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A single-electron transistor made from a cadmium selenide nanocrystal

Nature volume 389, pages 699–701 (1997)Cite this article

Abstract

The techniques of colloidal chemistry permit the routine creation of semiconductor nanocrystals1,2 whose dimensions are much smaller than those that can be realized using lithographic techniques3,4,5,6. The sizes of such nanocrystals can be varied systematically to study quantum size effects or to make novel electronic or optical materials with tailored properties7,8,9. Preliminary studies of both the electrical10,11,12,13 and optical properties14,15,16 of individual nanocrystals have been performed recently. These studies show clearly that a single excess charge on a nanocrystal can markedly influence its properties. Here we present measurements of electrical transport in a single-electron transistor made from a colloidal nanocrystal of cadmium selenide. This device structure enables the number of charge carriers on the nanocrystal to be tuned directly, and so permits the measurement of the energy required for adding successive charge carriers. Such measurements are invaluable in understanding the energy-level spectra of small electronic systems, as has been shown by similar studies of lithographically patterned quantum dots3,4,5,6 and small metallic grains17.

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Figure 1: a, Diagram of the device.
Figure 2: Conductance, G, plotted against gate voltage, V g, for a single-nanocrystal transistor measured at T = 4.2 K.
Figure 3: a, b, Composite grey-scale plots of the differential conductance d I /d V of a CdSe nanocrystal plotted as a function of both V g and V.
Figure 4: a, Energy-level diagram for a nanocrystal with N electrons at a gate voltage midway between two Coulomb oscillations.

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Authors and Affiliations

  1. Department of Physics, University of California, Berkeley, 94720, California, USA

    David L. Klein & Paul L. McEuen

  2. Department of Chemistry, University of California, Berkeley, 94720, California, USA

    David L. Klein, Richard Roth, Andrew K. L. Lim & A. Paul Alivisatos

  3. Molecular Design Institute, Lawrence Berkeley National Laboratory, Berkeley, 94720, California, USA

    Richard Roth, Andrew K. L. Lim, A. Paul Alivisatos & Paul L. McEuen

Authors
  1. David L. Klein
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  2. Richard Roth
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  3. Andrew K. L. Lim
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  4. A. Paul Alivisatos
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  5. Paul L. McEuen
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Correspondence to Paul L. McEuen.

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Klein, D., Roth, R., Lim, A. et al. A single-electron transistor made from a cadmium selenide nanocrystal. Nature 389, 699–701 (1997). https://doi.org/10.1038/39535

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