The assembly of semiconductor nanowires and carbon nanotubes into nanoscale devices and circuits could enable diverse applications in nanoelectronics and photonics1. Individual semiconducting nanowires have already been configured as field-effect transistors2, photodetectors3 and bio/chemical sensors4. More sophisticated light-emitting diodes5 (LEDs) and complementary and diode logic6,7,8 devices have been realized using both n- and p-type semiconducting nanowires or nanotubes. The n- and p-type materials have been incorporated in these latter devices either by crossing p- and n-type nanowires2,5,6,9 or by lithographically defining distinct p- and n-type regions in nanotubes8,10, although both strategies limit device complexity. In the planar semiconductor industry, intricate n- and p-type and more generally compositionally modulated (that is, superlattice) structures are used to enable versatile electronic and photonic functions. Here we demonstrate the synthesis of semiconductor nanowire superlattices from group III–V and group IV materials. (The superlattices are created within the nanowires by repeated modulation of the vapour-phase semiconductor reactants during growth of the wires.) Compositionally modulated superlattices consisting of 2 to 21 layers of GaAs and GaP have been prepared. Furthermore, n-Si/p-Si and n-InP/p-InP modulation doped nanowires have been synthesized. Single-nanowire photoluminescence, electrical transport and electroluminescence measurements show the unique photonic and electronic properties of these nanowire superlattices, and suggest potential applications ranging from nano-barcodes to polarized nanoscale LEDs.
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Lieber, C. M. The incredible shrinking circuit. Sci. Am. 285, 58–64 (2001).
Cui, Y. & Lieber, C. M. Functional nanoscale electronic devices assembled using silicon nanowire building blocks. Science 291, 851–853 (2001).
Wang, J. F., Gudiksen, M. S., Duan, X. F., Cui, Y. & Lieber, C. M. Highly polarized photoluminescence and photodetection from single indium phosphide nanowires. Science 293, 1455–1457 (2001).
Cui, Y., Wei, Q. Q., Park, H. K. & Lieber, C. M. Nanowire nanosensors for highly sensitive and selective detection of biological and chemical species. Science 293, 1289–1292 (2001).
Duan, X. F., Huang, Y., Cui, Y., Wang, J. F. & Lieber, C. M. Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices. Nature 409, 66–69 (2001).
Huang, Y. et al. Logic gates and computation from assembled nanowire building blocks. Science 294, 1313–1317 (2001).
Bachtold, A., Hadley, P., Nakanishi, T. & Dekker, C. Logic circuits with carbon nanotube transistors. Science 294, 1317–1320 (2001).
Derycke, V., Martel, R., Appenzeller, J. & Avouris, P. Carbon nanotube inter- and intramolecular logic gates. Nano Lett. 1, 453–456 (2001).
Huang, Y., Duan, X. F., Wei, Q. Q. & Lieber, C. M. Directed assembly of one-dimensional nanostructures into functional networks. Science 291, 630–633 (2001).
Zhou, C. W., Kong, J., Yenilmez, E. & Dai, H. J. Modulated chemical doping of individual carbon nanotubes. Science 290, 1552–1555 (2000).
Gudiksen, M. S. & Lieber, C. M. Diameter-selective synthesis of semiconductor nanowires. J. Am. Chem. Soc. 122, 8801–8802 (2000).
Cui, Y., Lauhon, L. J., Gudiksen, M. S., Wang, J. F. & Lieber, C. M. Diameter-controlled synthesis of single-crystal silicon nanowires. Appl. Phys. Lett. 78, 2214–2216 (2001).
Gudiksen, M. S., Wang, J. F. & Lieber, C. M. Synthetic control of the diameter and length of single crystal semiconductor nanowires. J. Phys. Chem. B 105, 4062–4064 (2001).
Wagner, R. S. in Whisker Technology 47–119 (Wiley-Interscience, New York, 1970).
Morales, A. M. & Lieber, C. M. A laser ablation method for the synthesis of crystalline semiconductor nanowires. Science 279, 208–211 (1998).
Duan, X. F. & Lieber, C. M. General synthesis of compound semiconductor nanowires. Adv. Mater. 12, 298–302 (2000).
Cui, Y., Duan, X. F., Hu, J. T. & Lieber, C. M. Doping and electrical transport in silicon nanowires. J. Phys. Chem. B 104, 5213–5216 (2000).
Nicewarner-Pena, S. R. et al. Submicrometer metallic barcodes. Science 294, 137–141 (2001).
Chow, E. et al. Three-dimensional control of light in a two-dimensional photonic crystal slab. Nature 407, 983–986 (2000).
Huang, M. H. et al. Room-temperature ultraviolet nanowire nanolasers. Science 292, 1897–1899 (2001).
Bachtold, A. et al. Scanned probe microscopy of electronic transport in carbon nanotubes. Phys. Rev. Lett. 84, 6082–6085 (2000).
Hu, J., Ouyang, M., Yang, P. & Lieber, C. M. Controlled growth and electrical properties of heterojunctions of carbon nanotubes and silicon nanowires. Nature 399, 48–51 (1999).
Bennett, C. H. & DiVincenzo, D. P. Quantum information and computation. Nature 404, 247–255 (2000).
We thank X. Duan for discussions, and W. MoberlyChan and A. J. Garratt-Reed for assistance with TEM imaging and analysis. M.S.G. thanks the NSF for predoctoral fellowship support. C.M.L. acknowledges support of this work by the Office of Naval Research and Defense Advanced Projects Research Agency.
The authors declare no competing financial interests.
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Gudiksen, M., Lauhon, L., Wang, J. et al. Growth of nanowire superlattice structures for nanoscale photonics and electronics. Nature 415, 617–620 (2002). https://doi.org/10.1038/415617a
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