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Paraffinic hydrocarbons from supercritical-gas extracts of coal as organic geochemical markers

Abstract

PARAFFINIC hydrocarbons have been proposed as indicators of the conditions obtaining during the deposition and subsequent maturation of sediments1–4. We consider here the relationship between the rank (as measured by carbon content) of coals and analytical results for the alkane fractions obtained by a novel extraction procedure (under investigation for the derivation of liquid fuels and feedstocks from coal5,6) which uses super-critical gases (SCG). We first discuss the limitations of n-alkane distributions and then deal with acyclic isoprenoids, drawing particular attention to the ratio of pristane to phytane.

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References

  1. Maxwell, J. R., Pillinger, C. T. & Eglinton, G. Q. Rev. 25, 571 (1971).

    Article  CAS  Google Scholar 

  2. Didyk, B. M., Simoneit, B. R. T., Brassell, S. C. & Eglinton, G. Nature 272, 216 (1978).

    Article  ADS  CAS  Google Scholar 

  3. Bartle, K. D., Jones, D. W. & Pakdel, H. in Analytical Methods for Coal and Coal Products Vol 2 (ed Karr, C., Jr) 209 (Academic, New York, 1979).

    Google Scholar 

  4. Welte, D. Erdöl Kohle 31, 139 (1978).

    CAS  Google Scholar 

  5. Whitehead, J. C. & Williams, D. F. J. Inst. Fuel 48, 182 (1975).

    CAS  Google Scholar 

  6. Maddocks, R. R. & Gibson, J. J. Chem. Engng Progr. 59 (1977).

  7. Leythaeuser, D. & Welte, D. H. in Advances in Organic Geochemistry 1968 (eds Schenck, P. A. & Havenaar, I.) 429 (Pergamon, Oxford, 1969).

    Book  Google Scholar 

  8. Brooks, J. D. & Smith, J. W. Geochim. cosmochim. Acta 31, 2389 (1967).

    Article  ADS  CAS  Google Scholar 

  9. Firth, J. N. & Eglinton, G. in Advances in Organic Geochemistry 1971 (eds von Gaertner, H. R. & Wehner, H.) 613 (Pergamon, London, 1972).

    Google Scholar 

  10. White, C. M., Shultz, J. L. & Sharkey, A. G. Jr, Nature 268, 620 (1977).

    Article  ADS  CAS  Google Scholar 

  11. Bartle, K. D., Martin, T. G. & Williams, D. F. Fuel 54, 226 (1975).

    Article  CAS  Google Scholar 

  12. Bartle, K. D., Jones, D. W. & Pakdel, H. in Molecular Spectroscopy (ed. West, A. R.) 127 (Heyden, London, 1977).

    Google Scholar 

  13. Bartle, K. D., Ladner, W. R., Snape, C. E., Martin, T. G. & Williams, D. F. Fuel (submitted).

  14. Kershaw, J. R. S. Afr. J. Chem. 30, 205 (1977).

    CAS  Google Scholar 

  15. Bartle, K. D., Jones, D. W., Martin, T. G. & Wise, W. S. J. appl. Chem. 20, 197 (1970).

    Article  CAS  Google Scholar 

  16. Vahrman, M. Fuel 49, 5 (1970).

    Article  CAS  Google Scholar 

  17. Allan, J. thesis, Univ. Newcastle-upon-Tyne (1972).

  18. Brooks, J. D., Gould, K. & Smith, J. W. Nature 222, 257 (1969).

    Article  ADS  CAS  Google Scholar 

  19. Connan, J. in Advances in Organic Geochemistry 1973 (eds Tissot, B. & Bienner, F.) 73 (Technip, Paris, 1974).

    Google Scholar 

  20. Albrecht, P., Vanderbroucke, M. & Mandengue, M. Geochim. cosmichim. Acta 40, 791 (1976).

    Article  ADS  CAS  Google Scholar 

  21. Teichmüller, M. in Advances in Organic Geochemistry 1973 (eds Tissot, B. & Bienner, F.) 379 (Technip, Paris, 1974).

    Google Scholar 

  22. Powell, T. G. & McKirdy, D. M. Bull. Am. Ass. Petrol. Geol. 59, 1176 (1975).

    CAS  Google Scholar 

  23. Given, P. H. in Advances in Organic Geochemistry 1971 (eds von Gaertner, H. R. & Wehner, H.) 69 (Pergamon, London, 1972).

    Google Scholar 

  24. Long, C. (ed.) Biochemists Handbook (Spon, London, 1961).

  25. Merrill, R. C., Scotti, L. J., Ford, L. & Domina, D. J. in Coal Processing Technology 2, 88 (American Institute of Chemical Engineers, New York, 1975).

    Google Scholar 

  26. Gibson, J. & Gregory, D. H. Carbonisation of Coal ch. 4 (Mills and Boon, London, 1971).

    Google Scholar 

  27. Bartle, K. D., et al. Fuel (submitted).

Download references

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BARTLE, K., JONES, D., PAKDEL, H. et al. Paraffinic hydrocarbons from supercritical-gas extracts of coal as organic geochemical markers. Nature 277, 284–287 (1979). https://doi.org/10.1038/277284a0

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