Abstract
MEASUREMENTS of atmospheric water vapour concentrations have been confined to altitudes below about 50 km showing an average volume mixing ratio of about 4×10−6 in the middle and upper stratosphere1. Only limited and rather indirect observational information on water vapour exists above 50 km including, for example, the presence of hydrated positive and negative ions and noctilucent clouds likely being composed of water ice particles. In a previous attempt to derive water vapour concentrations from measurements of hydrated positive ions, a mixing ratio between 1 and 2 × 10−6 below 78 km and a sharp decrease above was inferred2. In this paper, water vapour concentrations are derived at heights between 85km and 94km from two rocket-borne mass spectrometer measurements of atmospheric positive ions. The experiments took place at Andoya (69°N, 16°E) on May 31 1972 (ref. 3) and at Kiruna (68°N, 21°E) on August 18 1974 (ref. 4).
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ARNOLD, F., KRANKOWSKY, D. Water vapour concentrations at the mesopause. Nature 268, 218–219 (1977). https://doi.org/10.1038/268218a0
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DOI: https://doi.org/10.1038/268218a0
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