How did the preference for 'single-handedness' in biological molecules arise? Amplification of the trace imbalance in a mixture of handed molecules bolsters the case for chance being the answer.
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References
Singleton, D. A. & Vo, L. K. J. Am. Chem. Soc. 124, 10010–10011 (2002).
Siegel, J. S. Chirality 10, 24–27 (1998).
Havinga, E. Chem. Weekblad 38, 642–645 (1941).
Link, D. R. et al. Science 278, 1924–1927 (1997).
Soai, K., Shibata, T., Morioka, H. & Choi, K. Nature 378, 767–768 (1995).
Sato, I., Kadowaki, K. & Soai, K. Angew. Chem. Int. Edn 39, 1510–1512 (2000).
Soai, K., Shibata, T. & Kowata, Y. Japan Kokai Tokkyo Koh o (1997) 9-268179 (application date: 1 February 1996 and 18 April 1996).
Blackmond, D. G., McMillan, C. R., Ramdeehul, S., Schorm, A. & Brown, J. M. J. Am. Chem. Soc. 123, 10103–10104 (2001).
Berger, R., Quack, M. & Tschumper, G. S. Helv. Chim. Acta 83, 1919–1950 (2000).
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Siegel, J. Shattered mirrors. Nature 419, 346–347 (2002). https://doi.org/10.1038/419346a
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DOI: https://doi.org/10.1038/419346a
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