interest. They, of all people, must have known that the sky seems more intensely blue when the atmosphere is dry and dust free. Even more curiously, evidence accumulated that any scattering particles must have the same refractive index as air itself.
Since the time of Newton, the wave theory of light has gradually become widely accepted, thanks to its power to explain interference phenomena; there has been a growing understanding of polarization; and doubters have been converted to the reality of atoms and molecules. The cornerstone of today's view, developed by the third Baron Rayleigh, is that light is scattered by the molecules of the air, principally nitrogen and oxygen. The interaction of these molecules with electromagnetic radiation leads to some of the light being diverted from its original path and re-radiated isotropically. This process is known as Rayleigh scattering, and its efficiency increases as the fourth power of the frequency — very sharply. Wavelength is inversely proportional to frequency, so shorter wavelengths are scattered much more than longer ones: blue much more than red.
Marian Smoluchowski reached similar conclusions in a different way, basing his argument on the opalescence of carbon dioxide near its critical point, as observed by Einstein and Thomas Andrews. One last point worth making is that the scattering in our atmosphere that makes the sky blue requires the molecules to act independently of each other — the scattering has to be incoherent. If the density of the atmosphere were too high, the scattering would be multiple and coherent (the latter occurs in transparent solids), so the colour would be lost. With too low a density, there would be too little scattering to be registered by the eye.
Pesic has a broadly based erudition and the science in his book is pretty sound. I do not agree entirely with his account of the excitation of the airglow, and I know that Earth is not 10 billion years old, but these are small matters. A huge amount of important science is presented in an accessible way that makes no huge demands on non-scientist readers, and the level and approach provide enough intellectual substance for the specialist. Copious notes flesh out many of the points made in the main text. The notes are preceded by an interesting selection of letters between George Stokes, Tyndall and Lord Kelvin on the blue of the sky. Many of the concepts developed are taken for granted by almost everyone and are deeply ingrained in the very heart of modern science. Science does not always proceed in a linear or expected fashion, being helped forward in some cases by inspiration. As Pesic says of a prose poem by Edgar Allen Poe dedicated to Alexander von Humboldt: “a visionary was able to discern a conclusion vindicated only much later by sober science”.
I commend this book to those who want to read about truly significant discoveries linked together through a need to answer what seems to be a simple question. Unlike many other attempts to popularize science, this book has managed not to garble the facts or sensationalize them. It is well worth reading.