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Synthesis of inorganic materials with complex form

Abstract

Recent developments in inorganic materials chemistry suggest that concepts such as morphogenesis, replication, self-organization and metamorphosis could be useful for devising new synthetic strategies. Inorganic materials with complex form can be chemically synthesized by pattern replication of self-organized organic assemblies, such as micelles, vesicles and foams.

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References

  1. Barrer, R. M. Hydrothermal Chemistry of Zeolites (Academic, London, 1982).

    Google Scholar 

  2. Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C. & Beck, J. S. Nature 359, 710–712 (1992).

    Article  ADS  CAS  Google Scholar 

  3. Beck, J. S. et al. J. Am. chem. Soc. 114, 10834–10843 (1992).

    Article  CAS  Google Scholar 

  4. Mackay, A. L. Curr. Sci. 69, 151–161 (1995).

    CAS  Google Scholar 

  5. Mann, S. J. Mater. Chem. 5, 935–946 (1995).

    Article  CAS  Google Scholar 

  6. Mann, S. Nature 332, 119–124 (1988).

    Article  ADS  CAS  Google Scholar 

  7. Heuer, A. H. et al. Science 225, 1098–1105 (1992).

    Article  ADS  Google Scholar 

  8. Mann, S. et al. Science 261, 1286–1292 (1993).

    Article  ADS  CAS  Google Scholar 

  9. Mann, S. Nature 365, 499–505 (1993).

    Article  ADS  CAS  Google Scholar 

  10. Ozin, G. A. & Oliver, S. Adv. Mater. 7, 943–947 (1995).

    Article  CAS  Google Scholar 

  11. Oliver, S., Ozin, G. A., Khushalani, D., Kuperman, A. & Coombs, N. in NATO Adv. Res. Workshop Proc.: Modular Chemistry (ed. Michl, J.) (Aspen, Colorado, 1995).

    Google Scholar 

  12. Garcia-Ruiz, J. M. J. Cryst. Growth 73, 251–262 (1985).

    Article  ADS  CAS  Google Scholar 

  13. Kumar, A., Abbott, N. L., Kim, E., Biebuyck, H. A. & Whitesides, G. Acc. Chem. Res. 28, 219–226 (1995).

    Article  CAS  Google Scholar 

  14. Wilbur, J. L., Kim, E., Xia, Y. & Whitesides, G. Adv. Mater. 7, 649–652 (1995).

    Article  CAS  Google Scholar 

  15. Harting, P. Q. J. Microsc. Sci. 12, 118–123 (1872).

    Google Scholar 

  16. Thompson, D. W. On Growth and Form (Cambridge Univ. Press, 1942).

    MATH  Google Scholar 

  17. Anderson, O. R. in Biomineralization in Lower Plants and Animals (eds Leadbeater, B. S. C. & Riding, R.) 375–391 (Systematics Assocn Vol. 30, Oxford Univ. Press, 1986).

    Google Scholar 

  18. Crawford, R. M. & Schmid, A.-M. M. in Biomineralization in Lower Plants and Animals (eds Leadbeater, B. S. C. & Riding, R.) 290–314 (Systematics Assocn Vol. 30, Oxford Univ. Press, 1986).

    Google Scholar 

  19. Leadbeater, B. S. C. Proc. R. Soc. Lond. B304, 529–536 (1984).

    Google Scholar 

  20. Westbroek, P., van der Wal, P., van Emburg, P. R., de Vrind-de Jong, E. W. & de Bruijn, W. C. in Biomineralization in Lower Plants and Animals (eds Leadbeater, B. S. C. & Riding, R.) 189–203 (Systematics Assocn Vol. 30, Oxford Univ. Press, 1986).

    Google Scholar 

  21. Ledger, P. W. & Jones, W. C. Cell Tiss. Res. 181, 553–567 (1977).

    Article  CAS  Google Scholar 

  22. Märkel, K., Röser, U., Mackenstedt, U. & Klosterman, M. Zoomorphology 106, 232–243 (1986).

    Article  Google Scholar 

  23. Wilbur, K. M. & Saleuddin, A. S. M. in The Mollusca Vol. 4 (eds Saleuddin, A. S. M. & Wilbur, K. M.) 235–287 (Academic, New York, 1983).

