The simple hydrogen exchange reaction was well understood until an unexpected effect emerged in detailed experimental measurements of the process. An explanation for this effect has now been found.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Schnieder, L. et al. Science 269, 207–210 (1995).
Althorpe, S. C. et al. Nature 416, 67–70 (2002).
Fernandez-Alonso, F. & Zare, R. N. Annu. Rev. Phys. Chem. 53, 67–99 (2002).
Aoiz, F. J. et al. J. Chem. Phys. 117, 2546–2556 (2002).
Harich, S. A. et al. Nature 419, 281–284 (2002).
Miller, W. H. & Zhang, J. Z. H. J. Phys. Chem. 95, 12–19 (1991).
Friedman, R. S. & Truhlar, D. G. Chem. Phys. Lett. 183, 539–546 (1991).
Seideman, T. & Miller, W. H. J. Chem. Phys. 95, 1768–1780 (1991).
Sadeghi, R. & Skodje, R. T. Phys. Rev. A 52, 1996–2010 (1995).
Liu, K., Skodje, R. T. & Manolopoulos, D. E. Phys. Chem. Commun. 5, 27–33 (2002).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Manolopoulos, D. A delayed reaction. Nature 419, 266–267 (2002). https://doi.org/10.1038/419266a
Issue Date:
DOI: https://doi.org/10.1038/419266a
This article is cited by
-
Revealing the stereospecific chemistry of the reaction of Cl with aligned CHD3(ν1 = 1)
Nature Chemistry (2012)
