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Stratospheric NO2 and upper limits of CH3Cl and C2H6 from measurements at 3.4 µm

Nature volume 303, pages 221–222 (1983)Cite this article

Abstract

Measurements of stratospheric minor constituent gas concentrations are important, for the elucidation of the complex chemistry and the evaluation of the predictions presented by theoretical models regarding the short and long term future of this important atmospheric region. We report here high resolution absorption spectra that have been obtained from a balloon-borne platform in the 3.4-µm spectral region, a region which contains bands due to several atmospheric constituent gas species including methane (CH4), hydrochloric acid (HCl), nitrogen dioxide (NO2), methyl chloride (CH3Cl) and ethane (C2H6). From analysis of the atmospheric spectra obtained during sunset, mixing ratio versus altitude profiles have been obtained for HCl (which will be reported elsewhere) and NO2, and upper limits have been obtained for the lower stratospheric mixing ratios of CH3Cl and C2H6.

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References

  1. Dana, V. & Maillard, J. P. J. molec. Spectrosc. 71, 1–14 (1978).

    Article  ADS  CAS  Google Scholar 

  2. Perrin, A., Flaud, J.-M. & Camy-Peyret, C. Infrared Phys. 22, 343–348 (1982).

    Article  ADS  CAS  Google Scholar 

  3. Morillon-Chapey, M. & Graner, G. J. molec. Spectrosc. 31, 155–169 (1969).

    Article  ADS  CAS  Google Scholar 

  4. Cole, A. R. H., Cross, J. H., Cugley, J. A. & Heise, H. M. J. molec. Spectrosc. 83, 233–244 (1980).

    Article  ADS  CAS  Google Scholar 

  5. Toth, R. A., Brown, L. R., Hunt, R. H. & Rothman, L. S. Appl. Opt. 20, 932–935 (1981).

    Article  ADS  CAS  Google Scholar 

  6. Park, J. H. et al. Atlas of Absorption Lines From 0 to 17900 cm−1 (NASA Ref. Publ. 1084, 1981).

    Google Scholar 

  7. Traub, W. A. & Stier, M. T. Appl. Opt. 15, 364–377 (1976).

    Article  ADS  CAS  Google Scholar 

  8. Murcray, D. G. & Goldman, A. (eds) CRC Handbook of High Resolution Infrared Laboratory Spectra of Atmospheric Interest (CRC Press, Boca Raton, Florida, 1981).

  9. Ackerman, M. & Muller, C. Nature 240, 300–301 (1972).

    Article  ADS  CAS  Google Scholar 

  10. Camy-Peyret, C., Flaud, J.-M., Laurent, J. & Stokes, G. M. Geophys. Res. Lett. 10, 35–38 (1983).

    Article  ADS  CAS  Google Scholar 

  11. Ackerman, M. et al. Planet. Space Sci. 23, 651–660 (1975).

    Article  ADS  CAS  Google Scholar 

  12. Fontanella, J.-C., Girard, A., Gramont, L. & Louisnard, N. Appl. Opt. 14, 825–839 (1975).

    Article  ADS  CAS  Google Scholar 

  13. Niple, E., Mankin, W. G., Goldman, A., Murcray, D. G. & Murcray, F. J. Geophys. Res. Lett. 7, 489–492 (1980).

    Article  ADS  CAS  Google Scholar 

  14. Blatherwick, R. D. et al. Geophys. Res. Lett. 7, 471–473 (1980).

    Article  ADS  CAS  Google Scholar 

  15. Kerr, J. B. & McElroy, C. T. Atmosphere 14, 166–171 (1976).

    Article  Google Scholar 

  16. Goldman, A., Fernald, F. G., Williams, W. J. & Murcray, D. G. Geophys. Res. Lett. 5, 257–260 (1978).

    Article  ADS  CAS  Google Scholar 

  17. Evans, W. F. J. et al. WMO Symp. on the Geophysical Aspects and Consequences of Changes in the Composition of the Stratosphere 55–59 (WMO No. 511, 1978).

    Google Scholar 

  18. Kerr, J. B., McElroy, C. T. & Evans, W. F. J. Can. J. Phys. 60, 196–200 (1982).

    Article  ADS  CAS  Google Scholar 

  19. Toth, R. A. & Hunt, R. H. J. molec. Spectrosc. 79, 182–202 (1980).

    Article  ADS  CAS  Google Scholar 

  20. Goldman, A. & Saunders, R. S. J. quant. Spectrosc. Radiat. Transf. 21, 155–161 (1979).

    Article  ADS  CAS  Google Scholar 

  21. Roscoe, H. K., Drummond, J. R. & Jarnot, R. F. Proc. R. Soc. A375, 507–528 (1981).

    Article  ADS  CAS  Google Scholar 

  22. Miller, C., Filkin, D. L., Owens, A. J., Steed, J. M. & Jesson, J. P. J. geophys. Res. 86, 12039–12065 (1981).

    Article  ADS  CAS  Google Scholar 

  23. Noxon, J. F. J. geophys. Res. 84, 5067–5076 (1979); 85, 4560–4561 (1980).

    Article  ADS  CAS  Google Scholar 

  24. Coffey, M. T., Mankin, W. G. & Goldman, A. J. geophys. Res. 86, 7331–7341 (1981).

    Article  ADS  CAS  Google Scholar 

  25. Margolis, J. S. & Toth, R. A. J. molec. Spectrosc. 66, 30–34 (1977); 68, 171 (1977).

    Article  ADS  CAS  Google Scholar 

  26. Dang-Nhu, M., Morillon-Chapey, M., Graner, G. & Guelachvili, G. J. quant. Spectrosc. Radiat. Transf. 26, 515–521 (1981).

    Article  ADS  CAS  Google Scholar 

  27. Penkett, S. A., Derwent, R. G., Fabian, P., Borchers, R. & Schmidt, U. Nature 283, 58–60 (1980).

    Article  ADS  CAS  Google Scholar 

  28. Fabian, P., Borchers, R., Penkett, S. A. & Prosser, N. J. D. Nature 294, 733–735 (1981).

    Article  ADS  CAS  Google Scholar 

  29. Rudolph, J., Ehhalt, D. H. & Tonnissen, A. J. geophys. Res. 86, 7267–7272 (1981).

    Article  ADS  CAS  Google Scholar 

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Authors and Affiliations

  1. Herzberg Institute of Astrophysics, National Research Council of Canada, Ottawa, Ontario, Canada, K1A 0R6

    D. J. W. Kendall

  2. Bomem Inc., 910 Place Dufour, Vanier, Québec, Canada, G1M 3B1

    H. L. Buijs

Authors
  1. D. J. W. Kendall
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  2. H. L. Buijs
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Kendall, D., Buijs, H. Stratospheric NO2 and upper limits of CH3Cl and C2H6 from measurements at 3.4 µm. Nature 303, 221–222 (1983). https://doi.org/10.1038/303221a0

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