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Nanotechnology

Spinning continuous carbon nanotube yarns

Carbon nanotubes weave their way into a range of imaginative macroscopic applications.

Abstract

The creation of continuous yarns made out of carbon nanotubes would enable macroscopic nanotube devices and structures to be constructed1,2. Here we show that carbon nanotubes can be self-assembled into yarns of up to 30 cm in length simply by being drawn out from superaligned arrays of carbon nanotubes, and that the strength and conductivity of these yarns can be enhanced by heating them at high temperatures. Our findings should help to translate the remarkable mechanical, electrical and thermal properties of carbon nanotubes to a macroscopic scale.

Main

While attempting to pull out a bundle of carbon nanotubes (CNTs) from a CNT array several hundred micrometres high and grown on a silicon substrate, we obtained instead a continuous yarn of pure CNTs (Fig. 1a). This process is very similar to drawing a thread from a silk cocoon, corresponding here to the CNT array. Figure 1b shows a 100-µm-high, free-standing CNT array held by adhesive tape: the indentation at the top of the array marks the region that is being turned into a yarn 30 cm long and 200 µm wide. We estimate that an array area of roughly 1 cm2 can generate about 10 m of yarn.

Figure 1: Carbon nanotube yarns.
figure 1

a, b, A carbon nanotube yarn being continuously pulled out from a free-standing carbon nanotube array (a), which is shown enlarged in b (roughly × 8 magnification). c, Scanning electron microscope (SEM) images of a carbon nanotube array grown on a silicon substrate, showing the superalignment of carbon nanotubes (scale bars: 100 µm; inset, 200 nm). d, SEM image of the yarn in a; inset, transmission electron microscope (TEM) image of a single thread of the yarn (scale bars: 500 nm; inset, 100 nm). e, Carbon nanotube filaments emitting incandescent light. Inset, IV curve measured before (green) and after (red) light emission for 3 h at 70 V. f, A carbon nanotube polarizer. Polarized laser light (Plaser) is focused on the surface of a silicon wafer and reflected back, passing the carbon nanotube polarizer twice before being collected by a CCD detector. Inset, normalized intensity (squares, ratio of the current I to Imax; a.u., arbitrary units) plotted against the angle between the polarization direction of the laser light and the carbon nanotube polarizer, compared with values calculated from Malus's law (I = I0cos2θ; red line).

Although several methods can be used to prepare CNT arrays on different substrates3,4,5,6, we find that continuous yarns can only be drawn out from superaligned arrays in which the CNTs are aligned parallel to one another and are held together by van der Waals interactions to form bundles (Fig. 1c). The yarns usually appear as thin ribbons composed of parallel threads that have diameters in the range of several hundreds of nanometres (Fig. 1d), with the width of the yarn roughly depending on the number of threads in the yarn. In principle, the size of the yarn can be controlled by the tip size of the tool that is used to pick up the yarn — the smaller the tip, the thinner the yarn.

To demonstrate the properties of these yarns, we constructed a light-bulb filament by winding a CNT yarn between two metal leads. The filament emits incandescent light when a DC voltage is applied in a vacuum of 5 × 10–3 Pa (Fig. 1e). After emitting light for 3 h at 70 V, the conductivity of the filament increases by 13% and the tensile strength changes from 1 mN to 6.4 mN. These results indicate that some welding effect may be occurring at the weak connection points of the CNTs during light emission, because these points have a higher resistivity and, as a result, a higher temperature when a current is applied.

We were also able to construct a CNT polarizer by parallel alignment of CNT yarns. When a beam of light passes through the CNT polarizer, photons having a polarization direction parallel to the axis of the CNTs are absorbed, whereas those that are perpendicularly polarized pass through it7,8. Because the CNT diameter is about 10 nm, the polarizer can work in the ultraviolet region, and could even be used for ultraviolet light of wavelengths in the region of tens of nanometres. Figure 1f shows the polarization ability of the CNT device measured at 325 nm, which is in good agreement with that predicted by Malus's law, I = I0cos2θ. The degree of polarization of the CNT polarizer, P = (ImaxImin)/(Imax + Imin), is 0.92.

We envisage that pure CNT yarns such as these, particularly after appropriate heat treatment, should eventually be able to be woven into a variety of macroscopic objects for different applications, such as bullet-proof vests and materials that block electromagnetic waves.

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Correspondence to Shoushan Fan.

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Jiang, K., Li, Q. & Fan, S. Spinning continuous carbon nanotube yarns. Nature 419, 801 (2002). https://doi.org/10.1038/419801a

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