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Chemical and isotopic evidence of thermochemical sulphate reduction by light hydrocarbon gases in deep carbonate reservoirs

Nature volume 333, pages 415–419 (1988)Cite this article

Abstract

Large H2S accumulations in deep carbonate reservoirs have been attributed to thermochemical sulphate reduction. Although organic matter has been invoked as the reducing agent, individual reactants in specific environments have hitherto not been identified. Carbon isotope data reveal that light hydrocarbon gases have been effective reducing agents in some Palaeozoic foothill reservoirs of western Canada.

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References

  1. Hitchon, B. J. Can. petrol. Technol. 2, 100–116 (1963).

    Article  Google Scholar 

  2. Anisimov, L. A. Int. geol. Rev. 13, 191–197 (1971).

    Article  Google Scholar 

  3. Hyne, J. B., Lau, C. S. C., Dowling, N. I., Davis, P. & Lesage, K. Alberta Sulphur Research Ltd Report XXII No. 1, 25–39 (1985).

  4. Anisimov, L. A. Geochem. int. 15, 63–71 (1978).

    Google Scholar 

  5. Harben, P. Mining Mag. 155, 374–379 (1986).

    Google Scholar 

  6. Orr, W. L. Am. Assoc. petrol. geol. Bull. 50, 2295–2318 (1974).

    Google Scholar 

  7. Orr, W. L. Advances in Organic Geochemistry 1975, Madrid, Enadisma (eds Campos, R. & Goni, J.) 571–597 (1977).

    Google Scholar 

  8. Krouse, H. R. J. geochem. Explor. 7, 189–211 (1977).

    Article  CAS  Google Scholar 

  9. Bely, V. M. & Vinogradov, V. I. Geologiya Nefti Gaza N2, 37–41 (1972).

  10. Toland, W. G. J. Amer. chem. Soc. 82, 1911–1916 (1960).

    Article  Google Scholar 

  11. Kiyosu, Y. Chem. Geol. 30, 47–56 (1980).

    Article  ADS  CAS  Google Scholar 

  12. Trudinger, P. A., Chambers, L. A. & Smith, J. W. Can. J. Earth Sci. 22, 1910–1918 (1985).

    Article  ADS  CAS  Google Scholar 

  13. Orr, W. L. Geol. Soc. Am. Abstr. Progm. 14, 580 (1982).

    Google Scholar 

  14. Eliuk, L. S. & Hunter, D. F. in 13th Can. Soc. Petrol. Geol. Core Conf. (eds F. Krause and G. Burrowes) 39–62 (1987).

    Google Scholar 

  15. Claypool, G. E., Holser, W. T., Kaplan, I. R., Sakai, H. & Zak, I. Chem. Geol. 28, 199–260 (1980).

    Article  ADS  CAS  Google Scholar 

  16. Harrison, A. G. & Thode, H. G. Trans. Faraday Soc. 53, 1648–1651 (1957).

    Article  CAS  Google Scholar 

  17. Grinenko, V. A., Grinenko, L. N. & Zagryazhskaya, G. D. Geokhimya 4, 484–491 (1969).

    Google Scholar 

  18. Husain, S. A. & Krouse, H. R. New Zealand Department Scientific and Industrial Research Bull. 220, 207–210 (1978).

    CAS  Google Scholar 

  19. Krouse, H. R. Final Report Alberta-Canada Energy Resources research fund, agreement U-30, 145 pp. (1983).

  20. Baas Becking, L. G. M. Ann. Bot. 39, 613–650 (1925).

    Article  CAS  Google Scholar 

  21. Krouse, H. R. in Proc. 10th World Petrol. Congress Vol. 10, 85–92 (1980).

    Google Scholar 

  22. Thode, H. G., Wanless, R. K. & Wallouch, R. Geochim. cosmochim. Acta 5, 286–298 (1954).

    Article  ADS  CAS  Google Scholar 

  23. Feely, H. W. & Kulp, J. L. Am. Assoc. petrol. geol. Bull. 41, 1802–1853 (1957).

    Google Scholar 

  24. Davis, J. B. & Kirkland, D. W. Econ. Geol. 65, 107–121 (1970).

    Article  CAS  Google Scholar 

  25. James, A. T. & Burns, B. J. Am. Assoc. petrol. geol. Bull. 68, 957–960 (1984).

    CAS  Google Scholar 

  26. Stahl, W. Chem. Geol. 20, 121–149 (1977).

    Article  ADS  CAS  Google Scholar 

  27. Bally, A. W., Gordy, P. L. & Stewart, G. A. Bull. Can. Petrol. Geol. 14, 337–381 (1966).

    Google Scholar 

  28. Woll, W. Erdöl Kohle Erdgas Petrochem. 99, 297–300 (1983).

    CAS  Google Scholar 

  29. Eliuk, L. S. 1984 Can. Soc. Petrol. Geol. Core Conf. 245–289 (1984).

  30. Berner, R. A. Am. J. Sci. 278, 1235–1252 (1978).

    Article  ADS  CAS  Google Scholar 

  31. Stahl, W. & Carey, B. C. Chem. Geol. 16, 257–267 (1975).

    Article  ADS  CAS  Google Scholar 

  32. James, A. T. Am. Assoc. Petrol. Geol. Bull. 67, 1176–1191 (1983).

    CAS  Google Scholar 

  33. Schoell, V. M. Am. Assoc. Petrol. Geol. Bull. 67, 2225–2238 (1983).

    CAS  Google Scholar 

  34. Harland, W. B. et al. A Geologic Time Scale: Cambridge Earth science series (Cambridge Univ. Press, 1982).

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Physics, The University of Calgary, Calgary, Alberta, T2N 1N4, Canada

    H. Roy Krouse

  2. Shell Canada Limited, P.O. Box 2506, Calgary, Alberta, T2P3S6, Canada

    Christian A. Viau & Leslie S. Eliuk

  3. Mitsubishi Metal Corporation, Central Research Institute, 1-297 Kitabukuro, Omiya, Saitama, 330, Japan

    Akira Ueda

  4. Marie Curie-Sklodowska University, Institute of Physics, Lublin, Poland

    Stan Halas

Authors
  1. H. Roy Krouse
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  2. Christian A. Viau
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  3. Leslie S. Eliuk
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  4. Akira Ueda
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  5. Stan Halas
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Krouse, H., Viau, C., Eliuk, L. et al. Chemical and isotopic evidence of thermochemical sulphate reduction by light hydrocarbon gases in deep carbonate reservoirs. Nature 333, 415–419 (1988). https://doi.org/10.1038/333415a0

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