Abstract
There is considerable interest in materials with nonlinear optical properties. Two important manifestations of light interacting with a nonlinear optical material are, the process of second-harmonic generation (SHG) which is relevant to new laser technology, and the electro-optic effect which has applications in telecommunications and in integrated optics1. Several inorganic and organic materials with unusually large second-order nonlinearities are known1. However, reports of organometallic compounds with second-order nonlinear optical properties are few2–4 and they have relatively small values for SHG efficiencies. Here we describe a new compound (cis)-[1-ferrocenyl-2-(4-nitrophenyl)ethylene] (compound 2) exhibits solvatochromic behaviour. A Kurtz-powder measurement, using 1.907 µm light from a Raman shifted Nd-YAG laser operating at 1.064 µm, shows the compound provides highly efficient second harmonic generation, with a signal some 62 times that from a urea reference sample. The single crystal X-ray structure of (cis)-[1-ferrocenyl-2-(4-nitrophenyl)ethylene] has been determined. The large nonlinear optical property of this compound demonstrates that organotransition metal compounds can play an important role in the development of the nonlinear optical properties of materials.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
1. Williams, D. J. Angew. Chem. Int. Ed. Engl. 23, 690-703, (1984) (References therein). 2. Frazier, C. C, Harvey, M. A., Cockerham, M. P., Hand, H. M., Chauchard, E. A. & Lee, Chi H. J. phys. chem. 90, 5703-5706 (1986). 3. Eaton, D. F., Anderson, A. G., Tarn W. & Yang, Y. J. Am. chem. Soc. 109, 1886-1888 (1987). 4. Calabrese J. C. & Tarn, W. Chem. phys. Lett. 133, 244-245 (1987). 5. Teng C. C. & Garito, A. F. Phys. Rev. B28, 6766-6733 (1983). 6. Pauson, P. L. & Watts, W. E. / chem. Soc. 2990-2996 (1963). 7. Toma, S., Gaplovsky A. & Elecko, P. Chem. Pap. 39, 115-124 (1985) 8. Kurtz S. K. & Perry, T. T. J. appl. Phys. 39, 3798 (1968). 9. Zyss, J. & Oudar, J. L. Phys. Rev. A26, 2028-2048 (1982). 10. Rollett, J. S. Crystallographic computing (ed. Ahmed, F. R.), 169-179 (Munksgaard, Copenhagen 1969). 11. Waser, J. Acta crystallogr. 16, 1091-1094 (1963). 12. Watkin, D. J., Carruthers, J. R. & Betteridge, P. W. CRYSTALS User Guide (Chemical Crystallography Laboratory, University of Oxford, 1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Green, M., Marder, S., Thompson, M. et al. Synthesis and structure of (cis)-[1-ferrocenyl-2-(4-nitrophenyl)ethylene], an organotransition metal compound with a large second-order optical nonlinearity. Nature 330, 360–362 (1987). https://doi.org/10.1038/330360a0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1038/330360a0
This article is cited by
-
The numerous paths of ferrocene
Nature Chemistry (2023)
-
Designing of gigantic first-order hyperpolarizability molecules via joining the promising organic fragments: a DFT study
Journal of Molecular Modeling (2023)
-
A theoretical study of alkaline-earthides Li(NH3)4M (M = Be, Mg, Ca) with large first hyperpolarizability
Journal of Molecular Modeling (2019)
-
The effect of Li doping on the nonlinear optical properties of [2.2]paracyclophane
Journal of Molecular Modeling (2016)
-
One lithium atom binding with P-nitroaniline: lithium salts or lithium electrides?
Journal of Molecular Modeling (2015)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.