The ratio of helium isotopes in some oceanic volcanoes seemed to demand a reservoir of virgin primordial gas in the Earth's mantle. In fact, that might not be necessary — a relief for other geophysical models.
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White, W. Helium not in store. Nature 436, 1095–1096 (2005). https://doi.org/10.1038/4361095a
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DOI: https://doi.org/10.1038/4361095a