    Book  Google Scholar 

  24. Currey, J. The Mechanical Adaptations of Bones (Princeton Univ. Press, New Jersey, 1984).

    Book  Google Scholar 

  25. Weiner, S. CRC Crit. Rev. Biochem. 20, 365–408 (1986).

    Article  CAS  Google Scholar 

  26. Heywood, B. R. & Mann, S. Adv. Mater. 6, 9–20 (1994).

    Article  CAS  Google Scholar 

  27. Fendler, J. H. & Meldrum, F. C. Adv. Mater. 7, 607–632 (1995).

    Article  CAS  Google Scholar 

  28. Feng, S. & Bein, T. Nature 368, 834–836 (1994).

    Article  ADS  CAS  Google Scholar 

  29. Shin, H., Collins, R. J., de Guire, M. R., Heuer, A. H. & Sukenik, C. N. J. Mater. Res. 10, 692–703 (1995).

    Article  ADS  CAS  Google Scholar 

  30. Baral, S. & Schoen, P. Chem. Mater. 5, 145–147 (1993).

    Article  CAS  Google Scholar 

  31. Archibald, D. D. & Mann, S. Nature 364, 430–433 (1993).

    Article  ADS  CAS  Google Scholar 

  32. Burkett, S. L. & Mann, S. Chem. Commun. 321–322 (1996).

  33. Tanev, P. T. & Pinnavaia, T. J. Science 271, 1267–1269 (1996).

    Article  ADS  CAS  Google Scholar 

  34. Chenite, A., Le Page, Y., Karra, V. R. & Sayari, A. Chem. Commun. 411–413 (1996).

  35. Attard, G. S., Glyde, J. C. & Goltner, C. G. Nature 378, 366–368 (1995).

    Article  ADS  CAS  Google Scholar 

  36. Braun, P. V., Osenar, P. & Stupp, S. I. Nature 380, 325–328 (1996).

    Article  ADS  CAS  Google Scholar 

  37. Zones, S. I. & Davis, M. E. Current Opin. Solid St. Mater. Sci. 1, 107–117 (1996).

    Article  ADS  CAS  Google Scholar 

  38. Anderson, S., Hyde, S. T., Larsson, K. & Lidin, S. Chem. Rev. 88, 221–240 (1988).

    Article  Google Scholar 

  39. Huo, Q. et al. Chem. Mater. 6, 1176–1191 (1994).

    Article  CAS  Google Scholar 

  40. Firouzi, A. et al. Science 267, 1138–1143 (1995).

    Article  ADS  CAS  Google Scholar 

  41. Yang, H., Coombs, N., Kuperman, A. & Ozin, G. A. Nature 379, 703–705 (1996).

    Article  ADS  CAS  Google Scholar 

  42. Manne, S. & Gaub, H. Science 270, 1480–1482 (1995).

    Article  ADS  CAS  Google Scholar 

  43. Khushalani, D., Kuperman, A., Oliver, S. & Ozin, G. A. in NATO Adv. Res. Workshop. Proc.: Modular Chemistry (ed. Michl, J.) (Aspen, Colorado, 1995).

    Google Scholar 

  44. Khushalani, D., Coombs, N., Kuperman, A. & Ozin, G. A. Adv. Mater. 7, 842–847 (1995).

    Article  CAS  Google Scholar 

  45. Watzke, H. J. & Dieschbourg, C. Adv. Colloid Interface Sci. 50, 1–14 (1994).

    Article  CAS  Google Scholar 

  46. Walsh, D., Hopwood, J. D. & Mann, S. Science 264, 1576–1578 (1994).

    Article  ADS  CAS  Google Scholar 

  47. Walsh, D. & Mann, S. Nature 377, 320–323 (1995).

    Article  ADS  CAS  Google Scholar 

  48. Oliver, S., Kuperman, A., Coombs, N., Lough, A. & Ozin, G. A. Nature 378, 47–50 (1995).

    Article  ADS  CAS  Google Scholar 

  49. Phil. Trans. R. Soc. Lond. B 304, 518 (1984).

Download references

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Mann, S., Ozin, G. Synthesis of inorganic materials with complex form. Nature 382, 313–318 (1996). https://doi.org/10.1038/382313a0

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